• Title/Summary/Keyword: emission spectra

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Fabrication and Characterization of CdSe/ZnS-QDs Incorporated Microbeads for Ultra-sensitive Sensor Applications (양자점을 이용한 고감도 마이크로 비드의 제조 및 특성)

  • Lee, Dong-Sup;Lee, Jong-Chul;Lee, Jong-Heun;Koo, Eun-Hae
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.189-194
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    • 2010
  • Compared with organic fluorophores, semiconductor quantum dots (QDs) have the better properties such as photostability, narrow emission spectra coupled to tunable photoluminescent emissions and exceptional resistance to both photo bleaching and chemical degradation. In this work, CdSe/ZnS QDs nanobeads were prepared by the incorporation of CdSe/ZnS QDs with mesoporous silica to use as the optical probe for detecting toxic and bio- materials with high sensitivity, CdSe/ZnS core/shell QDs were synthesized from the precursors such as CdO and zinc stearate with the lower toxicity than pyrotic precursors. The QD-nanobeads were characterized by transmission electron microscopy, FL microscopy, UV-Vis and PL spectroscopy, respectively.

Photoluminescence characteristics of ZnTe single crystal thin films substi-tuted by sulfur (Sulfur에 의하여 치환된 ZnTe 단결정 박막의 광발광 특성)

  • 최용대
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.6
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    • pp.279-283
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    • 2003
  • In this study, ZnTe : S single crystal thin films substituted by sulfur were grown on GaAs (100) substrates by hot-wall epitaxy. The photoluminescence (PL) characteristics of ZnTe : S single crystal thin films was measured to investigate the effects due to sulfur atoms in the ZnTe layer. The Peak of 2.339 eV identified as the isoelectronic center was observed in low temperature PL spectrum, but PL spectra which the origin had not been well-explained were not observed. Temperature dependence of PL intensities of the light hole free exciton was explained by extrinsic self-trapping. Besides it is reported that the emission lines near absorption edge at room temperature were observed.

Low molecular amorphous spirobifluorene derivatives for blue electroluminescence

  • Lee, Hyo-Young;Oh, Ji-Young;Chu, Hye-Yong;Lee, Jeong-Ik;Kim, Seong-Hyun;Yang, Yong-Suk;Do, Lee-Mi;Zyung, Tae-Hyoung
    • 한국정보디스플레이학회:학술대회논문집
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    • 2001.08a
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    • pp.209-212
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    • 2001
  • We report the synthesis and characterization of new alkoxy substituted spirobifluorene derivatives. The spiro compounds having alkoxy hydrocarbon chains were readily soluble in common organic solvents, having improved film-forming properties and had a significantly reduced tendency to crystallize, resulting in increasing their service lifetime. The results of DSC showed that it was amorphous. The optical and electroluminescent spectra were characterized. Electroluminescence (EL) properties of three-layer light emitting diodes (LED) of $ITO/TPD/spirobifluorene/Alq_3/LiF/Al$ as the active layer were characterized. Blue emission peaking of the EL spectrum of the three-layer device at 402 nm and a luminance of 3,125 $cd/m^2$ were achieved at a drive voltage 12.8 V. The luminous efficiency was obtained to be 1.7 lm/W. The color coordinate in CIE chromaticity is (0.16, 0.09), which is in a pure blue region. The external quantum efficiency was obtained to be 2.0%. The results indicate that the spirobifluorene compounds having alkoxy hydrocarbon chains are strongly potential blue emitters for LED applications.

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Luminous phosphor with modified surface composition and microwave treatment for plasma planar back light

  • Ting, Chu-Chi;Cheng, Hao-Ping;Hsieh, Yu-Heng;Sun, Oliver;Chen, San-Yuan;Lin, Chin-Ching;Kuo, Kuan-Ting;Lee, Shu-Ping
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1534-1535
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    • 2005
  • Highly luminescent efficiency phosphors have been successfully produced by surface modification and microwave irradiation treatment. The SEM image and XRD analysis reveal that the surface morphology of the white-light phosphors can be notably modified by microwave irradiation and exhibit with better crystalline property. The VUV PL spectra show that the microwave irradiation treatment can effectively enhance the luminescent efficiency by a factor of 1.5 times for intensity compared to that without microwave treatment. A further improvement in all visible emission can be made by modifying surface composition through MgO coating on the phosphor powder. These results demonstrate that such a simple approach can provide for improving luminescent efficiency of phosphors for the optoelectronic devices.

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The Origin of Change in Luminescent Properties of ZnMgS:Mn Thin Film Phosphor with Varying Annealing Temperature

  • Lee, Dong-Chin;Kang, Jong-Hyuk;Jeon, Duk-Young;Yun, Sun-Jin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1576-1579
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    • 2005
  • With varying rapid thermal annealing (RTA) temperature, luminescence properties of $Zn_{0.75}Mg_{0.25}S:Mn$ thin film deposited by RF-magnetron sputtering technique were investigated. In this study, $Zn_{0.75}Mg_{0.25}S:Mn$ thin film phosphor showed more red emission than those of the previous studies when annealed around 600 or $650^{\circ}C$. Although all samples were deposited from identical source composition, a main peak wavelength of photoluminescence spectra of $Zn_{0.75}Mg_{0.25}S:Mn$ shifted toward shorter wavelengths depending upon increase of RTA temperature. The same dependence of wavelength on RTA temperature was also observed in cathodoluminescence as well as electroluminescence measurements. It was revealed that the change of the luminescence properties were originated from structural changes in $Zn_{0.75}Mg_{0.25}S:Mn$ thin film phosphor from cubic to hexagonal phases analyze using conventional X-ray pole figure mapping. The phase transition would be the origin of luminescence property changes with respect to RTA temperature.

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Effect of Luminescence with Coactivator of $ZnGa_2O_4$:Mn,X phosphor ($ZnGa_2O_4$:Mn,X 형광체의 부활성제에 따른 발광 효과)

  • 박용규;한정인;주성후
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.3
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    • pp.242-247
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    • 1998
  • In this study, we have synthesized $ZnGa_2O_4$:Mn,X powder doped with Mn, MnO, $MnF_2$ and $MnCl_2$, low voltage green emitting phosphor, in vacuum atmosphere. From PL spectra, the intensity of the emission peak, the brightness with coactivator show that $ZnGa_2O_4$:Mn,Cl > $ZnGa_2O_4$:Mn,F > $ZnGa_2O_4$:Mn,O > $ZnGa_2O_4$:Mn. These improvement of the brightness are caused by the increase of the concentration of $Mn^{2+}$ ion. In case of $ZnGa_2O_4$:Mn,Cl and ZnGa$_2$O$_4$:Mn,F, the brightness is enhanced much more, which is owed to the decrease of defect of host material. For $ZnGa_2O_4$:Mn,Cl phosphor fabricated with optimized condition, the decay time becomes short from 30 ms of the $ZnGa_2O_4$:Mn and $ZnGa_2O_4$:Mn,O to 6 ms and the brightness of CL at 1 kV, 1 mA is 60 cd/$m^2$.

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EMI reduction of PWM converter By Binary Switching Frequency Modulation (2진 스위칭 주파수 변조에 의한 PWM 컨버터의 EMI 저감)

  • Jin, In-Su;Park, Seok-Ha;Yang, Kyeong-Rok;Kim, Yang-Mo
    • Proceedings of the KIEE Conference
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    • 1999.07f
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    • pp.2650-2652
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    • 1999
  • To satisfy the demand for small size, light weight. high density power supply, the switching frequency of DC/DC converters has been increased. The PWM control of the conventional SMPS have a switching frequency that a level of the conducted noise spectra contribute to switching frequency band. So the electronic equipment is not only affected from that but is restricted to internal regulation like CISPR, FCC, and VDE. In this paper, we analyzed Bi-FM. Bi-FM is two fixed switching frequency with a modulation frequency. So emission spectrum of Bi-FM control signal is spreaded and spectral power level is reduced. In this paper, we analyze the spectral analysis of Bi-FM control signal and the spectral comparison between the PWM control and Bi-FM control. And we confirm that reduced the spectrum power level through simulation using Pspice and experiment.

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Photoluminescence Excitation Spectroscopy Studies of Anodically Etched and Oxidized Porous Zn

  • Chang, Sung-Sik;Lee, Hyung-Jik
    • Journal of the Korean Ceramic Society
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    • v.41 no.5
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    • pp.359-363
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    • 2004
  • Photoluminescence excitation (PLE) spectroscopy studies were performed for anodically etched porous Zn, which exhibited a PL in the blue/violet spectral range peaking at 420 nm (2.95 eV), and oxidzed porous Zn at 380$^{\circ}C$ for 10 min and 12 h. A broad absorption band was observed at 4.07 eV (305 nm), 3.49 (355 nm) for anodically etched porous Zn. In contrast, both the oxidized porous Zn and sintered ZnO exhibited an almost identical one broad absorption band at 3.85 eV (322 nm), when PLE spectra were measured at 378 nm (3.28 eV). The oxidized porous Zn and sintered ZnO, which displayed both UV and green luminescence band, showed an additional absorption band at 389 nm (3.19 eV) and 467 nm (2.66 eV). In contrast, no significant absorption band was detected for a 10-min oxidized porous Zn, which only displayed one UV luminescence void of deep-level luminescence. These absorption bands determined by PLE studies enabled a clear understanding of an emission mechanism for the UV and green luminescence from ZnO.

The effect of helium thermal treatment using ZnO thin films (Zno 박막의 Helium 열처리에 대한 효과)

  • Ryu, Kung-Yul;Baek, Kyung-Hyung;Park, Hyeong-Sik;Jang, Kyung-Soo;Jung, Sung-Wook;Jeong, Han-Uk;Yun, Eui-Jung;Yi, J.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.145-145
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    • 2010
  • It is observed from SEM images that many voids were created after annealed by helium gas. The PL spectra of the ZnO samples revealed the strong violet emission peaks at 3.05 eV with the relative weak near band edge UV emissions. It was concluded from experiment results that native $Zn_i$ and $V_o$ donor defect levels can be generated below the conduction band edge due to the incorporation of helium atoms decomposed from helium gas into the ZnO matrix. He atoms in ZnO matrix will affect the interface trap existing in depletion regions located at the grain boundaries, which leads to the creation of $Zn_i$ and $V_o$ donor defect levels.

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Enhanced Hole Injections in Organic Light Emitting Diode using Rhodium Oxide Coated Anode

  • Kim, Soo-Young;Choi, Ho-Won;Kim, Kwang-Young;Tak, Yoon-Heung;Lee, Jong-Lam
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.5 no.2
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    • pp.77-82
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    • 2005
  • We compare electrical and optical properties of organic light emitting diodes (OLEDs) using rhodium-oxide-coated indium-tin-oxide ($O_2$-Rh/ITO) to that using $O_2$-plasma-treated ITO (ITO) anodes. The turn-on voltage decreased from 7 V to 5 V and luminance value increased when the $O_2$ plasma treated Rh layer was deposited on ITO. Synchrotron radiation photoelectron spectroscopy results showed the dipole energies of both ITO and $O_2$-Rh/ITO were same with each other, - 0.3 eV, meaning the formation of same amount of interface dipole. The secondary electron emission spectra revealed that the work function of $O_2$-Rh/ITO is higher hy 0.2 eV than that of ITO, resulting in the decrease of the tum-on voltage via reduction ofhole injection barrier.