• 제목/요약/키워드: emission spectra

검색결과 943건 처리시간 0.024초

유해성(有害性) 식품착색료(食品着色料)의 형광검사(螢光檢査) -여지흡착(濾紙吸着)을 이용한 형광분석법(螢光分析法)의 확립- (Fluorescence Analysis of Harmful Food Colors -Establishment of Fluorescence Assay Method by the Use of Filter Paper Adsorption-)

  • 이미순
    • 한국식품과학회지
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    • 제13권2호
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    • pp.114-120
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    • 1981
  • 색소(色素)를 흡착(吸着)시킨 여지(濾紙)를 시료(試料)로 간섭(干涉)필터를 통한 자다선(紫多線)을 조사(照射)한 경우에 $45^{\circ}$ 반사각(反射角)에서 발광(發光) 및 소광(消光)의 세기를 측정하여 신속하고 간편하게 색소(色素)를 감별(鑑別)할 수 있는 방법(方法)을 시도(試圖)하였다. 발광(發光) 스펙트럼 보다는 흡수(吸收) 스펙트럼이 보다 특징적인 패턴을 나타냈다. 흡수대(吸收帶)의 파장영역(波長領域), 분포상태(分布狀態) 및 개수(個數)와 소광(消光)정도를 조사하므로써 착색료(着色料) 종류가 용이하게 판별되었다.

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ON THE HOMOGENEITY OF THE EXTINCTION LAW IN OUR GALAXY

  • Bondar, A.;Galazutdinov, G.;Patriarchi, P.;Krelowski, J.
    • 천문학회지
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    • 제39권3호
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    • pp.73-80
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    • 2006
  • We analyze the extinction law towards several B1V stars-members of our Galaxy, searching for possible discrepancies from the galactic average extinction curve. Our photometric data allow to build extinction curves in a very broad range: from extreme UV till infrared. Two-colour diagrams, based on the collected photometric data from the ANS UV satellite, published UBV measurements and on the infrared 2MASS data of the selected stars, are constructed. Slopes of the fitted straight lines are used to build the average extinction curve and to search for discrepant objects. The selected stars have also been observed spectroscopically from the Terskol and ESO Observatories; these spectra allow to check their Sp/L's. The spectra of only about 30% of the initially selected objects resemble closely that of HD144470, considered as the standard of B1 V type. Other spectra either show some emission features or belong clearly to another spectral types. They are not used to build the extinction curve. Two-colour diagrams, constructed for the selected B1 V stars, showing no emission stellar features, prove that the interstellar extinction law is homogeneous in the Galaxy. Both the shape of the curve and the total-to-selective extinction ratio do not differ from the galactic average and the canonical value(3.1) respectively. The circumstellar emissions usually cause some discrepancies from the average interstellar extinction law; the discrepancies observed in the extraterrestrial ultraviolet, usually follow some misclassifications.

Structural and Optical Properties of Yellow-Emitting CaGd2ZrSc(AlO4)3:Ce3+ Phosphor for Solid-State Lighting

  • Kim, Yoon Hwa;Kim, Bo Young;Viswanath, Noolu S.M.;Arunkumar, Paulraj;Im, Won Bin
    • 한국세라믹학회지
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    • 제54권5호
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    • pp.422-428
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    • 2017
  • Single-phase yellow phosphor, $CaGd_{2-x}ZrSc(AlO_4)_3:xCe^{3+}$ ($CGZSA:Ce^{3+}$), possessing cubic symmetry with varied $Ce^{3+}$ concentrations, was synthesized using the solid-state reaction method. The samples were characterized using X-ray diffraction (XRD), excitation spectra, emission spectra, thermal quenching, and decay curves. The cubic phase of $CGZSA:Ce^{3+}$ phosphor was confirmed via XRD analysis. The photoluminescence spectra of $CGZSA:Ce^{3+}$ phosphor demonstrated that the phosphor could be excited at the wavelength of 440 nm; a broad yellow emission band was centered at 541 nm. These results indicate that the phosphors are adequately excited by blue light and have the potential to function as yellow-emitting phosphors for applications in white light-emitting diodes.

Resonant inelastic X-ray scattering of tantalum double perovskite structures

  • Oh, Ju Hyun;Kim, Jung Ho;Jeong, Jung Hyun;Chang, Seo Hyoung
    • Current Applied Physics
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    • 제18권11호
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    • pp.1225-1229
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    • 2018
  • In this paper, we investigated the electronic structures and defect states of $SrLaMgTaO_6$ (SLMTO) double perovskite structures by using resonant inelastic x-ray scattering. Recently, $Eu^{3+}$ doped SLMTO red phosphors have been vigorously investigated due to their higher red emission efficiency compared to commercial white light emitting diodes (W-LED). However, a comprehensive understanding on the electronic structures and defect states of host SLMTO compounds, which are specifically related to the W-LED and photoluminescence (PL), is far from complete. Here, we found that the PL spectra of SLMTO powder compounds sintered at a higher temperature, $1400^{\circ}C$, were weaker in the blue emission regions (at around 400 nm) and became enhanced in near infrared (NIR) regions compared to those sintered at $1200^{\circ}C$. To elucidate the difference of the PL spectra, we performed resonant inelastic x-ray spectroscopy (RIXS) at Ta L-edge. Our RIXS result implies that the microscopic origin of different PL spectra is not relevant to the Ta-related defects and oxygen vacancies.

$Tb^{3+}$ 첨가된 $YAlO_3$에서 Cross-Relaxation의한 발광 색변화 (Variation of Emission Colors through Cross-Relaxation In $Tb^{3+}$ Doped $YAlO_3$)

  • 김광철
    • 반도체디스플레이기술학회지
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    • 제11권1호
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    • pp.35-39
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    • 2012
  • $YAlO_3:Tb{_x}^{3+}$ has been synthesized by a combustion process and the concentration x of Tb was varied from 0.001 and 0.05 mol% per mole of $YAlO_3$. The emission optical properties on the $YAlO_3:Tb{_x}^{3+}$ have been investigated by time-resolved photoluminescence spectra and decay curves of center wavelength. The emission color changes from blue to green with increasing the $Tb^{3+}$ concentration from x= 0.001 to 0.05 mole fraction in $YAlO_3$ host. This emission color change can be explained in terms of cross-relaxation processes. Decay curves of emission intensity indicate that the type of energy transfer is donor-acceptor transition.

Exciplex를 이용한 백색 유기 전계발광소자의 발광특성 (Emission Properties of White Light Emission Organic Electroluminescent Device using Exciplex Emission)

  • 김주승;김종욱;구할본
    • 한국전기전자재료학회논문지
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    • 제14권9호
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    • pp.762-767
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    • 2001
  • We report the white light emission from the multilayer organic electroluminescent(EL) device using exciplex emission. The exciplex at 500nm originated between poly(N-vinylcarvazole)(PVK) and 2,5-bis(5'-tert-butyl-2-benzoxazoly)thiophene(BBOT) and exciplex of 50nm originated from N,N'-diphenyl-N,N'-(3-methyphenyl)-1,1'-biphenyl-4,4'-diamine(TPD) and BBOT were observed. Also, the energy transfer from PVK to BBOT and poly(3-hexylthiophene)(P3HT) in mixed emitting materials was occurred. The electroluminescence(EL) spectra of organic EL device which have a device structure of ITO/CuPc(5nm)/emitting layer(100nm)/BBOT(30nm)/LiF(1.4nm)/Al(200nm) were slightly changed as a function of the applied voltage. The luminance fo 12.3 ${\mu}$W/$\textrm{cm}^2$ was achieved at 20V and EL spectrum measured at 20V corresponds to Commission Internationale de L\`Eclairage(CIE) coordinates of x=0.29 and y=0.353.

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Synthesis and Photophysical Properties of Bispsoralen Derivatives Linked by a Bisamide-polymethylene Chain

  • Yoo, Dong-Jin
    • Bulletin of the Korean Chemical Society
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    • 제28권10호
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    • pp.1715-1719
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    • 2007
  • New bispsoralen derivatives 5-10, 8-MOP-NHCO(CH2)nCONH-8-MOP (BPSBA-Cn, n = 0, 1, 2, 3, 4 and 5) in which 5 position of an 8-methoxypsoralen (8-MOP) is linked by various lengths of bisamide polymethylene chain to 5 position of the other 8-MOP, have been synthesized by the amidation of 5-amino-8-methoxypsoralen (12) with α,ω-alkanoyl dichloride. Photophysical properties of their derivatives including π?π stacking interaction between the two aromatic moieties were investigated by UV absorption and fluorescence emission spectra. Efficient ring-ring stacking interactions have been observed in BPSBA-C4 (9) from the percent hypochromism (%H) of the models.

Measurement of Transient Electric Field Emission from a 245 kV Gas Insulated Substation Model during Switching

  • Rao, M. Mohana;Thomas, M. Joy;Singh, B.P.
    • Journal of Electrical Engineering and Technology
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    • 제2권3호
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    • pp.306-311
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    • 2007
  • The transient fields generated during switching operations in a Gas Insulated Substation (GIS) are associated with high frequency components in the order of few tens of MHz. These transient fields leak into the external environment of the gas-insulated equipment and can interfere with the nearby electronics. Measurements of the transient fields are thus required to characterise the interference caused by switching phenomena in such substations. In view of the above, E-field emission measurement during a switching operation has been carried out for a 245 kV GIS model, using a resonant dipole antenna and D-dot sensor. The characteristics of the E-fields i.e., frequency spectra and their levels have been analysed and are reported in the paper. Suitability of the measurements has been confirmed by comparing frequency spectra of the measured and computed transient fields.

Characteristics of Elastic Waves Generated by Fatigue Crack Penetration and Growth in an Aluminum Plate

  • Ahn, Seok-Hwan;Nam, Ki-Woo
    • Journal of Mechanical Science and Technology
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    • 제17권11호
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    • pp.1599-1607
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    • 2003
  • The characteristics of elastic waves emanated from crack initiation in 6061 aluminum alloy subjected to fatigue loading are investigated through experiments. The objective of the study is to determine the differences in the properties of the signals generated from fatigue test and also to examine if the sources of the waves could be identified from the temporal and spectral characteristics of the acoustic emission (AE) waveforms. The signals are recorded using nonresonant, flat, broadband transducers attached to the surface of the alloy specimens. The time dependence and power spectra of the signals recorded during the tests were examined and classified according to their special features. Six distinct types of signals were observed. The waveforms and their power spectra were found to be dependent on the crack propagation stage and the type of fracture associated with the signals. The potential application of the approach in health monitoring of structural components using a network of surface mounted broadband sensors is discussed.

PROTROPIC AND PHOTOPHYSICAL PROPERTIES OF 7-HYDROXYQUINOLINE IN X AND Y ZEOLITES

  • Park, Ji-Ho;Jang, Du-Jeon
    • Journal of Photoscience
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    • 제1권1호
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    • pp.25-29
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    • 1994
  • Diffuse reflectance and emission spectra of 7-hydroxyquinoline intercalated in the supercage of X and Y zeolites are compared with the absorption and emission spectra of aqueous 7-hydroxyquinoline solutions at various pH to understand protropic and photophysical properties of 7-hydroxyquinoline in zeolite microenvironments. Predominance of zwitterionic spedes with significant existences of the other three protropic equilibrium species, normal, protonated and deprotonated species in zeolite samples indicates that the major fraction of the molecules interact with strong acid and base sites of zeolite at an adsorbed position. Observed zeolite pHs of near neutrality are established by a near balance in numbers of many strong acid and base sites rather than by'small numbers or weakness of acid and base sites. Excitations of nonzwitterionic species such as deprotonated species also give prevailing zwitterionic fluorescence, indicating that excited and ground proton transfer cycles of protropic species can be triggered by photons in organized zeolite media as well as in water.

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