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http://dx.doi.org/10.5012/bkcs.2007.28.10.1715

Synthesis and Photophysical Properties of Bispsoralen Derivatives Linked by a Bisamide-polymethylene Chain  

Yoo, Dong-Jin (Department of Chemistry, Seonam University)
Publication Information
Bulletin of the Korean Chemical Society / v.28, no.10, 2007 , pp. 1715-1719 More about this Journal
Abstract
New bispsoralen derivatives 5-10, 8-MOP-NHCO(CH2)nCONH-8-MOP (BPSBA-Cn, n = 0, 1, 2, 3, 4 and 5) in which 5 position of an 8-methoxypsoralen (8-MOP) is linked by various lengths of bisamide polymethylene chain to 5 position of the other 8-MOP, have been synthesized by the amidation of 5-amino-8-methoxypsoralen (12) with α,ω-alkanoyl dichloride. Photophysical properties of their derivatives including π?π stacking interaction between the two aromatic moieties were investigated by UV absorption and fluorescence emission spectra. Efficient ring-ring stacking interactions have been observed in BPSBA-C4 (9) from the percent hypochromism (%H) of the models.
Keywords
8-Methoxypsoralen; Bispsoralen derivatives; UV absorption; Fluorescence emission spectra; Ring-ring stacking interaction;
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