• Title/Summary/Keyword: emission 파장

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고상반응법으로 합성된 SrAl_2O_4:Eu^{+2}, Dy^{+3}$ 장잔광 형광체 분말의 빛발광 특성

  • 김병규;유연태;엄기석;이영기
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.3
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    • pp.315-319
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    • 1999
  • Properties of both photoluminescence and long-phosphorescent for Eu, Dy-codoped $SrAl_2O_4$ powder phosphor synthesized by solid reaction method were investigated by PL instrument. Two intense peaks in the emission spectrum measured at 10 K are observed near 450 nm (2.755 eV) and 520 nm (2.384 eV) wavelength, but at 300 K the main peak of 520 nm wavelength is presented. After the removal of light excitation (360 nm), the excellent after-glow characteristic of the phosphorescence were obtained as a result of low decay tiem, although the after-glow intensities of phosphor vary exponentially with the times.

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Polarization of Stimulated Emission from Optically Pumped AIGaN/GaInN DH (AIGaN/GaInN DH의 광여기 유도방출광의 편광)

  • ;;H. Amano;I. Akasaki
    • Proceedings of the Materials Research Society of Korea Conference
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    • 1994.11a
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    • pp.98-98
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    • 1994
  • 최근 청색반도체레이저의 실현을 위하여 ZnSe가 대표하는 II-Ⅵ족 화합물반도체와 Gan가 대표하는 III족 질화물반도체분야에서 집중적인 연구가 이루어지고 있으며, 아직까지 실용화 되지 않고 있는 청색반도체레이저의 출현에 대하여 많은관심이 모아지고 있다. III족 질화물반도체는 InM(Eg:1.9eV)부터 AIN(Eg: 6.2eV)에 이르기까지 전 조성영역에서 완전한 고용체를 이루며, 실온에서 직접천이형 에너지 대구조를 가지므로 청색 혹은 자외영역에서 동작하는 발광소자를 제작하는데 있어 유망시 되고 있는 소재이다. 특히 GaN와 InN의 3원흔정인 GaInN를 활성층으로 이용하면 그 발전파장을 370nm부터 650nm까지 즉 가시 전 영역으로부터 근 자외영역을 포함할 수 있게 된다. 이 연구에서는 AIGaN/GaInN 이중이종접합(DH) 구조의 고아여기에 의한 유도방출고아의 편광 특성을 조사하였다. 유기금속기상에피텍셜(MOVPE)법으로 성장한 AIGaN/GaInN DH 구조의 표면에 수직으로 펄스 발진 질소레이저(파장: 337.1cm, 주기 10Hz, 폭: 8nsec) 빔을 조사하고 DH구조의 단면으로부터의 유도방출광을 편광기를 통과 시킨 후 스펙트럼을 측정하였다. 입사고아 밀도가 증가함에 따라 약 402nm의 파장에서 유도발출에 의한 가도가 큰 피크가 나타났고, 그 반치폭은 약 18meV이었다. 실온에서 AIGaN/GaInN DH 구조로 부터의 유도방출에 필요한 입사광밀도의 임계치는 약 130㎾/$\textrm{cm}^2$이었다. 한편 편광각이 90$^{\circ}$일때는 발광스펙트럼의 강도가 매우 낮고 단지 자연방출에 의한 스펙트럼만이 나타났다. 편광각이 0$^{\circ}$일 때 최대의 방출광 강도를 나타내었으며, 편광각이 -90$^{\circ}$로 회전함에 따라 발고아강도의 강도가 감소하였다. 이와 같은 결과는 광여기에 의하여 AIGaN/GaInN DH 로 부터의 유도방출광이 GaInN활성층의 단면에 평행한 전기장의방향으로, 즉 TE모드로 선형적으로 편광됨을 의미한다. AIGaN/GanN DH 로 부터의 유도방출이 선형적으로 TE모드로 편광되는 것은 이 구조를 이용한 청색 및 자외선 반도체 레이저다이오드의 실현에 매우 유익한 것이다.

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Detection of fluorescence from soils contaminated with monoaromatic hydrocarbons (유류 오염 토양에서의 단일방향족 탄화수소 농도 측정을 위한 자외선 형광 분석에 관한 연구)

  • 김우진;박재우;이주인
    • Journal of Soil and Groundwater Environment
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    • v.7 no.2
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    • pp.35-44
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    • 2002
  • In order to determine the contamination of the aromatic hydrocarbons in soil, a fiber-optic sensing technique with fluorescence detector has been proposed. Previous researches have shown that the optimal condition for detecting benzene, toluene, ethylbenzene, xylene (BTEX) was 260 nm /290 nm (excitation/emission wavelength). However, broader fluorescence spectra of BTEX-polluted soil sample ranging from 300 nm to 600 nm were observed. Additionally, the intensity of fluorescence increased with increasing BTEX concentration, which was conspicuous in the fine-particle soil, The overall results indicated that the suggested technique could be useful for in-situ monitoring system for subsurface oil-storage tank.

Multihop Connection Establishment Algorithms in Wavelength-Routed Optical Networks (파장분할다중화방식 전광통신망에서 다중홉 연결 알고리즘)

  • 김상완;서승우
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.25 no.7A
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    • pp.951-958
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    • 2000
  • In wavelength-routed all-optical networks, signals are transmitted on a direct optical path, or a lightpath, in a single-hop manner without opto-electronic/electro-optic(OE/EO) conversion at intermediate nodes. However, due to the physical constraints of optical elements such as ASE noise and crosstalk signals can be degraded un a long path. To establish a connection under such impairments, the optical signal may need to be regenerated at intermediate nodes, dividing a lightpath into two or more fragments. However, since signal regeneration at intermediate nodes requires additional network resources, the selection of these nodes should be made carefully to minimize blocking of other lightpaths. In this paper, we deal with the problem of establishing a lightpath in a multihop manner under physical constraints. We provide both minimal-cost and heuristic algorithms for locating signal regeneration nodes(SRNs). For a minimal-cost algorithm, we formulate the problem using dynamic programming(DP) such that blocking of other lightpaths due to the lack of transmitters/receivers(TXs/RXs) and wavelengths is minimized throughout the network.

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Fabrication of an Optical Fiber Amplifier Using Long-period Fiber Gratings Formed by Periodically Arrayed Metal Wire (금속선의 주기적 배열로 유도된 장주기 격자를 이용한 이득 평탄화된 광섬유 증폭기 제작)

  • Sohn, Kyung-Rak;Hwang, Woong;Shim, June-Hwan
    • Journal of Navigation and Port Research
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    • v.31 no.10
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    • pp.833-837
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    • 2007
  • In this study, we have fabricated a gain flattened erbium-doped optical fiber amplifier. Gain flattening filters were realized by the strain-induced long period fiber gratings, which are made of periodically arrayed metal wires. Using the filter of $550{\mu}m$ period, spontaneous emission amplified at C-band wavelength by a 980nm pumping laser was flattened within 1dB of gain ripple. The performance of the simultaneous multi channel amplification was measured using a fabry-perot laser diode. Amplification ratio was above 20dB. This amplifier can be applied to the long distance transmission system based on a wavelength division multiplexing for boosting an attenuated signal.

Inorganic Nanoparticles for Near-infrared-II Fluorescence Imaging (근적외선-II 형광 이미징을 위한 무기 나노입자)

  • Park, Yong Il
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.17-27
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    • 2022
  • Fluorescence imaging is widely used to image cells or small animals due to its high temporal and spatial resolution. Because conventional fluorescence imaging uses visible light, the penetration depth of light within the tissue is low, phototoxicity may occur due to visible light, and the detection sensitivity is lowered due to interference by background autofluorescence. In order to overcome this limitation, long-wavelength light should be used, and fluorescence imaging using near-infrared-I (NIR-I) in the region of 700~900 nm has been developed. To further improve imaging quality, researchers are interested in using a longer wavelength light, near-infrared-II (NIR-II) ranging from 1000 to 1700 nm. In the NIR-II region, light scattering is further minimized, and the penetration depth of light in the tissue is improved up to about 10 mm, and autofluorescence of the tissue is reduced, enabling high sensitivity and resolution fluorescence imaging. In this review, among various NIR-II fluorescence imaging probes, inorganic nanoparticle-based probes with excellent photostability and easily tunable emission wavelength were described, focusing on single-walled carbon nanotubes, quantum dots, and lanthanide nanoparticles.

Photoluminescence properties of $CaS_{1-x}Se_x:Eu$ phosphors ($CaS_{1-x}Se_x:Eu$ 형광체의 발광 특성)

  • Ryu, Eun-Kyoung;Huh, Young-Duk
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.5
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    • pp.204-209
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    • 2007
  • We synthesized a series of $CaS_{1-x}Se_x:Eu$ red-emitting phosphors for application in phosphor-converted three-band white light emitting diode(LED). The photoluminescence and structural properties of $CaS_{1-x}Se_x:Eu$ were examined. The $CaS_{1-x}Se_x:Eu$ phosphors have a strong absorption at 455 nm, which is the emission wavelength of a blue LED. CaS:Eu has a red omission peak at 651 nm due to the $4f^65d^1(T_{2g}){\rightarrow}4f^7(^8S_{7/2})$ transition of the $Eu^{2+}$. The emission peak of $CaS_{1-x}Se_x:Eu$ is shifted from 651 to 598 nm with increasing Se content. $CaS_{1-x}Se_x:Eu$ can be used as wavelength-tunable red-emitting phosphors pumped by a blue LED. We also fabricated a three-band white LED by doping $SrGa_2S_4:Eu$ and $CaS_{0.50}Se_{0.50}:Eu$ phosphors onto a blue LED chip.

Influence of InGaAs Capping Layers on the Properties of InAs/GaAs Quantum Dots (InAs/GaAs 양자점의 발광특성에 대한 InGaAs 캡층의 영향)

  • Kwon, Se Ra;Ryu, Mee-Yi;Song, Jin Dong
    • Journal of the Korean Vacuum Society
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    • v.21 no.6
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    • pp.342-347
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    • 2012
  • The optical properties of InAs quantum dots (QDs) grown on a GaAs substrates by migration enhanced molecular beam epitaxy method have been investigated by using photoluminescence (PL) and time-resolved PL measurements. The luminescence properties of InAs/GaAs QDs have been studied as functions of temperature, excitation laser power, and emission wavelength. The PL peak of InAs QDs capped with $In_{0.15}Ga_{0.85}As$ layer (QD2) measured at 10 K is redshifted about 80 nm compared with that of InAs QDs with no InGaAs layer (QD1). This redshift of QD2 is attributed to the increase in dot size due to the diffusion of In from the InGaAs capping layer. The PL decay times of QD1 and QD2 at 10 K are 1.12 and 1.00 ns taken at the PL peak of 1,117 and 1,197 nm, respectively. The reduced decay time of QD2 can be explained by the improved carrier confinement and enhanced wave function overlap due to increased QD size. The PL decay times for both QD1 and QD2 are independent on the emission wavelength, indicating the uniformity of dot size.

The Role of Acid in the Synthesis of Red-Emitting Carbon Dots (장파장 형광 탄소 양자점 제조에 있어서 산의 역할에 대한 연구)

  • Yun, Sohee;Lee, Jinhee;Choi, Jin-sil
    • Applied Chemistry for Engineering
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    • v.33 no.3
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    • pp.309-314
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    • 2022
  • Carbon dots (CDs) are few nanometer-sized carbon-based nanoparticles and emerging candidate materials in various fields such as biosensors and bioimaging due to their excellent optical properties and high biocompatibility. However, most CDs, emitting blue light, have limited their application in biomedical fields due to the low penetration of short-wavelength lights into the biological system. Therefore, there has been enormous need to develop long-wavelength emitting CDs. In this study, red-emitting CDs were successfully synthesized through the hydrothermal reaction of p-phenylenediamine with hydrochloric acid. In addition, the effect of the amount of hydrochloric acid on the formation of carbon dots, resulting in the variation of the chemical structures of CDs, were investigated, which was confirmed with the intensive structural analyses using infrared and X-ray photoelectron spectroscopy. It was found that the chemical structure of CDs governed their optical properties and quantum yield. Therefore, this study provides an insight into the role of acid in forming red-emitting CDs as the optimal probe for biomedical application.

Luminescence Characteristics of Sr3MgSi2O8:Eu Blue Phosphor for Light Emitting Diodes (LED용 Sr3MgSi2O8:Eu청색 형광체의 발광특성)

  • 최경재;박정규;김경남;김창해;김호건
    • Journal of the Korean Ceramic Society
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    • v.41 no.8
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    • pp.573-577
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    • 2004
  • We have synthesized a Eu$^{2+}$-activated Sr$_3$MgSi$_2$ $O_{8}$ blue phosphor and investigated an attempt to develop blue LEDs by combining it with a InGaN blue LED chip (Len=405 nm). The InGaN-based Sr$_3$MgSi$_2$ $O_{8}$:Eu LED Lamp shows two bands at 405 nm and 460 nm. The 405 nm emission band is due to a radiative recombination from a InGaN active layer. This 405 nm emission was used as an optical transition of the Sr$_3$MgSi$_2$ $O_{8}$:Eu phosphor. The 460 m emission band is ascribed to a radiative recombination of Eu$^{2+}$ impurity ions in the Sr$_3$MgSi$_2$ $O_{8}$ host matrix. As a consequence of a preparation of W blue LED Lamp using the Sr$_3$MgSi$_2$ $O_{8}$:Eu blue phosphor, the highest luminescence efficiency was obtained at the ration of epoxy/blue phosphor(1/0,202). At this time, the CIE chromaticity was x=0.1417 and y=0.0683.