• Corrosion Science and Technology
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• 제22권4호
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• pp.221-231
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• 2023

Interest in aluminum alloys for the hydrogen valves of fuel cell electric vehicles (FCEVs) is growing due to the reduction in fuel efficiency by the high weight. However, when an aluminum alloy is used, deterioration in mechanical characteristics caused by hydrogen embrittlement and wear is regarded as a problem. In this investigation, the aluminum alloy used to prevent hydrogen embrittlement was subjected to surface treatments by performing hard anodizing and plasma ion nitriding processes. The hard anodized Al alloy exhibited brittleness in which the mechanical characteristics rapidly deteriorated due to porosity and defects of surface, resulting in a decrease in the ultimate tensile strength and modulus of toughness by 15.58 and 42.51%, respectively, as the hydrogen charging time increased from 0 to 96 hours. In contrast, no distinct nitriding layer in the plasma ion-nitrided Al alloy was observed due to oxide film formation and processing conditions. However, compared to 0 and 96 hours of hydrogen charging time, the ultimate tensile strength and modulus of toughness decreased by 7.54 and 13.32%, respectively, presenting excellent resistance to hydrogen embrittlement.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1995년도 춘계학술발표회논문집(2)
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• pp.635-640
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• 1995

Two techniques for the verification of the phase separation in ferrite phase of primary pressure bounary component materials, the primary cause of thermal aging embrittlement, are presented. Data base of room-temperature Charpy V-notch impact energy during reactor service was estimated as a measure of the degree of embrittlement. The serviceable period of CF-3 and CF-8 alloys as the primary pressure boundary components may be acceptably extended for 60 years of lifetime. However, the integrity of CF-8M alloys can be degraded seriously after several years of service in the nuclear reactor.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 추계학술대회
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• pp.118-123
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• 2004

Cast austenitic stainless steel have been widely used for primary coolant piping in light water reactors. This material is subject to thermal embrittlement at reactor operating temperature. CF-8M and CF-8A cast austenitic stainless steel is used for several components, such as primary coolant piping, elbow, pump casing, and valve bodies in light water reactors. Thermal embrittlement results in spinodal decomposition of delta-ferrite leading to decreased fracture toughness. In this study, the specimens were prepared using an accelerated aging method. The measurement of ferrite content, Charpy impact test and J-R test were performed to verify the predicting equation for aged material properties. In case of above 25% ferrite content, predicted result of J-R curve might be non-conservative.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 춘계학술대회
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• pp.78-83
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• 2003

The aim of this study is to investigate the effect of hydrogen embrittlement od Zr-2.5Nb CANDU pressure tube. The test were performed at three hydrogen contents for transverse tensile and CCT specimens while the test temperatures were changed (RT to 300$^{\circ}C$). The specimens were directly machined from the tube retaining original curvature using electric discharge machine. Both the transverse tensile and the fracture toughness tests showed the hydrogen embrittlement clearly at RT but this phenomenon was disappeared while the test temperature arrived over 250$^{\circ}C$. From the fracture toughness test, it was found that fracture toughness dJ/da was increased up to 200$^{\circ}C$ and then decreased.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회A
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• pp.244-249
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• 2008

It happened a failure on special bolt which supported main landing gear actuator up-lock rod of 00 aircraft. Fracture was occurred at end of center drilled hole and thread machined on bolt. Metallographic, fractographic, and other characteristics of embrittlement analysis and experiments carried out on the failed bolt to find out the reason. Bolt surface was cadmium electroplated(EP) to give lubrication and provide excellent corrosion resistance. Resultly, Bolt was failed due to cadmium embrittlement occurred during baking treatment as well as center drilled hole. for the failure that are relevant to failure analysis and prevention. For their successful functional application, cadmium EP bolts require proper and adequate baking treatment after electroplating, and is complete with no center drilled hole

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.1192-1197
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• 2003

The aim of this study is to investigate the hydride embrittlement when the LBB evaluation is carried out for the integrity of PHWR Pressure Tubes. The transverse tensile and CCT tests were performed at three hydrogen concentrations while the test temperatures were changed (RT to $300^{\circ}C$). The specimens were directly machined from the pressure tube retaining original curvature. Both the transverse tensile and the fracture toughness tests showed the hydrogen embrittlement clearly at RT but this phenomenon was disappeared while the test temperature arrived over $250^{\circ}C$. Using the DHC test results, the CCL and LBB time were calculated and compared. The hydride embrittlement behavior at the LBB evaluation was definitely showed.

• Journal of Welding and Joining
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• 제8권3호
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• pp.39-52
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• 1990

The research is to insure the soundness of the stainless steel overlaid weld metal(21/4Cr-IMo steel + SUS 309L) for a pressure vessel application. Detail studies were conducted for the PWHT influence on the micrstructure and intergranular corrosion characteristics of the overlaid weld metal as well as initiation of hydrogen embrittlement crack(or Disbonding) when welded metal are exposed to the hydrogen atmosphere. Hydrogen was experimentally charged to the overlaid weld metal in order to study PWHT effect on the susceptibility of hydrogen embrittlement crack. The results of this research are as follows: 1. At the bond region, austenite grain of the stainless steel side became coarsed and Cr23C6 type carbide was precipitated at the coarsed austenitic grain boundaries. Intergranular Corrosion width(by Straiss test) increased with increasing PWHT temperature and PWHT time.

• Corrosion Science and Technology
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• 제15권5호
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• pp.237-244
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• 2016

2205 duplex stainless steels have been used for the construction of the marine environment, because of their excellent corrosion resistance and high strength. However, the resistance to hydrogen embrittlement (HE) may be less than that of 316L austenitic stainless steel. The reason why 316L stainless steels have better resistance to HE is associated with crystal structure (FCC, face centered cubic) and the higher stacking faults energy than 2205 duplex stainless steels. Furthermore 2205 stainless steels with or without tungsten were also examined in terms of HE. 2205 stainless steels containing tungsten is less resistible to HE. It is because dislocation tangle was formed in 2205 duplex stainless steels. Slow strain-rate tensile test (SSRT) was conducted to measure the resistance to HE under the cathodic applied potential. Hydrogen embrittlement index (HEI) was used to evaluate HE resistance through the quantitative calculation.

• Nuclear Engineering and Technology
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• 제53권8호
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• pp.2610-2615
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• 2021

The prediction of irradiation-induced transition temperature shift for RPV steels is an important method for long term operation of nuclear power plant. Based on the irradiation embrittlement data, an irradiation-induced transition temperature shift prediction model is developed with machine learning method XGBoost. Then the residual, standard deviation and predicted value vs. measured value analysis are conducted to analyze the accuracy of this model. At last, Cu content threshold and saturation values analysis, temperature dependence, Ni/Cu dependence and flux effect are given to verify the reliability. Those results show that the prediction model developed with XGBoost has high accuracy for predicting the irradiation embrittlement trend of RPV steel. The prediction results are consistent with the current understanding of RPV embrittlement mechanism.

• 한국수소및신에너지학회논문집
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• 제35권2호
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• pp.216-229
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• 2024

Pipeline steels for hydrogen transmission may cause hydrogen embrittlement due to absorption and diffusion of hydrogen through metals. Hydrogen pipes exhibited similar mechanical properties to atmospheric conditions in terms of tensile and yield strength in a hydrogen atmosphere. This paper aims to provide relevant information regarding hydrogen embrittlement in hydrogen transmission pipeline.