• Title/Summary/Keyword: elucidation

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Structural Elucidation of Carotenoids in Penaeus orientalis Shells (Penaeus orientalis 껍질로부터 분리 정제한 Carotenoids의 구조 결정)

  • 김재웅;김동희;이서구
    • The Korean Journal of Food And Nutrition
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    • v.13 no.3
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    • pp.269-272
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    • 2000
  • Penaeus orientalis 껍질에서 6종류의 carotenoids가 분리정제되었다. $\beta$-carotene(3.1%), doradexanhinester(6.1%), astaxanthin diester(54.8%), zeaxan-thin monoester(7.9%), astaxanthin monoester(12.4%) 그리고 astaxanthin(5.7%)의 함량과 구조들은 UV/VIS.IR $^1$H0NMR. MS 스펙트라와 검화반응, 아세탈화반응, 알릴릭그룹,에폭시 반응 그리고 환원반응을이용하여 결정되었다. Carotenoids와 에스테르 결합된 지방산들은 주로 $C_{18:1}$, $C_{16:0}$, $C_{16:1}$ 이고 나머지 지방산들도 소량 함유되었다.되었다.

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Sesquiterpenoids from the Rhizome of Curcuma zedoaria

  • Hong, Chai-Hee;Kim, Young-heem;Lee, Sang-Kook
    • Archives of Pharmacal Research
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    • v.24 no.5
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    • pp.424-426
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    • 2001
  • In the course of searching for biologically active sesquiterpenoids from Curcuma genus, two sesquiterpenoids were isolated from the rhizome of Curcuma zedoaria (Zingiberaceae). Their structures were identified as ar-turmerone (1) and $\beta$-turmerone (2). The structure elucidation of compounds 1 and 2 was carried out by comparison of their physical and spectral data with previously reported values.

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$^{13}C-Nuclear$ Magnetic Resonance of Phenolic Compounds (II) -A Study on the Chemical Shifts of the Phenolic Coumarine Derivatives- (Phenol성(性) 화합물(化合物)의 $^{13}C$-핵자기(核磁氣) 공명(共鳴)(II) -Phenol 성(性) Coumarine 유도체(誘導體)의 Chemical Shift에 관(關)하여-)

  • Ahn, Byung-Zun
    • Korean Journal of Pharmacognosy
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    • v.8 no.1
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    • pp.23-29
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    • 1977
  • The $^{13}C-chemical\;shifts$ of the phenolic coumarine derivatives, aesculetin, daphnetin and herniarin were studied on the basis of my previous report. All spectral data found in this report could be utilized to the structure elucidation of the unknown phenolic coumarine derivatives and other phenolic compounds. In addition, it is suggested that a long range coupling may occur in the following structure as represented by arrow.

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Isolation and Structure Elucidation of Flavonoid Glycosides from Lindera obtusiloba BL. (생강나무에서 분리한 Flavonoid 배당체의 화학구조)

  • 박종철;유영법;이종호
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.25 no.1
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    • pp.76-79
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    • 1996
  • 생강나무 (Libdera obtusiloba BL.)의 페놀성 화합물들을 분리하기 위하여 잎고 줄기의 MeOH 엑스로부터 계통 분획한 EtOAc 분획물은 silica gel column chro-matography로 분리하여 2종의 화합물을 얻었다. IR, UV,$^1H-NMR$, $^13C-NMR$ 등의 분석을 행하여 화학구조를 밝힌 결과 이들 화합물의 화학구조는 잎에서 $quer-cetin-3-O-\alpha-L-rhamnopyranoside(quercitrin),$ 줄기에서는 quercetin $3-O-\beta-D-galactoyranoside(hyperoside)로$ 각각 결정하였다. 이 화합물들은 생강나무에서 처음으로 분리하였다.

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Chemical Constituents of Pulicaria gnaphalodes

  • Ali, Muhammad Shaiq;Jahangir, Muhammad;Saleem, Muhammad;Ahmad, Viqar Uddin
    • Natural Product Sciences
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    • v.5 no.3
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    • pp.134-137
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    • 1999
  • The chloroform extract of Pulicaria gnaphalodes yielded flavonoids (1-2), sesquiterpenoid (3), sterol (4), benzoic acid derivative (5) and fatty acids (6-7). Their structures were elucidated with the aid of NMR spectroscopy. The described compounds have not been reported so far from this source.

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Cytotoxic Quassinoids from Simaba cedron

  • Hitotsuyanagi, Yukio
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1998.11a
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    • pp.52-55
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    • 1998
  • During a survey of new antitumor substances from higher plants, we have found that the crude extract of Simaba cedron Planchon (Simaroubaceae) showed cytotoxic activity (IC$\sub$50/ 0.7 $\mu\textrm{g}$/mL) against P388 leukemia cells. Activity-guided chromatographic purification using P388 cells led to the isolation of five novel quassinoids, cedronolactones A-E (1-5) and nine known quassinoids, simalikalactone D (6), chaparrinon (7), chaparrin (8), glaucarubolone (9), glaucarubol (10), samaderine Z (11), guanepolide (12), ailanquassin A (13), and polyandrol (14). In this seminar, the structural elucidation of 1-5 and the cytotoxic activity of the isolated compounds are discussed.

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NMR PEAK ASSIGNMENT FOR THE ELUCIDATION OF THE SOLUTION STRUCTURE OF T4 ENDONUCLEASE V

  • Im, Hoo-Kang;Jee, Jun-Goo;Yu, Jun-Suk;Lee, Bong-Jin
    • Proceedings of the Korean Biophysical Society Conference
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    • 1996.07a
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    • pp.18-18
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    • 1996
  • Bacteriophage T4 endonuclease V initiates the repair of ultraviolet (UV)-induced pyrimidine dimer photoproducts in duplex DNA. The mechanism of DNA strand cleavage involves four sequential steps: linear diffusion along dsDNA, pyrimidine dimer-specific binding, pyrimidine dimer-DNA glycosylase activity, and AP lyase activity. (omitted)

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