• Title/Summary/Keyword: elemental analysis

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Synthesis of Blue-green Naphthoxy, Chloro Derivative Zinc-phthalocyanines with LCD Requirements

  • Kumar, Rangaraju Satish;Min, Kyeong Su;Son, Young-A
    • Textile Coloration and Finishing
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    • v.30 no.3
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    • pp.159-167
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    • 2018
  • Here we designed and synthesized new zinc phthalocyanines and structures were fully confirmed by spectral and elemental analysis. All phthalocyanines have a very good solubility in industrial solvents like chloroform, dichloromethane, dimethyl sulfoxide, N,N-dimethyl formamide, propylene glycol monomethyl ether acetate (PGMEA), acetone, tetrahydrofuran and acetonitrile. UV-Visible absorption and transmittance in PGMEA showed that these dyes have suitable spectral properties for LCD color filters. By Triton X surfactant study, we confirmed that these dyes are not showing any aggregation in PGMEA. We dissolved the all phthalocyanines in LCD fabricating solvent (PGMEA), and all phthalocyanines showed more than 8 wt% of solubility. Finally, all of these results concluded that PCK1, PCK2 and PCK3 are fit for LCD green color filter.

A study on rib-web shaped ring forging using UBET (UBET를 이용한 리브-웨브형 링 단조에 관한 연구)

  • Kim, Y.H.;Bae, W.B.;Nam, K.H.
    • Journal of the Korean Society for Precision Engineering
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    • v.11 no.5
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    • pp.134-142
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    • 1994
  • An upper bound elemental technique (UBET) is applied to predict variations of neutral plane and optimal position of the initial billet for rib-wep shaped ring forging. In the analysis, the neutral plane position and velocity fields are determined by minimizing the total power consump- tion with respect to chosen parameters. The degree of die-cavity filling by initial billet-position and the variations of neutral plane by friction condition are investigated. Experiments have been carried out with pure plasticine billets at room temperature. The theoretical predictions of the forging load and the flow pattern are in good agrement with the experimental results.

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Upper Bound Analysis for Near-net Shape Forging of a Crown Gear Form

  • Lee, Seung-Dong;Kim, Won-Il;Kim, Yohng-Jo
    • International Journal of Precision Engineering and Manufacturing
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    • v.1 no.2
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    • pp.94-104
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    • 2000
  • A kinematically admissible velocity field for near-net shape forging of a crown gear form is proposed. This takes into account the profiled shape of the teeth chosen by approximating these kinematically as radially straight taper teeth, (rectangular and trapezoidal teeth). The upper bound to the forging load, the relative forging pressure and the deformed configurations, with both the initially solid circular cylindrical and hollow billets, are predicted using the velocity field at varying incremental punch movements considering differing frictional factors. These and other results are given and commented upon.

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Effects of carbonization temperature on pore development in polyacrylonitrile-based activated carbon nanofibers

  • Lee, Hye-Min;An, Kay-Hyeok;Kim, Byung-Joo
    • Carbon letters
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    • v.15 no.2
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    • pp.146-150
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    • 2014
  • In this work, activated carbon nanofiber (ACNF) electrodes with high double-layer capacitance and good rate capability were prepared from polyacrylonitrile nanofibers by optimizing the carbonization temperature prior to $H_2O$ activation. The morphology of the ACNFs was observed by scanning electron microscopy. The elemental composition was determined by analysis of X-ray photoelectron spectroscopy. $N_2$-adsorption-isotherm characteristics at 77 K were confirmed by Brunauer-Emmett-Teller and Dubinin-Radushkevich equations. ACNFs processed at different carbonization temperatures were applied as electrodes for electrical double-layer capacitors. The experimental results showed that the surface morphology of the CNFs was not significantly changed after the carbonization process, although their diameters gradually decreased with increasing carbonization temperature. It was found that the carbon content in the CNFs could easily be tailored by controlling the carbonization temperature. The specific capacitance of the prepared ACNFs was enhanced by increasing the carbonization temperature.

A Study on Roll Wear in the Roll Forming Process (롤포밍 공정에서의 롤 마모에 관한 연구)

  • Kang, Byung-Seok;Kim, Nak-Soo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.11
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    • pp.1881-1888
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    • 2003
  • This study show a numerical method to predict roll wear in the roll forming process. Archard's wear model was reformulated in an elemental form to predict volume of roll wear and then wear depth on the roll was calculated using the results of finite element analysis. Abrasive wear occurs at contact area in the roll forming process and the results of simulation are compared with experimental data in production line. The wear simulation approach with 3-D FEM program for roll forming process, SHAPE-RF is in good agreement with it in tendency.

Study on synthesis of CuPc derivative and preparation of its Langmuir- Blodgett Films. (($NO_{2}$가스센서용 phthalocyanine 유도체의 합성과 LB막의 제작 및 특성에 관한 연구)

  • Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.11 no.2
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    • pp.147-150
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    • 1994
  • Ultra thin films of HDSM-CuPc(Tetra-3-hexadecylsulphamoylcopperphthalocya-nine) were formed on various substrates by Langmuir-Blodgett method, where HDSM-CuPc was synthesized by attaching long-chain alkylamine(hexa-decylamine) to CuPc. The reaction product was identified with FT- IR, UV-visible absorption spectroscopies, elemental analysis and thin layer chromatography. The formation of ultrathin films of HDSM-CuPc was confirmed by FT-IR and UV-visible spectroscpies.

An Analysis on Optimal Type and Core Technologies for Construction Automation System (건설 자동화 시스템의 적정 유형 및 핵심요소기술 분석)

  • Lee, Jin Woong;Cho, Kyuman;Kim, Taehoon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.10a
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    • pp.140-141
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    • 2016
  • Dynamic nature and diverse requirements on construction sites make the automation technology harder to be employed actively. In this study, we analyzed optimal type of automation system and importance of core technologies for developing efficient construction automation system on 11 construction operations. As a result, it showed that man-machine cooperation system may be the most suitable for most operations, while autonomous robot will be best suited in hard working environment such as maintenance of exterior wall. In elemental technology, ease and accuracy of control and operation showed higher priority than others regardless of automation system type. These findings will provide useful information for developing the construction automation system.

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Synthesis and Microstructural Characterization of Cu-C Composite Metal Powder by Mechanical Alloying (기계적 합금화 방법에 의한 Cu-C계 복합금속분말의 제조 및 미세구조 제어 특성)

  • 이광민
    • Journal of Powder Materials
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    • v.4 no.1
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    • pp.42-47
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    • 1997
  • It was investigated whether mechanical alloying (MA) processing could be more effective to the formation of metallic composite powder in Cu-C system. Elemental powder mixtures of Cu-70vo1.%C were mechanically alloyed with an attritor in an argon atmosphere and microstructural evolution was examined by X-ray diffraction analysis, scanning electron microscopy and transmission electron microscopy. It has been found that even with the high volume fraction of immiscible graphite in Cu-C system, the refinement with a few ten nanometer size as well as the highly uniform distribution of copper phases have been achieved by the MA processing.

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Study on Synthesis of Metal Complex and Preparation of Its Thin Films for Organic Electroluminescent Device (유기 발광 소자를 위한 금속 착물의 합성 및 그 박막 제조에 관한 연구)

  • Hwang, Jang-Hwan;Kim, Young-Kwan;Kim, Jung-Su;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.14 no.2
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    • pp.81-85
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    • 1997
  • Tris(8-hydroxyquinoline)-aluminum complex($AlQ_3$) having greenish luminescent characteristics was synthesized and it was confirmed with UV-Vis absorption spectroscopy, elemental analysis, and FT-IR spectroscopy that $AlQ_3$ was successfully synthesized. Thin films of $AlQ_3$ having multilayer structure were prepared by spin coating method and vacuum evaporation technique. Photopluminescent characteristics of these films were investigated by Luminescence spectroscopy and Current-Voltage(I-V) characteristics of these films were also investigated.

토양-휴민의 물리화학적 특성 및 PAHs의 결합 특성 연구

  • Im Dong-Min;Sin Hyeon-Sang
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.16-19
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    • 2006
  • Humin is the insoluble fraction of humic materials and play an important roles in the irreversible sorption of hydrophobic organic contaminants onto soil particles. However, there have been limited knowledge about the sorption and chemical properties of humin due to the difficulties in its separation from the inorganic matrix(mainly clays and oxides). In this study, do-ashed humin was isolated from a soil sample after removing free lipid and alkali-soluble humic fractions followed by dissolution of mineral matrix with 2% HF, and characterized by elemental analysis, C-13 NMR spectroscopic method. Sorption behavior of 1-naphthol with humin was also investigated from aqueous solution. C-13 NMR spectra indicate that humin molecules are mainly made up of aliphatic carbon including carbohydrate, methylene chain etc.. Sorption intensity for 1-naphthol was increased as organic carbon content of humin increased and log Koc values for the 1-naphthol sorption were determined to be ${\sim}3.12$

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