• Title/Summary/Keyword: electrostatic spinning

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Preparation and Characterization of PAN-based Web of Carbon Nanofibers by Electrostatic Spinning

  • Kim, Chan;Yang, Kap-Seung
    • Carbon letters
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    • v.3 no.4
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    • pp.210-218
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    • 2002
  • Electrostatic spinnings were performed with the solutions of PAN/DMF to be nanofiber webs. The diameter of the fibers ranged from 200 nm to 1000 nm depending on the PAN concentration and on the applied DC voltage. The nanofibers were oxidatively stabilized and subsequently carbonized up to $1000^{\circ}C$ with carbonization yield of 40%. The bulk electric conductivity of the carbonized web increased form $6.8{\times}10^{-3}S/cm$ to 1.96 S/cm while the carbonizaton temperature increased from $700^{\circ}C$ to $1000^{\circ}C$.

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Physical Properties and Dyeability of Wool/Polyester Spun Blend Yarn and Its Fabrics Using Air Blowing and Electrostatic Spinning Technology(Cyclone) (공기분사 전기방적 기술(Cyclone)을 이용한 Wool/Polyester 혼섬사 소재의 물성 및 염색성)

  • Kim, Mikyung;Kim, Dongkwon;Jeong, Jaeseok;Jang, Bongsik
    • Textile Coloration and Finishing
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    • v.28 no.2
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    • pp.77-91
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    • 2016
  • Recently, the spun blend yarns with staple fibers and filaments are being developed in the spinning process using an air blowing and electrostatic spinning technology(cyclone) in order to enhance the soft feeling and the fine count spun blend yarn manufacturing competitiveness. In this study, the appropriate separation condition of polyester multifilament was examined according to the treatment condition of conductive agents and voltage on polyester multifilament in the newly developed cyclone spinning process. And it was investigated the physical properties and dyeability of the cyclone wool/polyester spun blend yarns and its wool composite fabrics in comparison with existing sirofil wool/polyester spun blend yarn and its fabrics. As the result, it is determined that the newly developed cyclone wool/polyester spun blend yarn applied fabrics has a superior quality level in terms of practicality.

Spin-coated ultrathin multilayers and their micropatterning using microfluidic channels

  • Hongseok Jang;Kim, Sangcheol;Jinhan Cho;Kookheon Char
    • Korea-Australia Rheology Journal
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    • v.15 no.1
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    • pp.1-7
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    • 2003
  • A new method is introduced to build up organic/organic multilayer films composed of cationic poly(allylamine hydrochloride) (PAH) and negatively charged poly (sodium 4-styrenesulfonate) (PSS) using the spinning process. The adsorption process is governed by both the viscous force induced by fast solvent elimination and the electrostatic interaction between oppositely charged species. On the other hand, the centrifugal and air shear forces applied by the spinning process significantly enhances desorption of weakly bound polyelectrolyte chains and also induce the planarization of the adsorbed polyelectrolyte layer. The film thickness per bilayer adsorbed by the conventional dipping process and the spinning process was found to be about 4 ${\AA}$ and 24 ${\AA}$, respectively. The surface of the multilayer films prepared with the spinning process is quite homogeneous and smooth. Also, a new approach to create multilayer ultrathin films with well-defined micropatterns in a short process time is Introduced. To achieve such micropatterns with high line resolution in organic multilayer films, microfluidic channels were combined with the convective self-assembly process employing both hydrogen bonding and electrostatic intermolecular interactions. The channels were initially filled with polymer solution by capillary pressure and the residual solution was then removed by the .spinning process.

Characteristics of Static Electrification on Insulation Oil Aging (변압기 절연유의 열화에 따른 대전특성)

  • Kweon, Dong-Jin;Kim, Han-Sang;Chong, Yong-Ki;Kim, Kyoung-Wha;Kim, Du-Seok;Kwak, Hee-Ro;Park, Tong-Wha
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1615-1618
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    • 1994
  • This paper studied the streaming electrification of the U.H.V. transformer with the spinning cylinder system, and compared and analyzed it with the conventional forced flowing system which uses a pump or gas for oil flowing. Also, accumulated surface voltage in its electrified material was measured with the electrostatic voltmeter, and the effect of insulation oil aging was measured. As results, in spinning cylinder system, characteristics of the streaming electrification to its rotational speed and oil temperature are same tendency as those of tile forced flowing system and it showed the spinning cylinder system is useful to study the streaming electrification. And, aging of insulation oil increases the electricity of streaming electrification at initial stage of aging.

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Aerosol filtration and electrostatic properties of electrospun nanofiber air filters (전기방사 나노섬유 에어필터의 정전기적 특성 및 에어로졸 여과특성)

  • Park, Hyun-Seol;Lim, Koung Soo
    • Particle and aerosol research
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    • v.5 no.2
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    • pp.71-81
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    • 2009
  • In this study, Nylon 6,6 electrospun (ES) nanofiber filter media were prepared at various spinning conditions. The ES filters tested had no intrinsic electrical charges. The ES filters were triboelectrically charged in the course of filter sample handling, and the charge was drastically decayed in a few hours. On the other hand, the corona charged melt blown filter media showed a permanent electrical charge. The electrical charge state of the ES filters was also examined by comparing collection efficiencies of ES filters for uncharged and charged aerosol particles.

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CNT-BASED FIELD EMISSION X-RAY SOURCE

  • Kim, Hyun Suk;Lee, Choong Hun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.433-433
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    • 2016
  • Carbon nanotubes (CNT) emitter has widely become an attractive mechanism that draws growing interests for cold cathode field emission. CNT yarns have demonstrated its potential as excellent field emitters. It was demonstrated that a small focal spot size was achieved by manipulating some electrical parameters, such as applied bias voltage at the mesh gate, and electrostatic focal lenses, geometrical parameters, such as axial distances of the anode, and the electrostatic focal lens from the cathode assembly, and the dimension of the opening of the electrostatic lens. Electrical-optics software was used to systematically investigate the behavior of the electron beam trajectory when the aforementioned variables were manipulated. The results of the experiment agree with the theoretical simulation results. Each variable has an individual effect on the electron beam focal spot size impinging on the target anode. An optimum condition of the parameters was obtained producing good quality of X-ray images. Also, MWCNT yarn was investigated for field emission characteristics and its contribution in the X-ray generation. The dry spinning method was used to fabricate MWCNT yarn from super MWCNTs, which was fabricated by MW-PECVD. The MWCNT yarn has a significant field emission capability in both diode and the triode X-ray generation structure compared to a MWCNT. The low-voltage-field emission of the MWCNT yarn can be attributed to the field enhancing effect of the yarn due to its shape and the contribution of the high-aspect-ratio nanotubes that protrude from the sides of the yarn. Observations of the use of filters on the development of X-ray images were also demonstrated. The amount of exposure time of the samples to the X-ray was also manipulated. The MWCNT yarn can be a good candidate for use in the low voltage field emission application of X-ray imaging.

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Characterization and Preparation of Electrospun Poly(ethylene terephthalate) (PET) Nonwoven/Polyurethane (PU) composites (전기방사된 PET 부직포/PU 복합체의 제조 및 특성)

  • Kim, Kwan-Woo;Lee, Keun-Hyung;Kim, Chul-Ki;Kim, Hak-Yong;Lee, Sung-Gu;Park, Soo-Jin
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.275-276
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    • 2003
  • Electrostatic spinning or electrospinning has been recently paid attention to prepare ultrafine fiber mats which are composed of diameters in a range of submicrons to nanoscale size[l]. Due to small diameters and porous structure, electrosun fibers have a high specific surface area and expected to use for broad applications, such as filters, membranes, wound dressing materials, artificial blood vessels. a nonwoven fabric, a reiforcement of nanocomposites[2,3], etc. (omitted)

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Studies on Electrostatic Propensity of Fabrics (직물대전성에 관한 연구)

  • 최병희;배도규
    • Journal of Sericultural and Entomological Science
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    • v.27 no.2
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    • pp.54-63
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    • 1985
  • This studies has been carried out how to effect on electrostafic propensity of synthetic fabrics by coating with 0.5% acrylic polymer solution which was previously developed by the author to improve anticrease nature of silk. The work conditions are: (A) Applied synthetic polymer was acrylic polymer 525, developed by the author. (B) Electrostatic voltage for various fabrics were carried out by Korea standard abrasion partner with Korea standard (KS K 0905) cotton, nylon, polyester and the self sample fabric. (C) Applied fabrics for the investigations were carried out by using abrasion partner with Korea standard (KS K 0905) cotton, nylon, polyester and the self sample fabric. (D) Electrostatic propensity investigations were carried out by use of sample as silk, nylon, polyester and acrylic fabrics, seperating before finish or after finish. (E) Washing after the finish or the original fabric was carried out by Korea standard method, KS K 0465. Through the investigations, he happened to find many interesting matters and the obtained results are as followings. 1. Electrostatic voltage for the finished fabrics increased more than their original silk, nylon, acrylic fabrics except polyester fabric. (See Table 5) 2. Electrostatic voltage for the finished polyester against K.S. polyester decreased remarkably than the original fabric test. 3. In spite of no problem on electrostatic propensity of silk, it showed high electrostatic voltage between the same nature fabric abrasion, because silk is very weak against abrasion and because the test method had been developed to be useful for only synthetic fabrics. 4. Electrostatic voltage increased more in case of abrasion between different nature of fabrics than the same nature of fabrics. 5. Electrostatic voltage of each fabric increased by repeat of wash. 6. Many investigation data were followed with Contact Electrification Series Principle, another word, the farther each other located fabric on the series abrasion was, the higher electrostatic voltage. (See Fig. 6) 7. Such investigation gives warning of use on the mix fiber spinning service as far as concern with electrification. 8. It may also call attention for such increase of electrification in case any finishing of silk textile.

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Preparations of PAN-based Activated Carbon Nanofiber Web Electrode by Electrostatic Spinning and Their Applications to EDLC (정전방사에 의한 PAN계 활성화 탄소 나노섬유 전극 제조와 EDLC 응용)

  • Kim, Chan;Kim, Jong-Sang;Lee, Wan-Jin;Kim, Hyung-Sup;Edie, Dan D.;Yang, Kap-Seung
    • Journal of the Korean Electrochemical Society
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    • v.5 no.3
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    • pp.117-124
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    • 2002
  • Poly(acrylonitrile)(PAN) solutions in dimethylformamide(DMF) were electrospun to prepare webs consisting of 400nm ultra-fine fibers. The webs were oxidatively stabilized, activated by steam and resulted to be activated carbon fibers(ACFs). The specific surface area was $800\~1230 m^2/g$, which showed a trend of a decrease of the surface area with an increase in activation temperature, showing opposite behavior to the other ACFs. The activation energy of the stabilized fibers for the steam activation was determined as 29.2 kJ/mol to be relatively low indicating the easier activation than that of other carbonized fibers. The ACF webs were characterized by pore size and specific surface uea which would be related to the specific capacitance of the electrical double layer capacitor (EDLC). The specific capacitances measured were 27 F/g, 25 F/g, 22 F/g at the respective activation temperature of $700^{circ}C,\;750^{\circ}C\;800^{\circ}C$, showing similar trend with the specific surface area i.e., the higher activation temperature was, the lower specific capacitance resulted.

Preparation of Amine-functionalized Graphene Fiber and Its Application (아민 분자로 개질된 그래핀 섬유의 제조 및 응용)

  • Lee, Wonoh;Yoon, Sang Su;Um, Moon-Kwang;Lee, Jea Uk
    • Composites Research
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    • v.28 no.5
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    • pp.265-269
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    • 2015
  • Development of simple and efficient method for large-scale production of mechanically strong and electrically conductive graphene fiber is highly desirable for practical applications, such as fiber-reinforced composites, wearable electronics, and electromagnetic irradiation shielding. Here, we present a facile approach for the preparation of amine-functionalized graphene fibers by simple wet-spinning of diamine-functionalized graphene oxide (GO-$NH_2$), which is used because of its synthetic convenience, good dispersity, and scalable production with low cost. The amine-functionalized graphene fiber shows high electrical and mechanical properties compared to pristine graphene oxide fiber due to the electrostatic interaction between amine groups and electronegative functional groups of graphene oxide.