• 통합자연과학논문집
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• 제3권4호
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• pp.226-230
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• 2010

Calculation of partial charge is important in chemistry. However, because there are many methods developed, it is of considerable interest to know how to calculate and apply properly to address various chemical problems. For basis set, usually double zeta quality is acceptable, and double zeta polarization function would be enough for most cases. To describe electronic state more accurately, Many electron configurations would be necessary to describe highly strained or anionic species. The NPA population introduced new concept about amide bonds, i.e., the planar geometry of nitrogen atom may not come from resonance, but from the lowering of p-orbital energy by electronegative carbonyl carbon atom. The issues for hypervalent atomic charges was also addressed by various charge derivation scheme. When the charge schemes were applied to organolithium compounds, the ionic nature of boding was revealed. This comes from the fact that previous Mulliken partial atomic charges overemphasized the covalent character, wihout much justification. The other partial charge derivation schemes such as NPA(natural population analysis), IPP (Integrated Projected Population) showed that much more ionic picture. ESP potential derived charges are generally believed to be suitable to describe intermolecular interactions, therefore they are used for molecular dynamics simulations and CoMFA (comparative molecular field analysis). The charge derivation schemes using multipole polarization was mainly applied to reproduce experimental infrared spectroscopy. In some reports these schemes are also suitable for intermecular electrostatic interactions. Charges derived from electron density gradient have shown the some bonds are not straight, but actually bent. The proper choice of charge-calculation method along with suitable level of theory and basis set are briefly discussed.

• Journal of electromagnetic engineering and science
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• 제3권1호
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• pp.72-76
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• 2003

For the purpose of numerically efficient analysis for electrostatic problems, an improved equivalent image method, by which infinite exact image of a point charge in parallel-plate and rectangular conducting structures can be replaced by only a few equivalent images, is considered. Through this study, it is observed that the error is of the order of 0.001 % when the present method is used to evaluate electric potential for a point charge in parallel-plate and rectangular conducting planes.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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• pp.1158-1161
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• 2006

The toner type paper-like display (PLD) has been developed with two polymer particles having opposite polarity which is composed of polymer, colorant and external additives (nano-sized silica). Nano-sized silica with triboelectric charge was used for the charge control agent (CCA) and influenced on the electrostatic properties of the silica-coated polymer particles. The PLD cell using silica-coated particles (200 seconds) had shown a good white appearance and low driving voltage. The result could be explained in terms of the surface morphology and the cohesiveness depending on the silica coating time.

• Journal of Advanced Marine Engineering and Technology
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• 제19권2호
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• pp.81-91
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• 1995

A miniature size electrostatic induction motor has been fabricated and studied with emphasis on the role of the surface resistivity, the relative dielectric constant of the rotor surface materials and the rotor liner materials, which control the charge induction and relaxation on the rotor surface and the field intensity between the rotor and the stator. It is found that the higher resitivity and/or the higher relative dielectric constant, concurrently the longer relaxation time constant of the rotor surface materials make the motor speed get higher speed. In case of discrete coated rotor surface it is found that the motor speed was increased logarithmically as narrow as width of the discrete coated Ti. And the degree of width of discrete coated Ti to the axial direction of the rotor was $60^{\circ}$ and $150^{\circ}$, the motor has got a 125% higher than that at the degree of $0^{\circ}$.

• Journal of Information Display
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• 제8권1호
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• pp.14-17
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• 2007

The toner type paper-like display (PLD) has been developed with two polymer particles having opposite polarity composed of polymer, colorant and external additives (nano-sized silica). Nano-sized silica with triboelectric charge was used for the charge control agent (CCA) and influenced on the electrostatic properties of the silica-coated polymer particles. The surface morphology and the cohesiveness of silica-coated polymer particles were changed with the silica coating time. From these results, it was verified that the PLD cell using silica-coated particles (200 seconds) shows a good white appearance and low driving voltage.

• KIEE International Transactions on Electrophysics and Applications
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• 제5C권5호
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• pp.196-203
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• 2005

A semi-empirical method to determine the electrostatic characteristics of a diode type corona aerosol charger based on ion current measurement and electrostatic charging theory was presented. Results from mathematical model were in agreement with those from experimental investigation of the charger. Current-voltage characteristics, $N_{i}t$ product and charge distribution against aerosol size were obtained. It was shown that the space charge was significant and must be taken into account at high ion number concentration and low flow rate. Additionally, significant particle loss was evident for particles smaller than 20 nm in diameter where their electrical mobility was high. Increase in charging efficiency may be achieved by introducing surrounding sheath flow and applying AC high voltage. Overall, the approach was found to be useful in characterizing the aerosol charger.

• 멤브레인
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• 제13권1호
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• pp.29-36
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• 2003

A characterization of the permeation and separation using single salt solution was carried out with charged composite membranes. Various charged composite membranes were fabricated by blending an ionic polymer with a nonionic polymer in different ratios. In this study, sodium alginate, chitosan and poly(vinyl alcohol) were employed as anionic, cationic and nonionic polymers, respectively. The permeation and separation behaviors of the aqueous salt solutions have been investigated through the charged composite membranes with various charge densities. As the content of the ionic polymer increased in the membrane, the hydrophilicity of the membrane increased, and pure water flux and the solution flux increased correspondingly, indicating that the permeation performance through the membrane is determined mainly by its hydrophilicity. Electrostatic interaction between the charged membrane and ionic solute molecules, that is, Donnan exclusion, was observed to be attributed to salt rejection to a greater extent, and molecular sieve mechanism was effective for the separation of salts under a similar electrostatic circumstance of solutes.

• 한국조명전기설비학회:학술대회논문집
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• 한국조명전기설비학회 1990년도 추계학술발표회논문집
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• pp.53-56
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• 1990

When oil flows and rubs against various materials in transformer, electrostatic charges are separated at the interface of the oil and the solid material. Using simplified model transformer, authors investigated the basic characteristics of the streaming electrifica-tion which is caused by forced oil circulation. As the result of the study, it was concluded that the electrostatic charge distribution on test pipe of the transformer showed larger leakage current at the inlet and the outlet.

• Applied Microscopy
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• 제44권3호
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• pp.100-104
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• 2014

As decreasing device size, probing of nanoscale surface properties becomes more significant. In particular, nanoscale probing of surface potential has paid much attention for understanding various surface phenomena. In this article, we review different atomic force microscopy techniques, including electrostatic force microscopy and Kelvin probe force microscopy, for measuring surface potential at the nanoscale. The review could provide fundamental information on the probing method of surface potential using atomic force microscopy.

• 약학회지
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• 제35권6호
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• pp.461-465
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• 1991

Silica-based gel filtration chromatography has been used to characterize molecular weight of proteins. However, the molecular weight measured by this method was distorted by protein-silica interactions like hydrophobic and electrostatic forces. Therefore, we characterized protein-silica interaction using two forms of phytochrome (124 kDa) having different hydrophobicity and surface charge. PH and ionic strength affected the retention time of phytochrome suggesting that electrostatic force is the major interaction between protein and silica surface.