• Title/Summary/Keyword: electron transport rate

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Applications of Plasma Modeling for Semiconductor Industry

  • Efremov, Alexandre
    • Electrical & Electronic Materials
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    • v.15 no.9
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    • pp.10-14
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    • 2002
  • Plasma processing plays a significant role in semiconductor devices technology. Development of new plasma systems, such as high-density plasma reactors, required development of plasma theory to understand a whole process mechanism and to be able to explain and to predict processing results. A most important task in this way is to establish interconnections between input process parameters (working gas, pressure flow rate input power density) and a various plasma subsystems (electron gas, volume and heterogeneous gas chemistry, transport), which are closely connected one with other. It will allow select optimal ways for processes optimizations.

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High-rate growth $YBa_2$$Cu_3$$O_{7-x}$ thick films and thickness dependence of critical current density (Y$Ba_2$$Cu_3$$O_{7-x}$ 후막의 고속 증착과 임계 전류 밀도의 두께 의존성)

  • Jo W.
    • Progress in Superconductivity
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    • v.6 no.1
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    • pp.13-18
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    • 2004
  • High-.ate in-situ$ YBa_2$Cu$Cu_3$$O_{7-x}$ (YBCO) film growth was demonstrated by means of the electron beam co-evaporation. Even though our oxygen pressure is low, ∼$5 ${\times}$10^{-5}$ Torr, we can synthesize as-grown superconducting YBCO films at a deposition rate of around 10 nm/s. Relatively high temperatures of around 90$0^{\circ}C$ was necessary in this process so far, and it suggests that this temperature at a given oxygen activity allows a Ba-Cu-O liquid formation along with an YBCO epitaxy. Local critical current density shows a clear correlation with local resistivity. Homogeneous transport properties with a large critical current density ($4 ∼ 5 MA/\textrm{cm}^2$ at 77K, 0T) are observed in top faulted region while it is found that the bottom part carries little supercurrent with a large local resistivity. Therefore, it is possible that thickness dependence of critical current density is closely related with a topological variation of good superconducting paths and/or grains in the film bodies. The information derived from it may be useful in the characterization and optimization of superconducting films for electrical power and other applications.

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Nitrate Reduction by Fe(0)/iron Oxide Mineral Systems: A Comparative Study using Different Iron Oxides (영가철과 여러 가지 산화철 조합공정을 이용한 질산성질소 환원에 관한 연구)

  • Song, Hocheol;Jeon, Byong-Hun;Cho, Dong-Wan
    • Journal of Soil and Groundwater Environment
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    • v.19 no.1
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    • pp.63-69
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    • 2014
  • This paper presents the feasibility of using different iron oxides (microscale hematite (HT), microscale magnetite (MT), and nanoscale maghemite (NMH)) in enhancing nitrate reduction by zero-valent iron (Fe(0)) under two solution conditions (artificial acidic water and real groundwater). Addition of MT and NMH into Fe(0) system resulted in enhancement of nitrate reduction compared to Fe(0) along reaction, especially in groundwater condition, while HT had little effect on nitrate reduction in both solutions. Field emission scanning electron microscopy (FESEM) analysis showed association of MT and NMH with Fe(0) surface, presumably due to magnetic attraction. The rate enhancement effect of the minerals is presumed to arise from its role as an electron mediator that facilitated electron transport from Fe(0) to nitrate. The greater enhancement of MT and NMH in groundwater was attributed to surface charge neutralization by calcium and magnesium ions in groundwater, which in turn facilitated adsorption of nitrate on Fe(0) surface.

Barrier-Transition Cooling in LED

  • Kim, Jedo
    • Journal of Power System Engineering
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    • v.17 no.5
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    • pp.44-51
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    • 2013
  • This paper proposes and analyzes recycling of optical phonons emitted by nonradiative decay, which is a major thermal management concern for high-power light emitting diodes (LED), by introducing an integrated, heterogeneous barrier cooling layer. The cooling is proportional to the number of phonons absorbed per electron overcoming the potential barrier, while the multi-phonon absorption rate is inversely proportional to this number. We address the theoretical treatment of photon-electron-phonon interaction/transport kinetics for optimal number of phonons (i.e., barrier height). We consider a GaN/InGaN LED with a metal/AlGaAs/GaAs/metal potential barrier and discuss the energy conversion rates. We find that significant amount of heat can be recycled by the barrier transition cooling layer.

Chlorophyll α fluorescence as an indicator of establishment of Zostera marina transplants on the southern coast of Korea

  • Li, Wen-Tao;Park, Jung-Im;Park, Sang-Rul;Zhang, Xiu-Mei;Lee, Kun-Seop
    • ALGAE
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    • v.25 no.2
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    • pp.89-97
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    • 2010
  • To test the feasibility of using chlorophyll ${\alpha}$ fluorescence to assess the establishment success of seagrass transplants, photosynthetic characteristics of eelgrass Zostera marina transplants were measured using a Diving-pulsed amplitude modulation fluorometer in Jindong Bay on the southern coast of Korea. Maximum quantum yield ($F_v/F_m$), photosynthetic efficiency ($\alpha$), saturating irradiance ($E_k$) and maximum electron transport rate ($ETR_{max}$) of transplants and reference plants in a nearby transplant site were measured using the fluorometer for 5 months. Additionally, shoot morphology, individual shoot weight and productivity of transplants and reference plants were also monitored. Shoot height, leaf weight and productivity of transplants were significantly reduced during the first two or three months after transplantation compared to those of reference plants, and then increased to the levels of reference plants Characteristics of chlorophyll a fluorescence, including $F_v/F_m$, $\alpha$, $E_k$ and $ETR_{max}$ of transplants were also significantly reduced in the initial period, but recovered slightly sooner than shoot morphology or leaf productivity. These results indicated that after transplantation, Z. marina transplant photosynthesis recovered faster than shoot morphology, biomass or productivity. Thus, chlorophyll a fluorescence can be used as an indicator for early assessment of the status of eelgrass transplants without destructive sampling.

Electrical Characteristics of OLEDs depending on the Deposition Rate of Hole Transport Layer(TPD) (정공 수송층(TPD) 증착 속도에 따른 유기 발광 소자의 전기적 특성)

  • Kim, Weon-Jong;Lee, Young-Hwan;Lee, Sang-Kyo;Park, Hee-Doo;Cho, Kyung-Soon;Kim, Tae-Wan;Hong, Jin-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.87-88
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    • 2008
  • In the structure of ITO/N,N'-diphenyl-N,N' bis (3-methylphenyl)-1,1'-biphenyl-4,4'-diamine(TPD)/tris (8-hydroxyquinoline)aluminum$(Alq_3)$/Al device, we studied the efficiency improvement of organic light-emitting diodes due to variation of deposition rate of TPD materials. The thickness of TPD and $Alq_3$ was manufactured 40 nm, 60 nm, respectively under a base pressure of $5\times10^{-6}$Torr using a thermal evaporation. The $Alq_3$ used for an electron-transport and emissive layer were evaporated to be at a deposition rate of 2.5 $\AA$/s. When the deposition rate of TPD increased from 1.5 to 3.0 $\AA$/s, we found that the average roughness is rather smoother, external quantum efficiency is superior to the others when the deposition rate of TPD is 2.5 $\AA$/s. Compared to the ones from the devices made with the deposition rate of TPD 3.0 $\AA$/s, the external quantum efficiency was improved by a factor of eight.

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Effect of ON/OFF Cycles of Ar Gas on Structural and Optical Properties of ZnO Nanostructure Grown by Vapor Phase Transport

  • Nam, Gi-Woong;Kim, Min-Su;Cho, Min-Young;Kim, So-A-Ram;Leem, Jae-Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.415-415
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    • 2012
  • ZnO nanostructures were synthesized by a vapor phase transport process in a single-zone furnace within a horizontal quartz tube with an inner diameter of 38 mm and a length of 485 mm. The ZnO nanostructures were grown on Au-catalyzed Si(100) substrates by using a mixture of zinc oxide and graphite powders. The growth of ZnO nanostructures was conducted at $800^{\circ}C$ for 30 min. High-purity Ar and $O_2$ gases were pushed through the quartz tube during the process at a flow rate of 100 and 10 sccm, respectively. The sequence of ON/OFF cycles of the Ar gas flow was repeated, while the $O_2$ flow is kept constant during the growth time. The Ar gas flow was ON for 1 min/cycle and that was OFF for 2 min/cycle. The structure and optical properties of the ZnO nanostructures were investigated by field-emission scanning electron microscope, X-ray diffraction, temperature-dependent photoluminescence. The preferred orientation of the ZnO nanostructures was along c-axis with hexagonal wurtzite structure.

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FTIR study of gamma and electron irradiated high-density polyethylene for high dose measurements

  • Al-Ghamdi, Hanan;Farah, Khaled;Almuqrin, Aljawharah;Hosni, Faouzi
    • Nuclear Engineering and Technology
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    • v.54 no.1
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    • pp.255-261
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    • 2022
  • A reliable and well-characterized dosimetry system which is traceable to the international measurement system, is the key element to quality assurance in radiation processing with cobalt-60 gamma rays, X-rays, and electron beam. This is specifically the case for health-regulated processes, such as the radiation sterilization of single use medical devices and food irradiation for preservation and disinfestation. Polyethylene is considered to possess a lot of interesting dosimetric characteristics. In this work, a detailed study has been performed to determine the dosimetric characteristics of a commercialized high-density polyethylene (HDPE) film using Fourier transformed infrared spectrometry (FTIR). Correlations have been established between the absorbed dose and radiation induced infrared absorption in polyethylene having a maximum at 965 cm-1 (transvinylene band) and 1716 cm-1 (ketone-carbonyl band). We have found that polyethylene dose-response is linear with dose for both bands up to1000 kGy. For transvinylene band, the dose-response is more sensitive if irradiations are made in helium. While, for ketone-carbonyl band, the dose-response is more sensitive when irradiations are carried out in air. The dose-rate effect has been found to be negligible when polyethylene samples are irradiated with electron beam high dose rates. The irradiated polyethylene is relatively stable for several weeks after irradiation.

Humic Substances Act as Electron Acceptor and Redox Mediator for Microbial Dissimilatory Azoreduction by Shewanella decolorationis S12

  • Hong, Yi-Guo;Guo, Jun;Xu, Zhi-Cheng;Xu, Mei-Ying;Sun, Guo-Ping
    • Journal of Microbiology and Biotechnology
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    • v.17 no.3
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    • pp.428-437
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    • 2007
  • The potential for humic substances to serve as terminal electron acceptors in microbial respiration and the effects of humic substances on microbial azoreduction were investigated. The dissimilatory azoreducing microorganism Shewanella decolorationis S12 was able to conserve energy to support growth from electron transport to humics coupled to the oxidation of various organic substances or $H_2$. Batch experiments suggested that when the concentration of anthraquinone-2-sulfonate (AQS), a humics analog, was lower than 3 mmol/l, azoreduction of strain S12 was accelerated under anaerobic condition. However, there was obvious inhibition to azoreduction when the concentration of the AQS was higher than 5 mmol/l. Another humics analog, anthraquinone-2-sulfonate (AQDS), could still prominently accelerate azoreduction, even when the concentration was up to 12 mmol/l, but the rate of acceleration gradually decreased with the increasing concentration of the AQDS. Toxic experiments revealed that AQS can inhibit growth of strain S12 if the concentration past a critical one, but AQDS had no effect on the metabolism and growth of strain S12 although the concentration was up to 20 mmol/l. These results demonstrated that a low concentration of humic substances not only could serve as the terminal electron acceptors for conserving energy for growth, but also act as redox mediator shuttling electrons for the anaerobic azoreduction by S. decolorationis S12. However, a high concentration of humic substances could inhibit the bacterial azoreduction, resulting on the one hand from the toxic effect on cell metabolism and growth, and on the other hand from competion with azo dyes for electrons as electron acceptor.

Effects of Cadmium and Cadmium Binding Protein on the Respiration of Mitochondria of Rat Kidney (흰쥐 신장의 미토콘드리아 호흡에 미치는 Cadmium과 Cadmium Binding Protein의 영향)

  • Cho, Hae-Kyoung;Boo, Moon-Jong;Choe, Rim-Soon
    • Applied Microscopy
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    • v.19 no.2
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    • pp.59-73
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    • 1989
  • To investigate the effect of cadmium and cadmium binding protein on the electron transport system and conformational changes of rat kidney mitochondria, various cadmium concentration were treated in vitro and respiration rate, NADH-CoQ reductase activity were measured. Ultrastructural changes at state IV respiration were also observed. CdBP was isolated from the rat liver by Sephadex G-75 column fractionation and treated in vitro with cadmium. Also mitochondrial state IV respiration rate was measured. When cadmium was treated in vitro, state IV respiration and enzyme activity were decreased and ultrastructural transformation of mitochondria from a condensed to an orthodox conformation was inhibited under state IV respiration. In case cadmium and CdBP were treated together, oxygen consumption was more increased than cadmium only. Conformational changes of mitochondria from a condensed to orthodox conformation were also observed. This indicates that CdBP have a protective effect against cadmium toxicity.

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