• Proceedings of the KIEE Conference
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• 1994.07b
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• pp.1400-1402
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• 1994

Plasma polymerized thin films was prepared using an interelectrod inductively coupled gas-flow-type reactor. Styrene was chosen as the monomer to be used. This thin films were also delineated by the electron-beam apparatus with an acceleration voltage 30kV, and the pattern in the resist was developed with RIE 80 with argon gas mixture ratio, pressure and RF power. The molecular structure of thin films was investigated by GPC and FT-IR and then was discussed in relation to its quality as a resist. In the case of plasma polymerization, thickness of resist could be controlled by discharge duration and power. Also etch rate is increased as to growing pressure with RIE 80.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1994.05a
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• pp.138-140
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• 1994

Plasma polymerized thin film was prepared using an interelectrod inductively coupled gas-flow-type reactor. Styrene was chosen as the monomer to be used. This thin films were also delineated by the electron-beam apparatus with an acceleration voltage 30kV, and the pattern in the resist was developed with RIE 80 with argon gas mixture ratio, pressure and RF power. The effect of charge of discharge power on growth rate and etching rate of the thin films were studied. The molecular structure of thin films were investigated by FIR and then was discussed in relation to its quality as a resist. In the case of Plasma polymerization, thickness of resist could be controlled by discharge duration and power. Also etch rate is increased as to growing argon gas and RF power with RIE 80.

• Proceedings of the KIEE Conference
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• 1993.07b
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• pp.1183-1185
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• 1993

The plasma polymerized thin film of MMA+Sty was prepared using a capacitively coupled gas-flow-type reactor. This thin films were also delincated by the electron-beam apparatus with an acceleration voltage 30KV, and the pattern in the resist was developed with the gas-flow-type reactor using an argon as an etchant. The effect of discharge power on groth rate and etching rate of the thin film were studied. The molacular structure of the resist was investigated by ESCA and FT-IR.

• The Bulletin of The Korean Astronomical Society
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• v.44 no.1
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• pp.51.1-51.1
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• 2019

The Korea Astronomy and Space Science Institute (KASI) has been developing a coronagraph in collaboration with the National Aeronautics and Space Administration (NASA), to install it on the International Space Station (ISS). The coronagraph will utilize spectral information to simultaneously measure electron density, temperature, and velocity. For this, we develop the coronagraph as a two-step process. First, we will perform a stratospheric balloon-borne experiment, so called BITSE, in 2019 with a new type of coronagraph. Second, the coronagraph will be installed and operate on the ISS (CODEX) in 2021 to address a number of questions (e.g., source and acceleration of solar wind, and coronal heating) that are both fundamental and practically important in the physics of the solar corona and of the heliosphere. In this presentation, we will introduce recent progresses.

• The Bulletin of The Korean Astronomical Society
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• v.44 no.2
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• pp.56.4-56.4
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• 2019

The Korea Astronomy and Space Science Institute (KASI) has been collaborating with the NASA's Goddard Space Flight Center, to install a coronagraph on the International Space Station (ISS). The coronagraph will utilize spectral information to simultaneously measure electron density, temperature, and velocity. As a first step, we developed a new coronagraph and launched it on a stratospheric balloon in 2019 (BITSE) from Fort Sumner, New Mexico in USA. As the next step, the coronagraph will be be further developed, installed and operate on the ISS (CODEX) in 2022 to address a number of important questions (e.g., source and acceleration of solar wind, and coronal heating) in the physics of the solar corona and the heliosphere. Recently, BITSE has been launched at Fort Sumner, New Mexico. In this presentation, we will introduce the BITSE mission and discuss recent progress.

• The Bulletin of The Korean Astronomical Society
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• v.45 no.1
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• pp.44.2-44.2
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• 2020

The Korea Astronomy and Space Science Institute (KASI) has been collaborating with the NASA Goddard Space Flight Center (GSFC), to install a diagnostic coronagraph on the International Space Station (ISS). The coronagraph is designed to obtain simultaneous measurements of electron density, temperature, and velocity using multiple filters in the 3-10 Rs range. In 2019, we developed a new coronagraph and launched it on a stratospheric balloon (BITSE) from Fort Sumner, New Mexico in USA. As the next step, the coronagraph will be further developed, installed and operated on the ISS (CODEX) in 2023 to understand the physical conditions in the solar wind acceleration region, and enable and validate the next generation space weather models. In this presentation, we will report recent progress and introduce future plan.

• The Bulletin of The Korean Astronomical Society
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• v.46 no.2
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• pp.79.3-79.3
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• 2021

The Korea Astronomy and Space Science Institute (KASI) has been developing a diagnostic coronagraph to be deployed in 2023 on the International Space Station (ISS) in collaboration with the NASA Goddard Space Flight Center (GSFC). The mission is known as "Coronal Diagnostic Experiment (CODEX)", which is designed to obtain simultaneous measurements of the electron density, temperature, and velocity using multiple filters in the 2.5-10 Rs range. The coronagraph will be installed and operated on the ISS to understand the physical conditions in the solar wind acceleration region, and to enable and validate the next generation space weather models. In this presentation, we will introduce recent progress and future plan.

• Journal of the Korean Chemical Society
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• v.26 no.5
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• pp.333-339
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• 1982

Substituent effects of substrate and leaving group for the reaction of substituted ${\beta}$-phenylethyl arenesulfonates with pyridine were determined conductometrically in acetonitrile at 50∼70$^{\circ}$C. The substituent effect in substrate is not so significant than expected, but still the electron donating substituent shows the slight acceleration to give a small negative ${\rho}$ value and Hammett plots show slight curvature on the acting substituents, even though it is not so remarkable than that of benzyl system. These results represent a little bit the favorable bond breaking at the transition state by the electron donating substituents. The effects of leaving group in the arenesulfonates in which the rate constants are decreased by electron donating substituents, while electron withdrawing groups presented the reverse effects. Hammett ${\rho}$ value is significantly smaller than that of p-nitrobenzyl arenesulfonates and thus, the mechanism should be closer to tight $S_N2$ one. Especially 2,5-dichlorobenzenesulfonate was more accelerated than expected at the additivity of substituents. This facts showed that dichlorobenzenesulfonate anion is more stabilized by the great electron withdrawing substituents at transition state.

• Polymer(Korea)
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• v.36 no.1
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• pp.47-52
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• 2012

Abstract: In this study, PAN/$TiO_2$ fiber mats were fabricated from polyacrylonitrile (PAN) and titanium(IV) butoxide ($Ti(OBu)_4$) by an electrospinning method with various solution concentrations, applied voltages and solution flow rates. The fiber mats were irradiated with an electron beam to induce structural crosslinking and enhance photocatalytic activity. As a result, uniform and bead-free fibers without pits or cracks on surface were obtained at 5 wt% of $Ti(OBu)_4$ solution with 15 kV and 0.02 mL/min flow rate. The PAN/$TiO_2$ fiber mats were irradiated with an electron beam of 1.14 MeV acceleration voltage, 4 mA of current and $1{\times}10^4kGy$. Electron beam irradiation was enhanced the photocatalytic activity of PAN/$TiO_2$ nano fiber mat. The photocatalytic activity of the PAN/$TiO_2$ fiber mat was analyzed by degradation of methylene blue and volatile organic compounds.

• Korean Journal of Mineralogy and Petrology
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• v.35 no.4
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• pp.457-467
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• 2022

Electron bombardment to silicate glass during electron probe microanalysis (EPMA) causes outward migration of Na from the excitation volume and subsequent decrease in the measured X-ray count rates of Na. To acquire precise Na₂O content of silicate glass, one should use proper analytical technique to avoid or minimize Na migration effect or should correct for decreases in the measured Na X-ray counts. In this study, we analyzed 8 silicate glass standard samples using automated Time Dependent Intensity (TDI) correction method of Probe for EPMA software that can calculate zero-time intercept by extrapolating X-ray count changes over analysis time. We evaluated an accuracy of TDI correction for Na measurements of silicate glasses with EPMA at 15 kV acceleration voltage and 20 nA probe current electron beam, which is commonly utilized analytical condition for geological samples. Results show that Na loss can be avoided with 20 ㎛-sized large beam (<0.1 nA/㎛²), thus silicate glasses can be analyzed without TDI correction. When the beam size is smaller than 10 ㎛, Na loss results in large relative errors up to -55% of Na₂O values without correction. By applying TDI corrections, we can acquire Na₂O values close to the reference values with relative errors of ~ ±10%. Use of weighted linear-fit can reduce relative errors down to ±6%. Thus, quantitative analysis of silicate glasses with EPMA is required for TDI correction for alkali elements such as Na and K.