• Title/Summary/Keyword: electrical impedance

Search Result 2,485, Processing Time 0.036 seconds

Improvement of Rate Capability and Low-temperature Performances of Graphite Negative Electrode by Surface Treatment with Copper Phthalocyanine (구리 프탈로시아닌으로 표면처리된 흑연 음극의 속도특성 및 저온성능 개선)

  • Jurng, Sunhyung;Park, Sangjin;Ryu, Ji Heon;Oh, Seung M.
    • Journal of the Korean Electrochemical Society
    • /
    • v.18 no.3
    • /
    • pp.130-135
    • /
    • 2015
  • The rate capability and low-temperature characteristics of graphite electrode are investigated after surface treatment with copper phthalocyanine (CuPc) or phthalocyanine (Pc). Uniform coating layers comprising amorphous carbon or copper are generated after the treatment. The rate performance of graphite electrodes is enhanced by the surface treatment, which is more prominent with CuPc. The resistance of the graphite electrode estimated from electrochemical impedance spectroscopy and pulse resistance measurement is the smallest for the CuPc-treated graphite. It is likely that the amorphous carbon layer formed by the decomposition of Pc facilitates $Li^+$ diffusion and the metallic copper derived from CuPc improves the electrical conductivity of the graphite electrode.

Design of Koch Curve Microstrip Patch Antenna for Miniaturization Structure (소형화 구조를 위한 koch curve 마이크로스트립 패치 안테나 설계)

  • Kim, Sun-Woong;Kim, Gul-Bum;Yun, Jung-Hyun;Choi, Dong-You
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • v.18 no.12
    • /
    • pp.2823-2830
    • /
    • 2014
  • The antenna miniaturization technique involves the increment of the electrical length of the resonator the variation of the physical appearance of the antenna. The most typical method of size reduction is designing helical antenna, meander antenna, and fractal antenna. Size reduction using fractal antenna is proposed in this paper. Fractal koch curve has been etched in microstrip patch antenna to downsize the antenna at ISM (Industrial Scientific and Medical) frequency band of 2.45 GHz koch curve microstrip patch antenna ha FR4 epoxy substrate with dielectric constant 4.7, loss tangent equal to 0.02 and dielectric high of 1.6 mm. The designed antenna is fabricated using etching process. The fabricated antenna has return loss of 2.45 GHz, VSWR of 1.1492, and impedance is matched to $46{\Omega}$.

Necklace Type UHF RFID Tag Antenna for the Material with High Dielectric Constant for a Tree (고유전율에 적합한 목걸이 형태의 생목용 UHF RFID 태그 안테나 설계)

  • Chung, You-Chung
    • The Journal of Korean Institute of Communications and Information Sciences
    • /
    • v.37 no.1C
    • /
    • pp.34-37
    • /
    • 2012
  • The paper introduces the an necklace type UHF RFID tag for a live tree having high dielectric constant. When a general UHF RFID tag is used for the metal and the material with high dielectric constant, the electrical characteristics and impedance of antenna have been changed, and the tag is not recognized by an UHF RFID reader. The necklace type UHF RFID tag has been designed with consideration of the high dielectric constant of the tree material. The name tag for a live tree has been designed with the developed tag antenna. The performance of tag has been measured and the reading range is about 4~5m. The developed UHF RFID tag antenna can be applied to any high dielectric material for various industrial applications.

Design of Stack Monitoring System with Improved Performance (성능이 향상된 Stack Monitoring System의 설계)

  • Jang, Kyeong-Uk;Lee, Joo-Hyun;Lee, Seong-Won;Lee, Seung-Ho
    • Journal of IKEEE
    • /
    • v.20 no.3
    • /
    • pp.299-302
    • /
    • 2016
  • In this paper, we designed the stack monitoring system with improved performance. To block the incoming pulse noise to the amplifier, shield and the power supply impedance are reduced and the power circuit is isolated. The control unit is developed with variable high voltage, adaptive gain, offset and threshold in order to match the scintillation detector characteristic to the apparatus. 300-1500V variable high voltage power circuit is configured applicable to various scintillation detector. Stack monitoring system with improved performance guarantee the efficiency and the reliability by considering the characteristic of various scintillation detector. Developed stack monitoring system is evaluated with certified testing equipment and shows excellent performance with respect to the uncertainty of the sensor test results.

Electrochemical performance of double perovskite structured cathodes for intermediate temperature SOFCs

  • Jo, Seung-Hwan;Muralidharan, P.;Kim, Do-Kyung
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2009.05a
    • /
    • pp.56.1-56.1
    • /
    • 2009
  • The intermediate operating temperature of solid oxide fuel cells (IT-SOFCs) have achieved considerable importance in the area of power fabrication. This is because to improve materials compatibility, their long-term stability and cost saving potential. However, to conserve rational cell performance at reduced-temperature regime, cathode performance should be obtained without negotiating the internal resistance and the electrode kinetics of the cell. Recently, double perovskite structure cathodes have been studied with great attention as a potential material for IT-SOFCs. In this study, double-perovskite structured cathodes of $GdBaCoCuO_{5+\delta}$, $GdBaCo_{2/3}Cu_{2/3}Fe_{2/3}O_{5+\delta}$ compositions and $(1-x)GdBaCo_2O_{5+\delta}+xCe_{0.9}Gd_{0.1}O_{1.95}$ (x = 10, 20, 30 and 40 wt.%) composites were evaluated as the cathode for intermediate temperature solid oxide fuel cells(IT-SOFCs). Electrical conductivity of the cathodes were measured by DC 4-probe method, and the thermal expansion coefficient of each sample was measured up to $900^{\circ}C$ by a dilatometer study. Area specific resistances(ASR) of the $GdBaCo_{2/3}Cu_{2/3}Fe_{2/3}O_{5+\delta}$ cathode and 70 wt.% $GdBaCo_2O5+\delta$ + 30wt.% Ce0.9Gd0.1O1.95 composite cathode on CGO electrolyte substrate were analyzed using AC 3-probe impedance study. The obtained results demonstrate that double perovskite-based compositions are promising cathode materials for IT-SOFCs.

  • PDF

Carbon Nanotube-based Nanohybrid Materials as Counter Electrode for Highly Efficient Dye-sensitized Solar Cells (고효율 염료감응형 태양전지를 위한 탄소나노튜브 기반 나노 하이브리드 상대전극)

  • Kim, Ji-Soo;Sim, Eun-Ju;Dao, Van-Duong;Choi, Ho-Suk
    • Korean Chemical Engineering Research
    • /
    • v.54 no.2
    • /
    • pp.262-267
    • /
    • 2016
  • In this study, we present an excellent approach for easily and uniformly immobilizing Pt, Au and bimetallic PtAu nanoparticles (NPs) on a multi-walled carbon nanotube (MWNT)-coated layer through dry plasma reduction. The NPs are stably and uniformly immobilized on the surface of MWNTs and the nanohybrid materials are applied to counter electrode (CE) of dye-sensitized solar cells (DSCs). The electrochemical properties of CEs are examined through cyclic voltammogram, electrochemical impedance spectroscopy, and Tafel measurements. As a result, both electrochemical catalytic activity and electrical conductivity are highest for PtAu/MWNT electrode. The DSC employing PtAu/MWNT CE exhibits power conversion efficiency of 7.9%. The efficiency is better than those of devices with MWNT (2.6%), AuNP/MWNT (2.7%) and PtNP/MWNT (7.5%) CEs.

Analysis of Eddy Current Effect in Magnetic Resonance Imaging Using the Finite Element Method (유한요소법에 의한 자기공명영상시스템에서의 와전류 영향 분석)

  • Lee, Jeong-Han;Gang, Hyeon-Su;Jo, Min-Hyeong;Mun, Chi-Ung;Lee, Gang-Seok;Lee, Su-Yeol
    • Journal of Biomedical Engineering Research
    • /
    • v.20 no.1
    • /
    • pp.53-58
    • /
    • 1999
  • Eddy current in MRI systems degrades gradient field linearity and distorts gradient waveform. When the waveform distortion is spatially variant, it is very difficult to perform special imaging techniques such as the echo planar imaging technique or the fast spin echo imaging technique. In this study, we have developed a new technique to estimate the distorted gradient waveforms at any points inside the imaging region using the finite element method. After obtaining the eddy-current-effect transfer function, which represents magnitude and phase characteristics of the gradient field at a particular point, we have used the transfer function to estimate the actual gradient waveforms at the point. To verify the proposed technique, we have compared the estimated gradient waveforms with the measured ones.

  • PDF

Characteristics of Antenna Factor for a Calculable Dipole Antenna above Ground Plane in 1~3 GHz Frequency Band (1~3 GHz 대역용 계산가능 다이폴안테나의 접지판 위 안테나 인자 특성)

  • Lim, Sung-Min;Kim, Sang-Myung;Jung, Sung-Woo;Kim, Ki-Chai
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • v.19 no.9
    • /
    • pp.1991-1998
    • /
    • 2015
  • This paper presents the antenna factor characteristics of a calculable dipole antenna with a hybrid balun, installed above ground plane vertically and horizontally, using Method of Moments (MoM). An expression for the antenna factor is formulated using the concept of power mismatch loss. The input impedance and effective length of the antenna, which are in the formula of the antenna factor, are calculated using the MoM. The results show that the antenna factors above a ground plane are agreed with the free space antenna factors within ± 0.14 dB. The horizontal antenna factors are varied more by 0.2 dB than the vertical antenna factors.

Quench Characteristics of HTSC Elements according to fault types in Integrated Three-Phase (삼상일체화된 자속구속형 SFCL의 사고종류에 따른 소자들의 퀜치 특성)

  • Park, Chung-Ryul;Lee, Jong-Hwa;Park, Sig;Du, Ho-Ik;Lim, Sung-Hun;Choi, Hyo-Sang;Han, Byoung-Sung
    • Proceedings of the KIEE Conference
    • /
    • 2005.07b
    • /
    • pp.960-962
    • /
    • 2005
  • In this paper, we investigated the quench characteristics of high-Tc superconducting(HTSC) elements in the integrated three-phase flux-lock type superconducting fault current limiter(SFCL) according to fault types such as the single-line-to-ground fault, the double-line-to-ground fault, the line-to-line fault and the triple-line-to-ground fault. The integrated three-phase flux-lock type SFCL is an upgrade version of single-phase flux-lock type SFCL. The structure of the integrated three-phase flux-lock type SFCL consisted of a three-phase flux-lock reactor wound on an iron core with the ratio of the same turn between coil 1 and coil 2 in each phase. When the SFCL is under the normal condition, the flux generated in the iron core is zero because the flux generated between two coils of each single phase is canceled out. Therefore, the SFCL's impedance is zero, and the SFCL has negligible influence on the power system. However, if a fault occurs in any single one of three phases, the flux generated in the iron core is not zero any more. The flux makes HTSC elements of all phases to quench irrespective of the fault type, which reduces the current in fault phase as well as the current of sound phase. It was obtained that the fault current limiting characteristics of the suggested SFCL were dependent on the quench characteristics of HTSC elements in all three phases.

  • PDF

Enhanced Si based negative electrodes using RF/DC magnetron sputtering for bulk lithium ion batteries

  • Hwang, Chang-Muk;Park, Jong-Wan
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2010.02a
    • /
    • pp.277-277
    • /
    • 2010
  • The capacity of the carbonaceous materials reached ca. $350\;mAhg^{-1}$ which is close to theorestical value of the carbon intercalation composition $LiC_6$, resulting in a relatively low volumetric Li capacity. Notwithstanding the capacities of carbon, it will not adjust well to the need so future devices. Silicon shows the highest gravimetric capacities (up to $4000\;mAhg^{-1}$ for $Li_{21}Si_5$). Although Si is the most promising of the next generation anodes, it undergoes a large volume change during lithium insertion and extraction. It results in pulverization of the Si and loss of electrical contact between the Si and the current collector during the lithiation and delithiation. Thus, its capacity fades rapidly during cycling. We focused on electrode materials in the multiphase form which were composed of two metal compounds to reduce the volume change in material design. A combination of electrochemically amorphous active material in an inert matrix (Si-M) has been investigated for use as negative electrode materials in lithium ion batteries. The matrix composited of Si-M alloys system that; active material (Si)-inactive material (M) with Li; M is a transition metal that does not alloy with Li with Li such as Ti, V or Mo. We fabricated and tested a broad range of Si-M compositions. The electrodes were sputter-deposited on rough Cu foil. Electrochemical, structural, and compositional characterization was performed using various techniques. The structure of Si-M alloys was investigated using X-ray Diffractometer (XRD) and transmission electron microscopy (TEM). Surface morphologies of the electrodes are observed using a field emission scanning electron microscopy (FESEM). The electrochemical properties of the electrodes are studied using the cycling test and electrochemical impedance spectroscopy (EIS). It is found that the capacity is strongly dependent on Si content and cycle retention is also changed according to M contents. It may be beneficial to find materials with high capacity, low irreversible capacity and that do not pulverize, and that combine Si-M to improve capacity retention.

  • PDF