• 제목/요약/키워드: effective thermal conductivity

검색결과 305건 처리시간 0.028초

Modified glycine-nitrate process(MGNP)로 합성한 BaCo1-x-yFexZryO3-δ 산소투과도 및 수소생산성 (Oxygen Permeation and Hydrogen Production of BaCo1-x-yFexZryO3-δ by a Modified Glycine-nitrate Process (MGNP))

  • 이은정;황해진
    • 한국수소및신에너지학회논문집
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    • 제24권1호
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    • pp.29-35
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    • 2013
  • A dense mixed ionic and electronic conducting ceramic membrane is one of the most promising materials because it can be used for separation of oxygen from the mixture gas. The $ABO_3$ perovskite structure shows high chemical stability at high temperatures under reduction and oxidation atmospheres. $BaCo_{1-x-y}Fe_xZr_yO_{3-{\delta}}$ (BCFZ) was well-known material as high mechanical strength, low thermal conductivity and stability in the high valence state. Glycine Nitrate Process (GNP) is rapid and effective method for powder synthesis using glycine as a fuel and show higher product crystallinity compared to solid state reaction and citrate-EDTA method. BCFZ was fabricated by modified glycine nitrate process. In order to control the burn-up reaction, $NH_4NO_3$ was used as extra nitrate. According to X-Ray Diffraction (XRD) results, BCFZ was single phase regardless of Zr dopants from y=0.1 to 0.3 on B sites. The green compacts were sintered at $1200^{\circ}C$ for 2 hours. Oxygen permeability, methane partial oxidation rate and hydrogen production ability of the membranes were characterized by using Micro Gas Chromatography (Micro GC) under various condition. The high oxygen permeation flux of BCFZ 1-451 was about $1ml{\cdot}cm^{-2}s^{-1}$. Using the humidified Argon gas, BCFZ 1-433 produced hydrogen about $1ml{\cdot}cm^{-2}s^{-1}$.

MOCVD RuOx 박막의 미세구조 특성평가와 열처리 가스환경 영향 (Microstructural Characterization of MOCVD RuOx Thin Films and Effects of Annealing Gas Ambient)

  • 김경원;김남수;최일상;김호정;박주철
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제51권9호
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    • pp.423-429
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    • 2002
  • RuOx thin films were fabricated by the method of liquid delivery MOCVD using Ru(C$_{8}$ $H_{13}$ $O_2$)$_3$ as the precursor and their thermal effects and conductivity were investigated. Ru films deposited at 25$0^{\circ}C$ were annealed at $650^{\circ}C$ for 1min with Ar, $N_2$ or N $H_3$ ambient. The changes of the micro-structure, the surface morphology and the electrical resistivity of the Ru films after annealing were studied. Ar gas was more effective than $N_2$ and N $H_3$ gases as an ambient gas for the post annealing of the Ru films, because of smaller resistivity and denser grains. The X-ray diffraction and X-ray photoelectron spectroscopy results indicate that the Ru $O_2$ phase and the silicidation are not observed regardless of the ambient gases. The minimum resistivity of the Ru film is found to have the value of 26.35 $\mu$Ω-cm in Ar ambient. Voids were formed at Ru/TiN interface of the Ru layer after annea1ing in $N_2$ ambient. The $N_2$ gas generated due to the oxidation of the TiN layer accumulated at the Ru/TiN interface, forming bubbles; consequently, the stacked film may peel off the Ru/TiN interface.e.

멀티-핀을 갖는 LED 패키지 방열장치의 동작특성 (Operating Characteristics of LED Package Heat-sink with Multi-Pin's)

  • 최훈;한상보;박재윤
    • 조명전기설비학회논문지
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    • 제28권7호
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    • pp.1-12
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    • 2014
  • This paper is proposed to design the new heat-sink apparatus for improving the heat transfer characteristics in the power LED chip, and results of the operation characteristics were discussed. The core design is that the soldering through-hole on the FR-4 PCB board is formed to the effective heat transfer. That is directly filled with Ag-nano materials, which shows the high thermal conductivity. The heat transfer medium consisting of Ag-nano materials is classified into two structures. Mediums are called as the heat slug and the multi-pin in this work. The heat of the high temperature generated from the LED chip was directly transferred to the heat slug of the one large size. And the accumulated heat from the heat slug was quickly dissipated by the medium of the multi-pin, which is the same body with the heat slug. This multi-pin was designed for the multi-dissipation of heat by increasing the surface areas with a little pins. Subsequently, the speed of the heat transfer with this new heat-sink apparatus is three times faster than the conventional heat-sink. Therefore, the efficiency of the illuminating light will be improved by adapting this new heat-sink apparatus in the large area's LED.

마이크로파를 이용한 비극성 고무컴파운드의 가황 효율 (Vulcanization Efficiency of Non-polar Rubber Compounds by Microwave)

  • 정우선;이원기;임권택
    • 폴리머
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    • 제35권3호
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    • pp.228-231
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    • 2011
  • 열원으로 열풍과 마이크로파를 이용하여 비극성 ethylene-propylene-diene terpolymer(EPDM)/카본블랙 컴파운드 제조에 있어서 시편의 두께 및 첨가제 함량에 따른 가황속도의 영향을 비교 조사하였다. 열풍가황의 경우, 컴파운드의 두께가 가장 중요한 인자로서 EPDM의 나쁜 열전도도 특성으로 인하여 컴파운드의 두께가 증가할수록 가황속도는 느려졌으며 두께 3 mm 컴파운드의 완전 가황은 $250^{\circ}C$에서 7분 이상이 소요되었다. 반면에 마이크로파 가황에서는 컴파운드의 두께에 의한 영향은 없었으나 극성첨가제인 카본블랙 함량에 큰 영향을 받았다. 카본블랙이 80 phr 이상인 컴파운드는 30초간 마이크로파 노출에 의해 거의 100% 가황이 일어남을 확인하였다. 이러한 결과는 극성물질을 포함하는 컴파운드의 가황열원으로서 마이크로파가 효과적임을 알 수 있었다.

온수 가열 바닥 난방 시스템용 고성능 버블젯 루프 히트파이프 개발 (Development of High Performance Bubble Jet Loop Heat Pipe for Hot Water Floor Heating System)

  • 김종수;권용하;김정웅
    • 동력기계공학회지
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    • 제18권4호
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    • pp.23-28
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    • 2014
  • In order to increase the performance of conventional hot water floor heating system, the bubble jet loop heat pipe for the system was developed. This experiment was conducted under next conditions : Working fluid was R-134a, charging ratio was 50%. A temperature of hot water, room temperature and flow rate were $60^{\circ}C$, $15^{\circ}C$ and 0.5~1.5 kg/min, respectively. The experimental results, show that bubble jet loop heat pipe had a high effective thermal conductivity of $4714kW/m^{\circ}C$ and a sufficient heat flux of $73W/m^2$ to heat the floor to $35^{\circ}C$ in case of the 1.5 kg/min of flow rate. So the bubble jet loop heat pipe has a possibility for appling of the floor heating system. Additionally, the visualization of bubble jet loop heat pipe was performed to understand the operating principle. Bubbles made by the narrow gap between inner tube and outer tube of evaporating part generate pulsation at liquid surface of working fluid. The pulsation had slug flow and wavy flow. So working fluid circulates in the bubble jet loop heat pipe as two phase flow pattern. And large amount of heat is transferred by the latent heat from evaporating part to condensing part.

Synthesis of CdS with Graphene by CBD(Chemical Bath Deposition) Method and Its Photocatalytic Activity

  • Pawar, R.C.;Lee, Jin-Yong;Kim, Eun-Jeong;Kim, Hyungsub;Lee, Caroline Sunyong
    • 한국재료학회지
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    • 제22권10호
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    • pp.504-507
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    • 2012
  • Synthesis of RGO (reduced graphene oxide)-CdS composite material was performed through CBD (chemical bath deposition) method in which graphene oxide served as the support and Cadmium Sulfate Hydrate as the starting material. Graphene-based semiconductor photocatalysts have attracted extensive attention due to their usefulness for environmental and energy applications. The band gap (2.4 eV) of CdS corresponds well with the spectrum of sunlight because the crystalline phase, size, morphology, specic surface area and defects, etc., of CdS can affect its photocatalytic activity. The specific surface structure (morphology) of the photocatalyst can be effective for the suppression of recombination between photogenerated electrons and holes. Graphene (GN) has unique properties such as a high value of Young's modulus, large theoretical specific surface area, excellent thermal conductivity, high mobility of charge carriers, and good optical transmittance. These excellent properties make GN an ideal building block in nanocomposites. It can act as an excellent electron-acceptor/transport material. Therefore, the morphology, structural characterization and crystal structure were observed using various analytical tools, such as X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and Raman spectroscopy. From this analysis, it is shown that CdS particles were well dispersed uniformly in the RGO sheet. Furthermore, the photocatalytic property of the resulting RGO-CdS composite is also discussed in relation to environmental applications such as the photocatalytic degradation of pollutants. It was found that the prepared RGO-CdS nanocomposites exhibited enhanced photocatalytic activity as compared with that of CdS nanoparticles. Therefore, better efficiency of photodegradation was found for water purification applications using RGO-CdS composite.

혼합 작동 유체를 이용한 진동 세관형 히트 파이프의 압력 진동과 열전달 특성에 관한 연구 (The Study on Pressure Oscillation and Heat Transfer Characteristics of Oscillating Capillary Tube Heat Pipe Using Mixed Working Fluid)

  • 정현석;김정훈;김주원;김종수
    • 대한기계학회논문집B
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    • 제26권2호
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    • pp.318-327
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    • 2002
  • In this paper, heat transfer and pressure oscillation characteristics on oscillating capillary tube heat pipe(OCHP) according to input heat flux, mixture ratio of working fluid and inclination angle were investigated and were compared single working fluid(R-142b) with binary mixture working fluid(R-142b-Ethano1). OCHP was made to serpentine structure of loop type with 10 turns by drilling the channels of length 220mm, width 1.5mm, and depth 1.5mm on the surface of brass plate. In this study, R-l42b and R-l42b-Ethanol were used as working fluids, the charging ratio of working fluids was 40(vol.%), the input heat flux to evaporating section was changed from 0.3W/㎠ to 1.8W/㎠, and mixture ratio of working fluid was R(100%), R(95%)-E(5%), R(90%)-E(10%), and R(85%)-E(15%). From the experimental results, it was found that the effective thermal conductivity of single working fluid was better than that of binary mixture working fluid. But, in case of binary mixture working fluid, critical heat flux was higher than that of single working fluid. And, the higher the mixture ratios of working fluid, the lower heat transfer performance. In case of pressure oscillation, as the inclination angle was lower, pressure wave was more irregular. These phenomena were more serious when the working fluid was binary mixture. Besides, when mixture ratio was higher, saturated pressure was increased, more irregular wave was observed and the mean amplitude was increased. For the same input heat flux, inclination angle and charging ratio, when pressure oscillation has sinusoidal wave, mean amplitude was small, and saturated pressure was low value, the heat transfer was excellent.

설비공학 분야의 최근 연구 동향: 2008년 학회지 논문에 대한 종합적 고찰 (Recent Progress in Air-Conditioning and Refrigeration Research: A Review of Papers Published in the Korean Journal of Air-Conditioning and Refrigeration Engineering in 2008)

  • 한화택;최창호;이대영;김서영;권용일;최종민
    • 설비공학논문집
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    • 제21권12호
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    • pp.715-732
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    • 2009
  • This article reviews the papers published in the Korean Journal of Air-Conditioning and Refrigeration Engineering during 2008. It is intended to understand the status of current research in the areas of heating, cooling, ventilation, sanitation, and indoor environments of buildings and plant facilities. Conclusions are as follows. (1) Research trends in thermal and fluid engineering have been surveyed in the categories of general fluid flow, fluid machinery and piping, new and renewable energy, and fire. Well-developed CFD technologies were widely applied in developing facilities and their systems. New research topics include fire, fuel cell, and solar energy. Research was mainly focused on flow distribution and optimization in the fields of fluid machinery and piping. Topics related to the development of fans and compressors had been popular, but were no longer investigated widely. Research papers on micro heat exchangers using nanofluids and micro pumps were also not presented during this period. There were some studies on thermal reliability and performance in the fields of new and renewable energy. Numerical simulations of smoke ventilation and the spread of fire were the main topics in the field of fire. (2) Research works on heat transfer presented in 2008 have been reviewed in the categories of heat transfer characteristics, industrial heat exchangers, and ground heat exchangers. Research on heat transfer characteristics included thermal transport in cryogenic vessels, dish solar collectors, radiative thermal reflectors, variable conductance heat pipes, and flow condensation and evaporation of refrigerants. In the area of industrial heat exchangers, examined are research on micro-channel plate heat exchangers, liquid cooled cold plates, fin-tube heat exchangers, and frost behavior of heat exchanger fins. Measurements on ground thermal conductivity and on the thermal diffusion characteristics of ground heat exchangers were reported. (3) In the field of refrigeration, many studies were presented on simultaneous heating and cooling heat pump systems. Switching between various operation modes and optimizing the refrigerant charge were considered in this research. Studies of heat pump systems using unutilized energy sources such as sewage water and river water were reported. Evaporative cooling was studied both theoretically and experimentally as a potential alternative to the conventional methods. (4) Research papers on building facilities have been reviewed and divided into studies on heat and cold sources, air conditioning and air cleaning, ventilation, automatic control of heat sources with piping systems, and sound reduction in hydraulic turbine dynamo rooms. In particular, considered were efficient and effective uses of energy resulting in reduced environmental pollution and operating costs. (5) In the field of building environments, many studies focused on health and comfort. Ventilation. system performance was considered to be important in improving indoor air conditions. Due to high oil prices, various tests were planned to examine building energy consumption and to cut life cycle costs.

설비공학 분야의 최근 연구 동향 : 2013년 학회지 논문에 대한 종합적 고찰 (Recent Progress in Air-Conditioning and Refrigeration Research : A Review of Papers Published in the Korean Journal of Air-Conditioning and Refrigeration Engineering in 2013)

  • 이대영;김사량;김현정;김동선;박준석;임병찬
    • 설비공학논문집
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    • 제26권12호
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    • pp.605-619
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    • 2014
  • This article reviews the papers published in the Korean Journal of Air-Conditioning and Refrigeration Engineering during 2013. It is intended to understand the status of current research in the areas of heating, cooling, ventilation, sanitation, and indoor environments of buildings and plant facilities. Conclusions are as follows. (1) The research works on the thermal and fluid engineering have been reviewed as groups of fluid machinery, pipes and relative parts including orifices, dampers and ducts, fuel cells and power plants, cooling and air-conditioning, heat and mass transfer, two phase flow, and the flow around buildings and structures. Research issues dealing with home appliances, flows around buildings, nuclear power plant, and manufacturing processes are newly added in thermal and fluid engineering research area. (2) Research works on heat transfer area have been reviewed in the categories of heat transfer characteristics, pool boiling and condensing heat transfer and industrial heat exchangers. Researches on heat transfer characteristics included the results for general analytical model for desiccant wheels, the effects of water absorption on the thermal conductivity of insulation materials, thermal properties of Octadecane/xGnP shape-stabilized phase change materials and $CO_2$ and $CO_2$-Hydrate mixture, effect of ground source heat pump system, the heat flux meter location for the performance test of a refrigerator vacuum insulation panel, a parallel flow evaporator for a heat pump dryer, the condensation risk assessment of vacuum multi-layer glass and triple glass, optimization of a forced convection type PCM refrigeration module, surface temperature sensor using fluorescent nanoporous thin film. In the area of pool boiling and condensing heat transfer, researches on ammonia inside horizontal smooth small tube, R1234yf on various enhanced surfaces, HFC32/HFC152a on a plain surface, spray cooling up to critical heat flux on a low-fin enhanced surface were actively carried out. In the area of industrial heat exchangers, researches on a fin tube type adsorber, the mass-transfer kinetics of a fin-tube-type adsorption bed, fin-and-tube heat exchangers having sine wave fins and oval tubes, louvered fin heat exchanger were performed. (3) In the field of refrigeration, studies are categorized into three groups namely refrigeration cycle, refrigerant and modeling and control. In the category of refrigeration cycle, studies were focused on the enhancement or optimization of experimental or commercial systems including a R410a VRF(Various Refrigerant Flow) heat pump, a R134a 2-stage screw heat pump and a R134a double-heat source automotive air-conditioner system. In the category of refrigerant, studies were carried out for the application of alternative refrigerants or refrigeration technologies including $CO_2$ water heaters, a R1234yf automotive air-conditioner, a R436b water cooler and a thermoelectric refrigerator. In the category of modeling and control, theoretical and experimental studies were carried out to predict the performance of various thermal and control systems including the long-term energy analysis of a geo-thermal heat pump system coupled to cast-in-place energy piles, the dynamic simulation of a water heater-coupled hybrid heat pump and the numerical simulation of an integral optimum regulating controller for a system heat pump. (4) In building mechanical system research fields, twenty one studies were conducted to achieve effective design of the mechanical systems, and also to maximize the energy efficiency of buildings. The topics of the studies included heating and cooling, HVAC system, ventilation, and renewable energies in the buildings. Proposed designs, performance tests using numerical methods and experiments provide useful information and key data which can improve the energy efficiency of the buildings. (5) The field of architectural environment is mostly focused on indoor environment and building energy. The main researches of indoor environment are related to infiltration, ventilation, leak flow and airtightness performance in residential building. The subjects of building energy are worked on energy saving, operation method and optimum operation of building energy systems. The remained studies are related to the special facility such as cleanroom, internet data center and biosafety laboratory. water supply and drain system, defining standard input variables of BIM (Building Information Modeling) for facility management system, estimating capability and providing operation guidelines of subway station as shelter for refuge and evaluation of pollutant emissions from furniture-like products.

머신 러닝을 사용한 열전도 문제에 대한 기능적 등급구조 설계 (Functionally Graded Structure Design for Heat Conduction Problems using Machine Learning)

  • 문윤호;김철웅;박순옥;유정훈
    • 한국전산구조공학회논문집
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    • 제34권3호
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    • pp.159-165
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    • 2021
  • 본 연구는 효과적인 열전도를위한 거시적 구조 구성과 단위 구조 변화의 동시 설계를 위한 위상 최적화 방법을 제시한다. 거시적 규모의 구조 내에서 위치에 따른 단위 구조의 형태 변화는 거시적 규모뿐만 아니라 미시적 단위의 설계도 가능하며 등방성 단위 구조를 사용하는 것보다 더 나은 성능을 제공할 수 있다. 이 결과로 두 구성을 결합한 기능적으로 등급의 복합 구조가 생성된다. 대표 체적 요소 (RVE) 방법은 형태 변화에 따른 다중 재료 기반 단위 구조의 다양한 열전도 특성을 얻기 위해 적용된다. RVE 분석 결과를 바탕으로 머신 러닝 기법을 이용하여 특정 형태의 단위 구조물의 물성치를 도출할 수 있다. 거시적 위상 최적화는 기존의 SIMP 방법을 사용하여 수행되며, 거시 구조를 구성하는 단위 구조는 동시 최적화 과정에 따라 열전도 성능을 향상시키기 위한 다양한 형태를 가질 수 있다. 제안된 방법의 효과를 확인하기 위해 열 컴플라이언스 최소화 문제의 수치예가 제공된다.