• Title/Summary/Keyword: effect of fluidity

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Effect of Phospholipid Zwitterionic Surfactant CDP-W on the Characteristics of Liposome (인지질계 양쪽성 계면활성제 CDP-W 첨가가 리포좀 특성에 미치는 영향)

  • Jeong Min Lee;Jong Choo Lim
    • Applied Chemistry for Engineering
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    • v.35 no.3
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    • pp.230-238
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    • 2024
  • In the present work, the interaction of lipid-based zwitterionic surfactant CDP-W with the vesicle membrane of phospholipids was investigated. For this purpose, interfacial properties such as critical micelle concentration (CMC) and surface tension were measured for the zwitterionic surfactant CDP-W and lecithin S100-3. The zeta potential of 1 wt% aqueous surfactant solutions was also measured as a function of pH to determine the iso-electric point of CDP-W surfactant, where the characteristic of CDP-W surfactant changes from a cationic surfactant to an anionic surfactant. Based on the iso-electric point measurement of CDP-W surfactant, the effects of pH change and CDP-W addition on the stability of S100-3 liposome systems were studied, such as average particle size, polydispersity index (PDI), and zeta potential. The effect of CDP-W on the fluidity characteristics of liposome membranes such as fluorescence anisotropy ratio, deformability, and melting point was investigated at pH 6 where the most stable liposomes were prepared to understand the effect of the fluidity of the liposome membrane on the encapsulation efficiency of active materials and the stability of liposome systems.

Effect of Ti, B, Zr Elements on Grain Refinement and Castability of Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe Casting Alloy (주조용 Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe 합금의 결정립 미세화와 주조특성에 미치는 Ti, B, Zr 첨가원소의 영향)

  • Kim, Heon-Joo;Park, Su-Min
    • Journal of Korea Foundry Society
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    • v.35 no.5
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    • pp.120-127
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    • 2015
  • The effects of Ti, B and Zr on grain refinement and castability were investigated in Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe alloy. Measurement of cooling curve and micro-structure observation were performed to analyze the effects of the addition of minor elements Ti, B and Zr during solidification. The prominence of effect on grain refinement was in increasing order for Ti, Zr and B element. Fine grain size and an increase of the crystallization temperature for ${\alpha}$-Al solution were evident as the amount of addition elements increased in this study. Addition of 0.15wt% Ti was most effective for grain refinement, and the resulting grain size of ${\alpha}$-Al solution for shell mold and steel mold were $72.3{\mu}m$ and $23.5{\mu}m$, respectively. Fluidity and shrinkage tests were perform to evaluate the castability of the alloy. Maximum fluidity length and minimum ratio of micro shrinkage were recorded for 0.15wt% Ti addition due to the effect of the finest grain size.

Effect of Fe, Mn Content on the Castability in Al-9wt%Si-Mg System Alloys for High Elongation (고신율 금형주조용 Al-9wt%Si-Mg계 합금의 주조특성에 미치는 Fe, Mn함량의 영향)

  • Kim, Heon-Joo;Jeong, Chang-Yeol
    • Journal of Korea Foundry Society
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    • v.33 no.6
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    • pp.233-241
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    • 2013
  • Effect of Fe and Mn contents on the castability of Al-9wt%Si-xMg-yFe-zMn alloy has been studied. The alloy was composed of ${\alpha}$-Al phase, Al+eutectic Si phase, ${\beta}$-Al5FeSi compound and chinese script ${\alpha}$-$Al_{15}(Mn,Fe)_3Si_2$ compound. ${\beta}$-$Al_5FeSi$ and ${\alpha}$-$Al_{15}(Mn,Fe)_3Si_2$ compounds assumed to effect the fluidity and shrinkage behaviors of the alloy during solidification due to the crystallization of ${\alpha}$-$Al_{15}(Fe,Mn)_3Si_2$ and ${\beta}$-$Al_5FeSi$ compounds above eutectic temperature. As Fe and Mn contents of Al-9wt%Si-0.3wt%Mg system alloy increased from 0.15wt% to 0.6wt% and from 0.3wt% to 0.7wt%, fluidity of the alloy decreased by 5.7% and 3.3%, respectively. And as Mg content of Al-9wt%Si-0.45wt%Fe-0.5wt%Mn system alloy increased from 0.3wt% to 0.4wt%, fluidity of the alloy decreased by 8.6%. When Fe content of the alloy increased from 0.15wt% to 0.6wt%, macro shrinkage ratio decreased from 6.1% to 4.1%, and micro shrinkage ratio increased from 0.04% to 0.24%. Similarly, Mn content of the alloy increased from 0.3wt% to 0.7wt%, macro shrinkage ratio decreased from 6.0% to 4.5% and micro shrinkage ratio increased from 0.12% to 0.18%. Judging from the castability of the alloy, Al-9wt%Si-0.3wt%Mg alloy with low content of Fe and Mn, 0.1wt% Fe and 0.3wt% Mn, is recommendable.

Effects of Dopamine.HCI on Structural Parameters of Bovine Brain Membranes

  • Bae, Moon-Kyoung;Huh, Min-Hoi;Lee, Seung-Woo;Kang, Hyun-Gu;Pyun, Jae-Ho;Kwak, Myeong-Hee;Jang, Hye-Ock;Yun, Il
    • Archives of Pharmacal Research
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    • v.27 no.6
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    • pp.653-661
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    • 2004
  • Fluorescence probes located in different membrane regions were used to evaluate the effect of dopamine$.$HCI on the structural parameters (transbilayer lateral mobility, annular lipid fluidity, protein distribution, and thickness of the lipid bilayer) of synaptosomal plasma membrane vesicles (SPMV), which were obtained from the bovine cerebral cortex. An experimental procedure was used based on selective quenching of 1,3-di(1-pyrenyl)propane (Py-3-Py) by trinitrophenyl groups, and radiationless energy transfer from the tryptophan of membrane pro-teins to Py-3-Py and energy transfer from Py-3-Py monomers to 1-anilinonaphthalene-8-sulfonic acid (ANS) was also utilized. Dopamine$.$HCI increased both the bulk lateral mobility and annular lipid fluidity, and it had a greater fluidizing effect on the inner monolayer than on the outer monolayer. Furthermore, the drug had a clustering effect on membrane proteins.

Evaluation of Metal-mold Reactions and Fluidity of TiAl Alloys (TiAl 합금의 주형계면반응 및 유동성 평가)

  • Lee, Sang-Hwa;Sung, Si-Young;Choi, Bong-Jae;Kim, Myoung-Gyun;Kim, Young-Jig
    • Journal of Korea Foundry Society
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    • v.26 no.2
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    • pp.98-103
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    • 2006
  • Metal-mold reactions between investment mold and TiAl alloys were investigated for the economic net-shape forming of TiAl alloys. The effect of mold preheating temperatures on the metal-mold reaction were investigated using a vacuum induction-melting furnace. In the case of TiAl alloys, there were no ${\alpha}$-case formation reactions. There were neither interstitial nor substitutional ${\alpha}$-case formations as TiAl alloys have both negligible solubility of oxygen and low activity in molten states. The fluidity of TiAl alloys increases with mold preheating temperature since they have a peritectic reaction that appears in the form of envelope, surrounding each particles of the primary constituent. The results of the investment casting of TiAl alloys confirm that the casting route in our study can be an effective approach for the economic net-shape forming of TiAl alloys.

The Effect of Melamine Sulphonate High-Range Water Reducing Agent to the Fluidity of High-Flowability Paste (고유동페이스트의 유동특성에 미치는 멜라민계 고성능가수제의 영향)

  • Nam Ji-Hyun;Cho Eun-Young;Oh Sang-Gyun;Kim Jung-Kil
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2005.11a
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    • pp.71-74
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    • 2005
  • The viscosity of high-flowability paste is very high compared to normal concrete for the low water-binder ratio(W/B). Therefore, high-flowability concrete is positively necessary to high-range water reducing agent. High-Flowability paste can make much higher fluidity with no occurrence of segregation, by its higher viscosity and lower yield value than normal concrete. The flowability of high-flowability paste must be evaluated not only by convention consistency test such as slump test but also by the base of the rheological properties of the fresh concrete. The purpose of this study is to analyze the fluidity of high-flowability paste according to the addition ratio of the Melamine Sulphonate high-range water reducing agent.; high-flowability paste is considered as Bingham plastic fluid with the rheology parameters of the plaste viscosity and yield value.

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Analysis on Basic Characteristics of Mortar with Pre-Mix Cement (프리믹스 시멘트를 사용한 모르터의 기초적 특성 분석)

  • Jin, Cheng-Ri;Jang, Ki-Hyun;Lee, Chung-Sub;Han, Dong-Yeop;Kim, Ki-Hoon;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.05a
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    • pp.93-97
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    • 2008
  • The study analyzed on each kind of basic characteristics in mortar to prove an effect of pre-mix cement, ultra high strength binder. The results were as follows. in characteristics of not set mortar, fluidity time was the quickest at the time of using POBSA and was more delayed at the time of using Fly Ash than at the time of using Blast Furnace Slag as a binder. Mortar ring flow and flow con flow got smaller as fluidity time got longer, on the contrary to fluidity time. Unit capacity mass was smaller at the time of using Fly Ash than at the time of using Blast Furnace Slag. According to pre-mix, it was difficult to discover a regular tendency. In characteristics of hardening mortar, the 28th day compressive strength was better than thing mixed after measuring separately in pre-mix. According to a binder's kind, Silica Fume B, C was better than Silica Fume A.

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Rheological Characteristics of Fiber-Reinforced High-Strength AFR Concrete (섬유보강 고강도 내화콘크리트의 레올로지 특성 분석)

  • Choi, Sun-Mi;Lee, Bum-Sik;Bae, Kee-Sun;Kim, Sang-Yun;Park, Su-Hee
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.543-544
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    • 2009
  • The fiber(NY, PP) known to the effective material on improvement of the fire-resistance of HSC(high strength concrete) has a difference for fluidity according to the variation of a length and contents of fiber. In this study, to analyze the effect of a length and contents of the fiber on the fluidity of HSC and fheological characteristics, we calculated a viscosity of mortar by mini slump-flow, simple V-lot and viscometer. With the test results, the fluidity characteristic showed a moderate difference by a length and contents of the fiber, but showed a significant difference by increase of the fiber contents. ${\ast}$ AFR Concrete (Advenced Fire Resistant Concrete)

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The Effect of Adding Soybean Oil on the Fluidity of Garlic Chunggukjang Paste (대두유 첨가량이 마늘청국장 페이스트의 유동성에 미치는 영향)

  • Lee, Eun-Kyung;Kim, Kyeong-Yee
    • Korean journal of food and cookery science
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    • v.23 no.3 s.99
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    • pp.288-293
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    • 2007
  • In this study, chunggukjang was made from soybeans and Bacillus natto. This chunggukjang was meant to be consumed as a margarine and butter substitute, to help lower trans-fatty acid (TFA) intake. A freeze-dried garlic product was used during fermentation to aid in removing the smell of the chunggukjang. Chunggukjang has a very low fluidity due to its high viscosity; therefore, we added 3%(w/w) soybean oil to improve the fluidity. We found that the TFA content of the garlic chunggukiang paste was no more than 0.02${\sim}$0.05%, which was low compared to the usual contents of margarine and butter. After 4 weeks of storage the TFA content was 0.03${\sim}$0.08%, and it remained within the limits of the permissible amount. The addition of soybean oil allowed this chunggukjang to be made with greater ease, and the freeze-dried garlic eliminated the negative inherent qualities of the chunggukjang. Therefore, this garlic chunggukjang paste could be considered reasonable for commercial production.