• 제목/요약/키워드: effect of film composition

검색결과 312건 처리시간 0.026초

2성분 혼합물질의 층류 막비등에서 복사열전달의 효과 (Effect of Radiation on Laminar Film Boiling of Binary Mixtures)

  • 성현찬;김경훈
    • 설비공학논문집
    • /
    • 제16권10호
    • /
    • pp.942-951
    • /
    • 2004
  • This paper presents the results of a theoretical study of the effect of radiation during free convective laminar film boiling for methanol/water binary mixtures on an isothermal vertical wall at atmospheric pressure. With the well-known boundary layer theory as a basis, a theoretical model has been formulated into consideration for mass diffusion at liquid phase. The equations are numerically solved by a similarity method to investigate the effects of radiation emissivity on the surface with various parameters such as wall superheat and composition of more volatile component at liquid phase far from the wall. From the results, the distributions of the physical quantifies are investigated in both phases. New correlations are proposed to predict the heat transfer coefficient of binary mixtures. It is shown that the proposed correlations are in good agreement with numerical results and with Bromley's correlation within maximum $11\%$ errors. It is also found that as the wall superheat is increased, radiation effect becomes more important.

n-type $CuGaS_2$ 3원 화합물 박막의 제작과 분석에 관한 연구 (A Study on the properties and Fabrication of n-type $CuGaS_2$ Ternary Compound thin film)

  • 양현훈;백수웅;나길주;소순열;박계춘;이진;정해덕
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2009년도 하계학술대회 논문집
    • /
    • pp.467-468
    • /
    • 2009
  • For the manufacture of the $CuGaS_2$, Cu, Ga and S were vapor-deposited in the named order. Among them, Cu and Ga were vapor-deposited by using the Evaporation method in consideration of their adhesive force to the substrate so that the composition of Cu and Ga might be 1 : 1, while the surface temperature having an effect on the quality of the thin film was changed from R.T.[$^{\circ}C$] to $150[^{\circ}C$] at intervals of 50[$^{\circ}C$]. As a result, at 300[$^{\circ}C$]of the Annealing temperature, their chemical composition was measured in the proportion of 1 : 1 : 2. It could be known from this experimental result that it is the optimum condition to conduct Annealing on the $CuGaS_2$ thin film under a vacuum when the $CuGaS_2$ thin film as an optical absorption layer material for a solar cell is manufactured.

  • PDF

무전해 동도금 피막의 접착력 향상에 관한 연구 - PET 필름의 전처리 조건의 영향 - (Adhesion Improvement of Electroless Copper Plated Layer on PET Film - Effect of Pretreatment Conditions -)

  • 오경화;김동준;김성훈
    • 폴리머
    • /
    • 제25권2호
    • /
    • pp.302-310
    • /
    • 2001
  • 무전해도금법을 이용하여 구리/PET 필름 복합재료를 제조하였으며 에칭방법과 촉매액의 조성 및 acceleration 방법을 달리하여 PET 필름과 무전해도금된 구리 피막간의 접착력을 향상시키고자 하였다. HCl 용액으로 에칭된 PET 필름은 NaOH에 의한 것보다 더욱 세밀하게 에칭되어져 구리와 PET 필름간의 접착력은 향상되었으나 전자파 차폐효과는 유사한 경향을 보였다. 촉매액의 조성변화에 따른 영향을 살펴본 결과 PdCl$_2$:SnCl$_2$의 몰비가 1:4에서 1:16으로 증가할수록 PET 필름 위에 적층된 Pd/Sn 콜로이드 입자들의 크기가 감소하며 고르게 분포되는 경향을 보였다. 따라서 이들의 몰비가 증가할수록 구리도금이 균일하고 조밀하게 이루어져 접착력 및 차폐효과가 증가하였다. 또한 NaOH보다 HCl로 acceleration한 경우 촉매 입자의 크기가 작고 더 균일하게 분포되어 우수한 접착력과 도금물성을 나타내었다.

  • PDF

CBD법에 의한 ZnS 박막 성장의 하이드라진 효과 (Effect of Hydrazine as a Complex Agent on the Growth of ZnS Thin Film by Using Chemical Bath Deposition (CBD))

  • 이차란;김제하
    • 한국전기전자재료학회논문지
    • /
    • 제31권3호
    • /
    • pp.177-181
    • /
    • 2018
  • We prepared ZnS thin films via chemical bath deposition (CBD) in an aqueous solution of ammonia ($NH_3$) and hydrazine ($N_2H_4$). The composition ratio of hydrazine used was 0%, 17%, 22%, 29%, or 50%. We investigated the effects of hydrazine and ammonia on the growth, and the structural and optical properties of ZnS in terms of surface uniformity, voids, and grain size. We found that during the growth of ZnS films, hydrazine was very effective for improving the surface morphology and layer uniformity with fast layer formation, while it had no effect on the bandgap energy, $E_g$.

SHAPE MEMORY THIN FILM OF TITANIUM-NICKEL FOR MICROACTUATOR FORMED BY SPUTTERING

  • Takei, A.;Ishida, A.
    • 한국표면공학회지
    • /
    • 제29권5호
    • /
    • pp.424-429
    • /
    • 1996
  • Thin films of Ti-Ni alloy were formed by sputtering under various Ar gas pressures and r. f. powers to investigate the optimum sputtering conditions and to demonstrate their shape memory effect. The composition and structure of the films were examined by electron micro-probe analysis and scanning electron microscope. These films were annealed in order to crystallize them. The mechanical property of the annealed films was evaluated by a conventional bending test. The transformation tmeperatures were determined by differential scanning calorimetry. The shape memory behaviour was examined quantiatatively by changing in sample temperature under various constant loads. It was found that the Ar gas pressure had a critical effect on the mechanical property of the thin film,s although the r.f. power also affected it. The films formed at a high Ar gas pressure were too brittle to be bent successfully. However, the films formed at a low Ar gas pressur could be bent and their shape memory behavior was found to be comparable with that of bulk Ti-Ni alloys.

  • PDF

The Effect of Plasma Power on the Composition and Microhardness of a-SiC:H Films Grown by PECVD

  • Lee, Young-Ku-K;Kim, Yunsoo
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 1999년도 제17회 학술발표회 논문개요집
    • /
    • pp.123-123
    • /
    • 1999
  • Amorphous hydrogenated silicon carbide (a-SiC:H) films were deposited at the temperature of 40$0^{\circ}C$ using plasma enhanced chemical vapor deposition. The a-SiC:H films were characterized by x-ray photoelectron spectroscopy (XPS) and nanoindentation method. By increasing the plasma power from 20W to 160W, the oxygen content of the a-SiC:H films were observed to decrease from 12.1% to 4.4%. On the other hand, the plasma power did not affect the ratio of carbon to silicon in our experiment where the 1, 3-disilabutane was used as the precursor. Microhardness of the films was observed to increase as the plasma power increased, while the elastic modulus was observed to gave a maximum value at the plasma power of 80W. Microhardness of the film is thought to be strongly affected by the content of adventitious oxygen in the film and it is concluded that the hardness of the film can be improved by increasing the plasma power.

  • PDF

Transparent Conducting Zinc-Indium Oxides Thin Films by an Electron Beam Evaporation Method

  • Lee, Choon-Ho;Kim, Sun-Il
    • 한국세라믹학회지
    • /
    • 제41권2호
    • /
    • pp.102-105
    • /
    • 2004
  • ZnO-In$_2$O$_3$ films were fabricated on Corning 1737 glass substrate by an electron beam evaporation technique and their characteristics were investigated. The composition of ZnO-In$_2$O$_3$ films had a marked effect on the electrical properties of the films. The ZnO-In$_2$O$_3$ films showed superior transparent-conducting characteristics with increase of Zn content. The resistivity and carrier concentration of the film having Zn content of 45 at% are 4.45${\times}$10$^{-3}$ cm and 3.1${\times}$10$^{19}$ cm$^{-3}$ , respectively. Also, the transmittance was higher than 80% throughout the visible range. The average roughness of the film was 14.6 $\AA$ in terms of root mean square.

PZT의 무전해 니켈도금의에 미치는 액조현성의 영향 (Effect od solution composition on electroless Ni plating on PZT)

  • 김제경;이명훈;문경만
    • 한국표면공학회지
    • /
    • 제31권4호
    • /
    • pp.209-216
    • /
    • 1998
  • It is well knownthat electroledd plating is the desirable surface treatment method which is being widely used to all kinds of material such as requiring corrosing resistance, wear resistance and conductivity, especially nonconductivity materials' surface plating. However, it is suggested that there are some problems that must be solved, for exaple, rate of plating, corrosion resistance, thickness of plating film etc. Therefore in this paper, when electroless nickel plating was performed on the PZT(Pb(Zr,Ti))with varying of solution composition such as NaOH, and $H_2NCH_2COOH$, the effect of the rate of plating and corrosion resistance were investigated.

  • PDF

비정질 (Se,S)를 기본으로 한 칼코게나이드 박막의 Grating 형성과 광특성에 관한 연구 (A Study on the Grating Foemation and Optical Properties of Amorphous (Se,S)-based Chalcogenide Thin Films)

  • 박태성;정홍배;김종빈
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1988년도 춘계학술대회 논문집
    • /
    • pp.20-23
    • /
    • 1988
  • Effect of light irradiation on evaporated chalcogenide glass films of an As-Se-S-Ge system has been studied. Utiling this characteristics diffraction grating of the amorphous film was obtained. Parameters such as film thickness, composition, and exporsure time influencing the diffraction efficiency were also studied. The maximum value of the diffraction efficiency achieved was 4.6% in an $As_{75}Se_{15}S_{35}-Ge_{10}$ film.

  • PDF

Cu-Ni계 박막 스트레인 게이지의 개발 (Development of Cu-Ni Thin Film Strain Gages)

  • 민남기;이성래;김정완
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1996년도 하계학술대회 논문집 C
    • /
    • pp.1544-1546
    • /
    • 1996
  • Thin films of Cu-Ni alloys of various compositions were prepared by RF sputtering onto glass and stainless steel substrates. The effect of composition, substrate temperature, Ar partial pressure, aging time on the electrical properties of Cu-Ni film strain gages in the thickness range $500{\sim}2000{\AA}$ was studied. The maximum resistivity is obtained from 53wt%Cu-47wt%Ni films, while their TCR becomes minimum. This tendency is very desirable for thin film strain gages.

  • PDF