• Journal of the Korean institute of surface engineering
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• v.48 no.2
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• pp.62-67
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• 2015

Nickel is a commercially important and versatile element in electroplating. The applications of nickel electroplating fall into three main categories: decorative, functional and electroforming. In decorative applications, electroplated nickel is most often applied in combination with electrodeposited chromium. Nickel is deposited on surfaces to improve corrosion and wear resistance or modify magnetic and other properties. Electroforming is electroplating applied to the fabrication of products of various kinds. Nickel is deposited onto a substrate and then removed from it to create a part made entirely of nickel. In this study, mechanical property of Ni electrodeposits in various manufacturing condition such as temperature, current density, pH and electrolyte content, was investigated to understand effect of electrolysis condition on mechanical property. Vickers hardness increased as the temperature and pH increased and current density and electrolyte content decreased and pH increased. The results were explained by cathode overvoltage and hydrogen evolution.

• Journal of Advanced Marine Engineering and Technology
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• v.41 no.3
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• pp.276-280
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• 2017

In this study, we investigated the effect of sterilization and the neutralization of treated ballast water using seawater electrolysis. The electrolysis apparatus has a cation-selective membrane for passing the cation and a titanium electrode in each cell. We examined the sterilization effect after an incubation period of 24 hr. The oxidation reaction during electrolysis caused, the solution to become strongly acidic due to the generation of a hydroxyl group, and the oxidation reduction potentials(ORP) was increased to 800 - 1200mV. After the reduction reaction, the solution became alkaline(pH 9 - 12), and ORP was decreased to - 900 - - 750 mV. It might be possible to control the pH of ballast water through electrolysis. In addition, we demonstrated the effects of sterilization of ballast water containing generated hypochlorous acid using electrolysis under high ORP condition.

• Journal of Biosystems Engineering
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• v.34 no.4
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• pp.234-242
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• 2009

This study was attempted to develop surface washing-system of ginseng. The effect of sterilization, washing and keeping freshness of ginseng through analyzing unit process were examined to establish optimal condition for washing system. Surface washing method of fresh ginseng used two way and full cone spray type. Sterilization was used at $2^{\circ}C$ water with electrolysis water of 50 and 80 ppm. Ginseng was sterilized with electrolysis water during 30 and 60 s, dehydrated during 1 min and dried during 1min at 30 and $50^{\circ}C$. Hardness of surface-washed ginseng showed good result on 1 min spraying time with 80 ppm electrolysis water at $10^{\circ}C$ storage. Ginseng with 80 ppm electrolysis water was sterilized better with $1.05{\times}103$. There are no changes with 0% on appearance quality at 80 ppm electrolysis.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 1999.05a
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• pp.135-135
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• 1999

• Journal of the Korea Organic Resources Recycling Association
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• v.31 no.4
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• pp.41-49
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• 2023

This study examined the effect of input substrate concentration on hydrogen production of microbial electrolysis cells. To compare the performance of MEC according to the input substrate concentration, six laboratory-scale MEC reactors were operated by sequentially increasing the input substrate concentration from 2 g/L of sodium acetate, to 4 g/L, and 6 g/L. The current density, hydrogen production, and SCOD removal rate were analyzed, and energy efficiency and cathodic hydrogen recovery were calculated to compare the performance of MEC. The maximum volumetric current density was obtained at 4 g/L condition (76.3 A/m³) and it decreased to 19.0 A/m³, when the input concentration was increased to 6 g/L, which was a 75% decrease compared to the 4 g/L input condition. Maximum hydrogen production was obtained also at 4 g/L condition (47.3 ± 16.8 mL), but maximum hydrogen yield was obtained at 2 g/L input condition (1.1 L H₂/g COD_in). Energy efficiencies were also highest in 2 g/L condition; the lowest result was observed at 6 g/L condition. Maximum electrical energy efficiency was 76.4%, and the maximum overall energy efficiency was 39.7% at 2 g/L condition. However, when the substrate concentration increased to 6 g/L, the performance was drastically decreased. Cathodic hydrogen recovery also showed a similar tendency with energy efficiency, with the lowest concentration condition showing the best performance. It can be concluded that operating at low input substrate concentration might be better when considering not only hydrogen yield but also energy efficiency.

• Korean Chemical Engineering Research
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• v.61 no.1
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• pp.19-25
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• 2023

Although a lot of research and development has been conducted on the performance improvement of PEM (Proton Exchange Membrane) water electrolysis, the research on durability is still in early stage. This study investigated effect of temperature on the water electrolysis durability when driving temperature of the PEM water electrolysis was increased to improve performance. Voltage change, I-V, CV (Cyclic Voltammetry), LSV (Linear Sweep Voltammetry), Impedance, and FER (Fluoride Emission Rate) were measured while driving under a constant current condition in a temperature range of 50~80 ℃. As the operating temperature increased, the degradation rate increased. At 50~65 ℃, the degradation of the IrO₂ electrocatalyst mainly affected the durability of the PEM water electrolysis cell. At 80 ℃, the polymer membrane and electrode degradation proceeded similarly, and the short resistance decreased to 1.0 kΩ·cm² or less, and the performance decreased to about 1/3 of the initial stage after 144 hours of operation due to the shorting phenomenon.

• Transactions of the Korean hydrogen and new energy society
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• v.17 no.2
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• pp.141-148
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• 2006

This study was carried out to analyze the microstructure characteristics of electrolyte membrane through XRD, SEM and AC impedance measurement for using in high temperature steam electrolysis(HTE). It was investigated that thermal stability and electric characteristics by sintering condition using dry and wet process, and confirmed growth of particle and density change by sintering temperature. The sintering temperature and behavior had an effect on the relative density of the ceramic and the average grain size. The more amount of dispersant in organic compound increase, the more the density increased. But the binder was shown opposite phenomenon. It was analyzed that electrolyte resistance and electrical characteristics using AC impedance. The electrical properties of YSZ grain boundary changed with the sintering temperature.

• Journal of the Korean institute of surface engineering
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• v.27 no.5
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• pp.285-291
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• 1994

The effects of pulse current parameters on the composition and the microstructure of Pd-Ni alloy electrodeposits were studied. The cathode current efficiency of p.c. electrolysis conditions decreased with increasing both mean and peak current density and was lower than those under D.C. electrolysis condition. Palladium content of Pd-Ni alloy increased with increasing both peak current density and on-time, while it decreased with increasing mean current density and duty cycle. The preferred orientation of Pd-Ni alloys changed with increasing mean current density in the sequence of (111)+(110).(100) or (110)longrightarrow(111)longrightarrow(100) or random distribution of crystal structure. The surface morphology of Pd-Ni alloy changed mainly according to the mean current density and was related to the preferred orientation.

• Journal of Korean Society of Water and Wastewater
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• v.27 no.5
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• pp.547-554
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• 2013

Chlorine has strong oxidizing power, also it is many advantages over other disinfectants such as the residual characteristic and economic feasibility. However, chlorine also has disadvantages such as creating disinfection by-products of chlorine as THMs. In particular, the most deadly disadvantage of chlorine is that it is extremely poisonous toxins about all alive lives. Disinfection with electrolysis water can be a very useful way Because you do not have to worry about chlorine's dangerous. In this study, we evaluated the potential as a disinfectant, across the evaluating disinfection effect and generating characteristic of by-products. The electrolyzed water could be obtained removal efficiencies of over 99.9 % the coliform by operating condition such as residence time, current density (voltage), the electrode gap. The residual chlorine be generated 10,000 mg/L in current density $1.0A/dm^2$ and residence time of 10 minutes. The residual chlorine concentration was possible to maintain a stable. The by-products generated by high concentration residual chlorine in the reactor such as trihalomethanes, haloaceticacid, chloralhydrate, haloacetonitrile were detected in less than a water quality standards. At the concentration of less than residual chlorine of 1 ppm, the chlorine disinfection by-products be generated most below the detection limit.

• Applied Chemistry for Engineering
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• v.28 no.2
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• pp.257-262
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• 2017

In this study, CNF (carbon nanofiber) was prepared with different process variables of electrospinning method. Morphology of CNF was observed by SEM, and main parameters to form the CNF were applied voltage, TCD, polymer concentration and heat treatment condition. Comparison of toluene removal efficiency, as applying the prepared CNF to electrodes of an electrolysis process, showed the direct effect of cathode on electrolysis as well as anode.