• Journal of Adhesion and Interface
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• v.17 no.2
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• pp.49-55
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• 2016

In this study, we designed an environment friendly, water-based adhesive using the acrylic emulsion method as a replacement for solvent-based adhesives, which are most commonly used in layered laminates for flexible food packaging. We designed adhesives with different combinations of anionic, non-ionic, and phosphoric ester surfactants, and with different concentrations of chain transfer agent (CTA). We also examined the effect of the degree of cross-linking by synthesizing and comparing 8 test group adhesives with different types of functional monomers. Additionally, we synthesized 2 other test group pressure-sensitive adhesives (PSA) using styrene/alpha-methyl styrene/acrylic acid (SAA) semipolymer dispersing agents (with molecular weights of 13,000 g/mol and 8,600 g/mol, respectively) to replace the conventional surfactants. We evaluated whether the 10 test group pressure-sensitive adhesives met the basic physical property criteria required for flexible food packaging by carrying out a physical analysis of their glass transition temperature (Tg), particle size, adhesion, and molecular weight. In our test, 2 test group adhesives manufactured with the combination of anionic and non-ionic surfactants, CTA concentration of 0.2%, and functional monomers of hydroxyethyl acrylate (HEA) and glycidyl methacrylate (GMA) demonstrated molecular weight and flexibility suitable for flexible packaging, with low adhesiveness and small particle size.

• Advances in concrete construction
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• v.10 no.2
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• pp.93-104
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• 2020

Basalt fiber is an eco-friendly fiber and comparatively newer to the world of fiber-reinforced polymer (FRP) composites. A limited number of studies have been reported in the literature on the strengthening of reinforced concrete (RC) beams with basalt fiber reinforced polymer (BFRP). The present experimental work explores the feasibility of using the BFRP strips for shear strengthening of the RC beams. The strengthening schemes include full wrap and U-wrap. A simple mechanical anchorage scheme has been introduced to prevent the debonding of U-wrap as well as to utilize the full capacity of the BFRP composite. The effect of varying shear span-to-effective depth (a/d) ratio on the behavior of shear deficient RC beams strengthened with BFRP strips under different schemes is examined. The RC beams were tested under a four-point loading system. The study finds that the beams strengthened with and without BFRP strips fails in shear for a/d ratio 2.5 and the enhancement of the shear capacity of strengthened beams ranges from 5% to 20%. However, the strengthened beams fail in flexure, and the control beam fails in shear for a higher a/d ratio, i.e., 3.5. The experimental results of the present study have been compared with the analytical study and found that the latter gives conservative results.

• Journal of the Korean Society for Marine Environment & Energy
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• v.10 no.3
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• pp.181-186
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• 2007

Despite of environmental problems(safety hazards), mechanical recycling of FRP boats, which involves shredding and grinding of the scrap FRP in a new product. is one of the simpler and more technically proven methods than incineration or reclamation ones. Because FRP is made up of reinforced fiber glass, it is very difficult to break into pieces. It also occurs secondary problem such as air pollution and unacceptable shredding noise level. The another urgent problem which is a serious barrier to FRP recycling is very limited reusable applications. This study is to propose a new method which is efficient and environment friendly waste FRP regenerating system. And it also have shown the polymer cement and fiber-reinforced concrete applications with the waste FRP.

• Composites Research
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• v.22 no.4
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• pp.41-49
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• 2009

Natural fiber reinforced composites are emerging as low-cost, lightweight, recyclable, and eco-friendly materials. These are biodegradable and non-abrasive. Due to eco-friendly and biodegradable characteristics of natural fibers, they are being considered as potential candidates to replace the conventional fibers. The chemical, mechanical, and physical properties of natural fibers have distinct features depending upon the cellulose content of the fibers which varies from fiber to fiber. The mechanical properties of composites are influenced mainly by the adhesion between matrix and fibers. Several chemical and physical modification methods of fiber surface were incorporated to improve the tiber-matrix adhesion resulting in the enhancement of mechanical properties of the composites. This paper outlines the works reported on natural tiber reinforced composites with special reference to the type of fibers, polymer matrix, processing techniques, treatment of fibers, and fiber-matrix interface.

• Elastomers and Composites
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• v.54 no.3
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• pp.220-224
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• 2019

Herein, three polymer compounds were manufactured using three polymer combination methods, ethylene-vinyl acetate/ethylene-propylene-diene-copolymer (EPDM), ethylene-vinyl acetate (EVA)/polyethylene-A (PE-A; density: 0.870), and ethylene-vinyl acetate (EVA)/polyethylene-B (PE-B; density: 0.885), for making cable sheath for use in the shipping industry. In this study, EVA, EPDM, PE-A, and PE-B were used as matrix polymers, and EVA-grafted maleic anhydride was used as a coupling agent for compounding with various compounds such as a fire retardant, cross-linking agent, filler, and other additives, besides the plasticizer. ${\Delta}T$, Mooney viscosity, and tensile strength increased in order of EPDM < PE-A < PE-B, the probable reason is due to the different crosslinking effect. The three compounds showed similar results for fire resistance and aging resistance after compounding process, but they showed excellent cold resistance owing to the non-polarity of the polymers and sufficient plasticizer content.

• Current Applied Physics
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• v.18 no.11
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• pp.1300-1305
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• 2018

The tunable electronic performance of the solution-processed semiconductor metal oxide is of great significance for the printing electronics. In current work, transparent thin-film transistors (TFTs) with indium-zinc oxide (IZO) were fabricated as active layer by a simple eco-friendly aqueous route. The aqueous precursor solution is composed of water without any other organic additives and the IZO films are amorphous revealed by the X-ray diffraction (XRD). With systematic studies of atomic force microscopy (AFM), X-ray photoemission spectroscopy (XPS) and the semiconductor property characterizations, it was revealed that the electrical performance of the IZO TFTs is dependent on the concentration of precursor solution. As well, the optimum preparation process was obtained. The concentrations induced the regulation of the electronic performance was clearly demonstrated with a proposed mechanism. The results are expected to be beneficial for development of solution-processed metal oxide TFTs.

• Advances in concrete construction
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• v.13 no.2
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• pp.183-190
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• 2022

A wide range of experimental bases and improved performance with different forms of Fiber Reinforced Polymer (FRP) have attracted researchers to produce eco-friendly and sustainable structures. The reinforced concrete (RC) beam's shear capacity has remained a complex phenomenon because of various parameters affecting. Design recommendations for the shear capacity of RC elements having FRP reinforcement need a more experimental database to improve design recommendations because almost all the recommendations replace different parameters with FRP's. Steel and FRP are fundamentally different materials. One is ductile and isotropic, whereas the other is brittle and orthotropic. This paper presents experimental results of the investigation on the beams with glass fiber reinforced polymer (GFRP) reinforcement as longitudinal bars and stirrups. Total twelve beams with GFRP reinforcement were prepared and tested. The cross-section of the beams was rectangular of size 230 × 300 mm, and the total length was 2000 mm with a span of 1800 mm. The beams are designed for simply-supported conditions with the two-point load as per specified load positions for different beams. Flexural reinforcement provided is for the balanced conditions as the beams were supposed to test for shear. Two main variables, such as shear span and spacing of stirrups, were incorporated. The beams were designed as per American Concrete Institute (ACI) ACI 440.1R-15. Relation of VExp./VPred. is derived with axial stiffness, span to depth ratio, and stirrups spacing, from which it is observed that current design provisions provide overestimation, particularly at lower stirrups spacing.

• Membrane Journal
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• v.29 no.3
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• pp.173-182
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• 2019

Much research has been made for finding new and eco-friendly alternative sources of energy to solve the problems related with the pollution caused by emissions of greenhouse gases such as carbon dioxide as the use of fossil fuels increases worldwide. Among them, fuel cells draws particular interests as an eco-friendly energy generator because only water is obtained as a by-product. Anion exchange membrane-based alkaline fuel cell (AEMFC) that uses anion exchange membrane as an electrolyte is of increased interest recently because of its advantages in using low-cost metal catalyst unlike the PEMFC (potton exchange membrane fuel cell) due to the high-catalyst activity in alkaline conditions. The main properties required as an anion exchange membrane are high hydroxide conductivity and chemical stability at high pH. Recently we reported a chemically crosslinked poly(2-dimethyl-1,4-phenylene oxide) (PPO) by reacting PPO with N,N,N',N'-tetramethyl-1,6-hexanediamine as novel anion exchange membranes. In the current work, we further developed the same crosslinked polymer but having enhanced physicochemical properties, including higher conductivity, increased mechanical and dimensional stabilities by using the PPO with a higher molecular weight and also by increasing the crosslinking density. The obtained polymer membrane also showed a good cell performance.

• Textile Coloration and Finishing
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• v.33 no.4
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• pp.191-201
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• 2021

In this study, an eco-friendly indigo reduction system(scale up reduction, use of buffer solution, and pH control) using baker's yeast(Saccharomyces cerevisiae) was applied for natural indigo(Polygonum tinctorium) dyeing of Hanji fabric and Hanji-mixture fabric(Hanji/Cotton, Hanji/Silk). The effect of concentration of baker's yeast, repeat dyeing, and bath reuse was investigated in terms of dye uptake indicating reduction power. And the oxidation-reduction potential(ORP) was monitored. We also evaluated color properties and colorfastness according to the color strength. The yeast concentration did not significantly affect the maximum reduction power. However, the highest yeast concentration was effective in improving the initial dye uptake, and its the reduction retention power was the most excellent. Even on the last reduction day, the effect of increasing the dye uptake by repeat dyeing was observed. And it was confirmed that the reduction bath could be reused for up to 30 days by supplementing yeast at the end of reduction. For all the fabrics used, deeper and darker PB color were obtained by repeat dyeing. As dyeing was repeated, purplish tint got stronger on the Hanji/Silk fabric compared to other fabrics. Regardless of the composition of Hanji fabrics and color strength, washing and dry cleaning fastness were relatively good with above rating 4-5, and fastness to rubbing and light were acceptable with a rating 3-4 ~ 4-5. The eco-friendly natural indigo dyeing process using niram and baker's yeast would offer global marketability and diversity of Hanji product as a sustainable high value-added material.

• Membrane Journal
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• v.32 no.5
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• pp.275-282
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• 2022

In contemporary days, hydrogen-based energies including batteries are renowned to be effective. And its effectiveness comes from the fact that it possesses high efficiency as an energy carrier. Eco-friendly and high purity of hydrogens comes out from water electrolysis. And among different types of electrolysis, proton exchange membrane (PEM) water electrolysis is considered the most renewable, cheap, and eco-friendly. It produces oxygen and hydrogens which are feasible in using as energies. Since it has such a number of benefits, increased research is going on in PEM electrolysis. Nafion is widely used as PEM, but high cost and various other disadvantages leads to the exploration of alternative materials. This review is broadly classified into Nafion and non Nafion based PEM for water electrolysis.