• Journal of the Korean Institute of Gas
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• v.2 no.1
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• pp.59-65
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• 1998

Morphology and thermal properties of polyurethane synthesized from 4,4'-diphenylmethane diisocyanate (MDI), polyester polyol, and 1,4-butane diol are investigated using fourier transform infrared spectroscopy (FT-IR), differential scanning calorimeter (DSC), and dynamic mechanical thermal analysis (DMTA). From the FT-IR study, it is found that the stretching peaks of hydrogen bonded N-H and C=O are shifted to the low frequencies with the increase of hard segment content of the polyurethanes. The shift of the stretching peaks of hydrogen bonded N-H and C=O indicates that the degree of hydrogen bonding is increased. From the DSC study, it appears that the glass transition temperature ($T_g$) of the polyurethanes is increased with the increase of the hard segment content. Also, it is found that the polyurethanes investigated in this study have the homogeneous network structure due to the high functionality of the MDI. From the DMTA study, transition of the soft segment was not found. Therefore it is concluded that the polyurethanes investigated in this study have the one-phase morphology which is consistent with the DSC results.

• Journal of the Korean Institute of Gas
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• v.2 no.4
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• pp.18-24
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• 1998

Polyurethane (PU) synthesized from 4,4'-diphenylmethane diisocyanate having high functionality (f=2.9) and polyester polyol have been investigated by differential scanning calorimeter (DSC), dynamic mechanical thermal analyzer (DMTA), and Fourier transform infrared spectroscope (FT-IR). From the DSC measurement of polyurethane, a single transition temperature ($T_g$) was observed. This result indicates that polyurethanes synthesized in this work have homogeneous network structure due to high functionality of diisocyanate. It was also found that the $T_g$ of polyurethane was increased as hard segment content was increased. The results from DMTA measurement are consistent with DSC results. In order to investigate the effect of thermal annealing on the $T_g$ of polyurethane, the samples were annealed at various annealing conditions. $T_gs$ of polyurethanes were found to increased with annealing temperature. From swelling experiment and FT-IR studies, it was found that the $T_g$ was increased as crosslinking density of polyurethane was increased.

• Proceedings of the KSR Conference
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• 2008.11b
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• pp.993-999
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• 2008

A girder height limitation is the critical parameter for rapid construction of bridge deck and construction space limitation especially in urban area such as high population area and high density habitats. A standard post-tensioned I-shaped concrete girder usually demands relatively higher girder height in order to retain sufficient moment arm between compression force and tensile force. To elaborate this issue, a small U-shaped section with wide flanges can be used as a possible replacement of I-shaped standard girder. This prestressed concrete box girder allows more flexible girder height adjustment rather than standard I-shaped post-tensioned girder plus additional torsion resistance benefits of closed section. A 30m-long, 1.7m-high and 3.63m-wide actual small prestressed concrete box girder is designed and a laboratory test for its static behaviors by applying 6,200kN amount of load in the form of 4-point bending test was performed. The load-deflection curve and crack patterns at different loading stage are recorded. In addition, to extracting the dynamic characteristics such as natural frequency and damping ratio of this girder, several excitation tests with artificial mechanical exciter with un-symmetric mass are carried out using operational frequency sweep-up. Nonlinear finite element analysis of this 4 point bending test under monotonic static load is investigated and discussed with aids of concrete damaged plasticity formulation using ABAQUS program.

• Journal of the Korean Institute of Gas
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• v.23 no.3
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• pp.20-26
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• 2019

Selective catalytic reduction(SCR) method is widely used among various methods for reducing nitrogen oxides in combustion devices of coal power plant. In the present study, the computational fluid dynamic analysis was accomplished to derive the optimal shape of ammonia-dilution air mixing device in a ammonia injection grid. The distribution characteristics of flow and $NH_3$ concentration had been elucidated for the reference shape of ammonia mixing device(Case 1). In the mixing device of Case 1, it could be seen that $NH_3$ distribution was shifted to the wall opposite to the inlet of the ammonia injection pipe. For the improvement of $NH_3$ distribution, the case(Case 2) with closing one upper injection hole and 4 side injection holes, the case(Case 3) with installing horizontal plate at the upper of ammonia injection pipe, the case(Case 4) with installing horizontal plate and horizontal arc plate at he upper of ammonia injection pipe were investigated by analyzing flow and $NH_3$ concentration distributions. From the present study, it was found that the % RMS of $NH_3$ for Case 4 was 4.92%, which was the smallest value among four cases, and the range of $R_{NH3}$ also has the optimally uniform distribution, -10.82~8.34%.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.5
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• pp.612-620
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• 2019

The increasing use of curved beams in buildings, vehicles, ships, and aircraft has results in considerable effort being directed toward developing an accurate method for analyzing the dynamic behavior of such structures. The stability behavior of elastic curved beams has been the subject of a large number of investigations. Solutions of the relevant differential equations have traditionally been obtained by the standard finite difference. These techniques require a great deal of computer time as the number of discrete nodes becomes relatively large under conditions of complex geometry and loading. One of the efficient procedures for the solution of partial differential equations is the method of differential quadrature. The differential quadrature method(DQM) has been applied to a large number of cases to overcome the difficulties of the complex algorithms of programming for the computer, as well as excessive use of storage due to conditions of complex geometry and loading. In this study, the in-plane extensional vibration for asymmetric curved beams with linearly varying cross-section is analyzed using the DQM. Fundamental frequency parameters are calculated for the member with various parameter ratios, boundary conditions, and opening angles. The results are compared with the result by other methods for cases in which they are available. According to the analysis of the solutions, the DQM, used only a limited number of grid points, gives results which agree very well with the exact ones.

• Journal of the Korean Institute of Gas
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• v.23 no.1
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• pp.12-18
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• 2019

Exhaust gas recirculation method is widely used among various methods for reducing nitrogen oxides in automobile engines and incinerators. In the present study, the computational fluid dynamic analysis was accomplished to derive the optimal location of air nozzle exit position by changing its position in a venturi tube for the maximum flue gas recirculation effect. In addition, the flue gas recirculation characteristics with a cone at the exit of air nozzle was elucidated with flue gas recirculation flow rate ratio and mixed gas exit temperature. When the air nozzle exit position was changed from the start position (z = 0) to the end position (z = 0.6m) of the exhaust gas recirculation exit pipe, the change of streamline and temperature distribution in the venturi tube was observed. The exhaust gas recirculation flow rate and the average temperature at the mixed gas exit position was quantitatively compared. From the present study, the optimal location of air nozzle exit position for the maximum flue gas recirculation flow rate ratio and maximum mixed gas exit temperature is z = 0.15m (1/4L). In addition, when the cone is installed at the outlet of the air nozzle, the velocity of the air nozzle outlet is increased, the flue gas recirculation flow rate was increased by about 2 times of the flow rate without cone, and the mixed gas exit temperature is increased by $116^{\circ}C$.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.32 no.2
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• pp.75-86
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• 2019

The biggest obstacle in the nuclear power generation is the high level radioactive waste such as the spent nuclear fuel. High level radioactivities and generated heat make the safe treatment of the spent nuclear fuel very difficult. Nowadays, the only treatment method is a deep geological disposal technology. This paper treats the structural safe design problem of the spent nuclear fuel disposal canister which is one of the core technologies of the deep geological disposal technology. Especially, this paper executed the nonlinear structural analysis for the stresses and deformations occurring in the canister due to the impulsive force applied to the spent nuclear fuel disposal canister in the case of an accidental drop and ground impact event from the transportation vehicle in the repository. The main content of the analysis is about that the impulsive force is obtained using the commercial rigid body dynamic analysis computer code, RecurDyn, and the stress and deformation caused by this impulsive force are obtained using the commercial finite element static structural analysis computer code, NISA. The analysis results show that large stresses and deformations may occur in the canister, especially in the rid or the bottom of the canister, due to the impulsive force occurring during the collision impact period.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.1
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• pp.9-17
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• 2021

Curved beams are increasingly used in buildings, vehicles, ships, and aircraft, which has resulted in considerable effort being directed toward developing an accurate method for analyzing the dynamic behavior of such structures. The stability behavior of elastic circular arches has been the subject of a large number of investigations. One of the efficient procedures for the solution of ordinary differential equations or partial differential equations is the differential quadrature method DQM. This method has been applied to a large number of cases to overcome the difficulties of the complex computer algorithms, as well as excessive use of storage due to conditions of non-linear geometries, loadings, or material properties. This study uses DQM to analyze the in-plane vibration of the circular arches considering the effects of midsurface extension and rotatory inertia. Fundamental frequency parameters are calculated for the member with various parameter ratios, boundary conditions, and opening angles. The solutions from DQM are compared with exact solutions or other numerical solutions for cases in which they are available and given to analyze the effects of midsurface extension and rotatory inertia on the frequency parameters of the circular arches.

• Journal of the Korea Institute of Building Construction
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• v.22 no.6
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• pp.553-564
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• 2022

Concrete is a representative composite material that shows excellent performance in the construction field. However, it is a brittle and nonhomogeneous material and exhibits weak behavior against bending and tensile forces. To compensate for such weakens, fiber reinforcement has been utilized, and steel fiber has been recognized as one of the best material for such purpose. However, steel fiber can seriously affect the durability of concrete exposed to the marine environment due to the corrosion caused by chlorine ions. This study intended to evaluate the mechanical performance of steel fiber reinforce concrete during and after repeated wet/dry cycles in salt solution. According to the experimental results, there was no reduction in the relative dynamic modulus of concrete during the repeated wet/dry cycles in salt solution for 37 weeks. Flexural strength was not decreased after completion of repeated wet/dry cycles in salt solution. There was no sign of corrosion in steel fibers after visual observation of fractured surface. However, the flexural toughness was decreased, and this is because about half of the concrete specimen showed failure before reaching the maximum displacement of 3 mm. Although repeated wet/dry cycles in salt solution did not cause cracks in concrete through corrosion of steel fibers, specific attention is required because it can reduce flexural toughness of steel fiber reinforced concrete.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.29 no.1
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• pp.51-57
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• 2023

Because of the global pollution caused by plastic disposal, demand for eco-friendly transformation in the packaging industry is increased. As part of that, the utilization of polylactic acid (PLA) as a food packaging material is increased. However, it is necessary to improve the crystallinity of PLA by adding nucleating agents or to improve the modulus by adding fillers because of the excessive brittleness of the PLA matrix. Thus, the cellulose nanofiber (CNF) was fabricated and dried to obtain a powder form and applied to the CNF/PLA nanocomposite. The effect of CNF on the morphological, thermal, rheological, and dynamic mechanical properties of the composite was analyzed. We can confirm the impregnated CNF particle in the PLA matrix through the field emission scanning electron microscope (FE-SEM). Differential scanning calorimetry (DSC) analysis showed that the crystallinity of not annealed CNF/PLA nanocomposite was increased approximately 2 and 4 times in the 1st and 2nd cycle, respectively, with the shift to lower temperature of cold crystallization temperature (T_cc) in the 2nd cycle. Moreover, the crystallinity of annealed CNF/PLA nanocomposite increased by 13.4%, and shifted T_cc was confirmed.