• Title/Summary/Keyword: dye bath pH

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The Dyeability of Indigo Depending on the pH of Reduction Bath (환원액의 pH에 따른 인디고의 염색성)

  • 강지연;유효선
    • Textile Coloration and Finishing
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    • v.11 no.4
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    • pp.24-30
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    • 1999
  • Cotton fabric was dyed with indigo at different pHs, dye concentrations, and repeated dyeings. And the K/S value and dye uptake of the dyed materials at those conditions were determined. The decrease of pH during the reduction process of indigo stock solution was observed. As a result the decrease of pH of the dye stock solution depended on the dye concentration and initial pH. The highest K/S value was shown at fabric dyed at pH 11 and the relationship between K/S value and dye uptake depended on initial pH of reduction bath and the slope was lower as the pH increased to 13.

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A Study on the One Bath Dyeing of Wool/Nylon Blended Fabrics with Milling Type Acid Dyes. (밀링형 산성염료에 의한 양모/나일론 혼방직물의 일욕염색에 관한 연구)

  • Chang, Seun-Kee;Kim, Kwang-Soo
    • Textile Coloration and Finishing
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    • v.3 no.3
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    • pp.34-43
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    • 1991
  • The dyeing property of milling type acid dyes with various chemical constitution were studied in one bath dyeing of Wool/Nylon blended fabrics and the proper dyeing condition to get solid color by using reserving agent was also examined. The result of the experiments can be summarized as follows; 1) Although the effect of pH on dyeing of wool with a highly hydrophiilic dye is great in the dyeing of wool and nylon, the proper pH of dyeing bath is weakly acidic 5, in which levelling dye can be obtained by increasing the solubility product. 2) Under a constant pH, the dye with fewer numbers of sulfonic acid groups increases the dyeing amount of nylon as the concentration of the dye is increased. Thus the appropriate dye for light color is the one with many numbers of sulfonic acid groups and the proper dye for medium and deep color is of fewer sulfonic acid groups for one-bath dyeing. 3) When the dye concentration is greater than the critical depth, the K/S value of wool and nylon was almost not effected or slightly increased.

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Dyeing Property and Functionality of Silk Fabrics Dyed with Rhododedron brachycarpum Extracts (만병초 추출물에 의한 견직물의 염색성 및 기능성)

  • Kim, Sangyool
    • Journal of Fashion Business
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    • v.23 no.3
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    • pp.23-34
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    • 2019
  • The aim of this study is to explore the possibility utilizing Rhododedron brachycarpum as a new natural dye resource. It was dyed in silk fabric according to different dyeing conditions such as dye concentration, dye bath temperature, dyeing time and dye bath pH. The effect of the mordanting conditions were estimated as dyeability and color changes. Additionally, the colorfastness, antibacterial property, ultraviolet protection properties of the dyed and mordanted silk fabrics were examined. The water-soluble dye of Rhododedron brachycarpum extracted with distilled water was expressed as Yellow Red color. The dye-abilities of silk generally increased depending on the increasing values of dye concentration, dye bath temperature and dyeing duration. The highest K/S values were obtained at a dye concentration of 100% (v/v), a dye bath temperature of $90^{\circ}C$, a dyeing duration 120 minutes and a dyeing of pH 2. The light fastness of dyed and Cu mordanted silk fabrics were found to be 4 grade while Al, Fe mordanted silk fabrics were found to be 2~3 grade. The dry cleaning and rubbing fastness were excellent or good. The fade of washing fastness was not good, however, the stain of washing fastness was excellent. The dyed and Al, Cu mordanted silk fabrics indicated 99.9% reduction rate. The dyed and the mordanted fabrics showed very good ultraviolet protection factors.

A Study on The Natural Dyeing of Crataegi fructus Extracts (산사 추출물을 이용한 천연염색 연구)

  • Kim, Sangyool
    • Journal of Fashion Business
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    • v.23 no.4
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    • pp.100-111
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    • 2019
  • In this study, the dyeing properties and functionalities of Crataegi fructus extract were investigated for the purpose of application to new natural dye resources. The effects of dyeing conditions(concentration of dye, dye bath temperature, dyeing duration and dye bath pH) and mordanting on dye uptake and color changes were also examined. The study also estimated the colorfastness, antibacterial properties, and ultraviolet protection properties of the dyed and mordanted silk fabrics. The dye uptake increased in tandem with the dye concentration and dye bath temperature. The highest K/S values were obtained at the following conditions: a dye concentration of 100%(v/v), a dyeing period of 60 minutes, a dye bath temperature of $90^{\circ}C$, and a dyeing pH of 3. The colorfastness of the material when dry cleaned or rubbed ranged from good to excellent and fastness to light was rated at grade 2-3. The change in the color grade when exposed to washing was not good; however, the stain of washing fastness was good at a range of 4-5. In regards to the functional property aspects, the dyed and mordanted fabrics exhibited excellent results with a 99.9% reduction rate, and excellent ultraviolet protection factors.

A Study on Cochineal Dyeing by Various Mordants and pH Conditions II -Treatment on Wool Fabric- (염욕의 pH와 매염제의 변화에 따른 코치닐의 염색성 연구 II -양모직물을 중심으로-)

  • Kim Kyung-Sun;Kim Jong-Jun;Jeon Dong-Won
    • The Research Journal of the Costume Culture
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    • v.13 no.2 s.55
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    • pp.248-254
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    • 2005
  • In this study, wool fabric specimens were pre-mordanted using Sn, Al, Cu, Cr, and Fe, and subsequently dyed using cochineal, maintaining the pH of the dye bath constant using pH buffer solutions of 4, 5, 6, 7, and 8. In the case of wool fabric specimen, regardless of the type of mordanting agents, peak dye-uptake amount was obtained at the acidic region, pH 4, and above pH 6, the dye-uptake amount decreased remarkably. Differing from the cotton fabric case, the dyed wool fabric specimen exhibited red shade even in the case of non-mordanting, at the region of pH values of 4 and 5. It is presumed that in the acidic dye bath the effect of cationic amine group present in the structure of wool fiber molecules took place. The amount of color difference, among the mordanting agents, due to the increase of pH value, was highest for the Fe mordanting case. It seems, therefore, that the Fe mordanting is affected most by the pH value.

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Dyeing and Fastness Properties of a Reactive Disperse Dye on PET, Nylon, Silk and N/P Fabrics

  • Bae Jin-Seok;Park Jong-Ho;Koh Joon-Seok;Kim Sung-Dong
    • Fibers and Polymers
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    • v.7 no.2
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    • pp.174-179
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    • 2006
  • Dyeing and color fastness properties of a reactive disperse dye containing an acetoxyethylsulphone group on PET, Nylon, silk and N/P fabrics were examined. The reactive disperse dye exhibited almost the same dyeing properties on PET fabric as a conventional disperse dye except the level of dye uptake. The most appropriate pH and dyeing temperature for the dyeing of Nylon fabric were 7 and $100^{\circ}C$ respectively. The build-up on Nylon fabric was good and various color fastnesses were good to excellent due to the formation of the covalent bond. Application of the reactive disperse dye on silk fabric at pH 9 and $80^{\circ}C$ yielded optimum color strength. The rate of dyeing on Nylon fabric was faster than that on PET fabric when both fabrics were dyed simultaneously in a dye bath, accordingly color strength of the dyed Nylon was higher. The reactive disperse dye can be applied for one-step and one-bath dyeing of N/P mixture fabric with good color fastness.

A Study on the Physical Properties of Sappan Wood Dyeing Fabrics Treated by Rice Straw Ash Solution (잿물로 매염처리된 소방염포의 물성에 관한 연구)

  • 주영주
    • Journal of the Korean Society of Clothing and Textiles
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    • v.22 no.6
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    • pp.609-609
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    • 1998
  • This paper surveys the effect of rice straw ash solution to the physical properties of Sappan Wood dyeing fabrics. In the quantitative analysis of rice straw ash solution, the quantities of absorbed ingredients in fabrics were increased by bath pull treatment but the amount of absorption(K/S value) was increased by bath pH4.5 treatment. This is related to the metal ion. Among the metal ion, effect of Fe iou and Al ion were related. In case added extracted dye solution to mordants, the color dye solution became dark and increased reddish. The changes of mechanical properties of fabrics tensile resilience, bending rigidity(B), compressional resilience(RC) were increased. Generally mechanical properties were increased by rice straw ash solution treatment, specially bath pH9 treatment. Rice straw ash solution treatment of dyeing fabrics made the improvement in tensile strength and elongation and in the amount of absorption, dye ability, color fastness, mechanical properties, tensile strength, elongation.

A Study on the Physical Properties of Sappan Wood Dyeing Fabrics Treated by Rice Straw Ash Solution (잿물로 매염처리된 소방염포의 물성에 관한 연구)

  • 주영주
    • Journal of the Korean Society of Clothing and Textiles
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    • v.22 no.6
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    • pp.699-705
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    • 1998
  • This paper surveys the effect of rice straw ash solution to the physical properties of Sappan Wood dyeing fabrics. In the quantitative analysis of rice straw ash solution, the quantities of absorbed ingredients in fabrics were increased by bath pull treatment but the amount of absorption(K/S value) was increased by bath pH4.5 treatment. This is related to the metal ion. Among the metal ion, effect of Fe iou and Al ion were related. In case added extracted dye solution to mordants, the color dye solution became dark and increased reddish. The changes of mechanical properties of fabrics tensile resilience, bending rigidity(B), compressional resilience(RC) were increased. Generally mechanical properties were increased by rice straw ash solution treatment, specially bath pH9 treatment. Rice straw ash solution treatment of dyeing fabrics made the improvement in tensile strength and elongation and in the amount of absorption, dye ability, color fastness, mechanical properties, tensile strength, elongation.

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The One-bath One-step Dyeing of Nylon/Cotton Blends with Acid Dyes and Mononicotinic acid-triazine type Reactive Dyes (산성염료 및 중성고착형 반응성염료를 이용한 나일론/면 교직물의 1욕 1단 염색)

  • Kim Ji-Yeon;Lee Ki-Poong;Park Hyun-Min;Yoon Nam-Sik;Cho Kwang-Ho
    • Textile Coloration and Finishing
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    • v.16 no.5
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    • pp.1-7
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    • 2004
  • Because acid dyes and reactive dyes require acidic condition for adsorption and alkaline condition for fixation respectively, it is difficult to dye nylon/cotton blends in one-bath one-step dyeing method. In this paper we tried to find out the suitable dye and dyeing condition for one-bath one-step dyeing of nylon/cotton blends. MNT type reactive dyes showed higher exhaustion on cotton as compared with MCT type dyes at neutral pH, which means that the MNT type reactive dyes are preferable for one-bath one-step dyeing method. The optimum condition for one-bath one-step dyeing of nylon/cotton blends was found to be pH 7. Wash fastness of fabrics dyed with half-milling type acid dyes was superior to that of fabrics dyed with levelling type acid dyes, when MNT type reactive dyes were used together.

Dyeing Properties of Nylon Fabric with Reactive Dyes Having Different Reactive Group

  • Lee, Byung-Sun;Lee, Jin-Ah;Lee, Kwon-Sun;Park, Jong-Ho;Kim, Sung-Dong
    • Textile Coloration and Finishing
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    • v.18 no.5 s.90
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    • pp.1-7
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    • 2006
  • The dyeing properties of the several reactive dyes possessing different types of the reactive group on nylon 6 fabric have been investigated. Dyeing of nylon fiber with commercial reactive dyes was dependent on the dye bath pH. As pH increased, the extent of exhaustion decreased due to the deprotonation of the amino end group. But, the extent of fixation increased because of the enhanced reactivity with nylon fiber. It was found that all reactive dyes could be applied to nylon 6 reasonably at pH 5-6. But, the conflicting requirements of dye exhaustion and covalent bond formation limited the extent of fixation efficiency. The best method to improve the extent of the fixation efficiency of the reactive dyes was the conversion of sulphatoethylsulphone group to vinylsulphone group before dyeing with trisodium phosphate. The converted Supra type reactive dye gave the highest extent of fixation efficiency, which was about 90%.