• 제목/요약/키워드: draw solutions

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유도용액으로 비료를 사용한 정삼투 해수담수화에서 유도용액의 성능 평가 (Evaluating the Performance of Draw Solutions in Forward Osmosis Desalination Using Fertilizer as Draw Solution)

  • 정남조;김승건;이호원
    • 멤브레인
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    • 제24권5호
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    • pp.400-408
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    • 2014
  • 유도용액으로 비료를 사용하는 정삼투식 해수담수화에서 유도용액의 성능을 평가하였다. 일반적으로 많이 사용되는 비료 중에서 삼투압, 용해도 및 pH 등을 고려하여 $NH_4NO_3$, $NH_4H_2PO_4$, $(NH_4)_2HPO_4$, KCl, $KNO_3$$KHCO_3$를 유도용액 후보군으로 선정하였다. 수투과선속, 질소와 인의 역용질선속 및 비역용질선속을 측정하여 유도용액의 성능을 평가하였다. KCl은 본 연구에서 선정된 유도용액 중에서 가장 높은 수투과선속을 나타낸 반면에 $(NH_4)_2HPO_4$는 가장 낮은 수투과선속을 나타내었다. $NH_4H_2PO_4$가 가장 낮은 역용질선속 및 비역용질선속을 보였으며, $(NH_4)_2HPO_4$ < $KNO_3$ < $NH_4NO_3$의 순서로 역용질선속 및 비역용질선속이 증가하였다. $NH_4H_2PO_4$는 비록 다른 유도물질에 비해 수투과선속이 낮으나 비료의 주요 성분인 질소와 인을 모두 포함하고 있을 뿐만 아니라 질소와 인의 역용질선속 및 비역용질선속이 다른 유도물질에 비해 매우 낮으므로 FDFO (fertilizer drawn forward osmosis)에서 효과적으로 사용될 수 있을 것으로 판단된다.

중공사막 모듈을 이용한 정삼투 공정에서의 운영조건 변화에 따른 성능평가 (Performance evaluation of forward osmosis (FO) hollow fiber module with various operating conditions)

  • 김봉철
    • 상하수도학회지
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    • 제32권4호
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    • pp.357-361
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    • 2018
  • Forward osmosis (FO) process has been attracting attention for its potential applications such as industrial wastewater treatment, wastewater reclamation and seawater desalination. Particularly, in terms of fouling reversibility and operating energy consumption, the FO process is assumed to be preferable to the reverse osmosis (RO) process. Despite these advantages, there is a difficulty in the empirical step due to the lack of separation and recovery techniques of the draw solution. Therefore, rather than using FO alone, recent developments of the FO process have adapted a hybrid system without draw solution separation/recovery systems, such as the FO-RO osmotic dilution system. In this study, we investigated the performance of the hollow fiber FO module according to various operating conditions. The change of permeate flow rate according to the flow rates of the draw and feed solutions in the process operation is a factor that increases the permeate flow rate, one of the performance factors in the positive osmosis process. Our results reveal that flow rates of draw and feed solutions affect the membrane performance, such as the water flux and the reverse solute flux. Moreover, use of hydraulic pressure on the feed side was shown to yield slightly higher flux than the case without applied pressure. Thus, optimizing the operating conditions is important in the hollow fiber FO system.

Stability analysis of a three-layer film casting process

  • Lee, Joo-Sung;Shin, Dong-Myeong;Jung, Hyun-Wook;Hyun, Jae-Chun
    • Korea-Australia Rheology Journal
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    • 제19권1호
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    • pp.27-33
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    • 2007
  • The co-extrusion of multi-layer films has been studied with the focus on its process stability. As in the single-layer film casting process, the productivity of the industrially important multi-layer film casting and the quality of thus produced films have often been hampered by various instabilities occurring in the process including draw resonance, a supercritical Hopfbifurcation instability, frequently encountered when the draw ratio is raised beyond a certain critical value. In this study, this draw resonance instability along with the neck-in of the film width has been investigated for a three-layer film casting using a varying width non-isothermal 1-D model of the system with Phan-Thien and Tanner (PTT) constitutive equation known for its robustness in portraying extensional deformation processes. The effects of various process conditions, e.g., the aspect ratio, the thickness ratio of the individual film layers, and cooling of the process, on the stability have been examined through the nonlinear stability analysis.

The Effect of Coagulant and Molecular Weight on the Wet Spinnability of Regenerated Silk Fibroin solution

  • Yoo, Young-Jin;Kim, Ung-Jin;Um, In-Chul
    • International Journal of Industrial Entomology and Biomaterials
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    • 제21권1호
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    • pp.145-150
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    • 2010
  • The regenerated silk fibroin with various molecular weights (MW) was prepared by different dissolution condition and the effect of coagulant on the wet spinnability of the various MW silk fibroin solutions dissolved in formic acid was investigated by the observation of wet spun filament in coagulant and the measurement of maximum draw ratio. The observation on the wet spun filament in coagulation bath revealed that good fibers without bead were formed in a high MW and a very high MW silk fibroin samples. In contrast, beads were observed in the silk fibroin sample with medium MW. The maximum draw ratio of wet spun silk fibroin filament decreased with MW reduction. The decrease of maximum draw ratio in isopropanol, acetone, DMF and THF was remarkably higher than that in methanol and ethanol, indicating that the coagulant type strongly influenced the wet spinnability. The two simple evaluation methods used in this study showed complementary information for wet spinnability: (a) The observation of filament in coagulant was effective to check a continuous fiber formation and a bead formation, and (b) the maximum draw ratio measurement was useful to examine the post drawing ability related to molecular orientation.

Design of Spinning and Subsequent Drawing Parameters to Improve the Mechanical Properties of PVA Fibers

  • Chae, Dong Wook;Kim, Seung Gyoo;Kim, Byoung Chul
    • 한국염색가공학회지
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    • 제28권3호
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    • pp.125-133
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    • 2016
  • In this study, efforts were made to enhance the mechanical properties of the poly(vinyl alcohol) (PVA) fibers of medium molecular weight(number-average degree of polymerization=1735) varying the ratio in $DMSO/H_2O$ mixed solvent and spinning/drawing conditions. The gel fibers prepared from pure DMSO were opaquely frozen in the coagulating bath of $-20^{\circ}C$. However, transparent gel fibers were formed without freezing for the mixture to contain water less than 80wt%. As the amount of water in the mixture increased the residual solvent in the coagulated gel fibers decreased ranging from 85 to 42wt%. The complex viscosity increased with increasing PVA concentration in 80/20 $DMSO/H_2O$ exhibiting remarkable shear thinning at 18wt%. In the Cole-Cole plot, the 18wt% PVA solutions gave a deviated curve from 12 and 15wt% ones. Thus the optimum PVA concentration for the spinning processing of medium MW PVA solutions in 80/20 $DMSO/H_2O$ was determined to 18wt% with rheological concept. Low degree of drawing during hot drawing process in the dry state was available for high bath draft in the coagulation bath. The most improved mechanical properties were observed by applying the highest possible draw ratio attained by reducing bath draft over multi-step drawing process. In the given bath draft, linear relationship was observed between both tensile strength and modulus and draw ratio showing the inflection points at the draw ratio of 19.5 and 18.0 for tensile strength and modulus, respectively.

비료 유도용액의 정삼투를 이용한 하수처리수의 재이용 - 유도용액의 성능 평가 - (Water Reuse of Sewage Discharge Water Using Fertilizer Drawn Forward Osmosis - Evaluating the Performance of Draw Solution -)

  • 김승건;이호원
    • 멤브레인
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    • 제26권2호
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    • pp.108-115
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    • 2016
  • 비료를 유도용액으로 사용하는 정삼투를 하수처리수(2차 침전지 유출수)의 재이용에 적용하여 유도용액의 성능을 평가하였다. 일반적으로 많이 사용되고 있는 비료 중에서 삼투압, 용해도 및 pH 등을 고려하여 $NH_4H_2PO_4$, KCl, $KNO_3$, $NH_4Cl$, $(NH_4)_2HPO_4$, $NH_4NO_3$, $NH_4HCO_3$$KHCO_3$을 유도용액 후보군으로 선정하고, 수투과선속 및 역용질선속을 측정하여 유도용액의 성능을 평가하였다. 평균 수투과선속은 KCl > $NH_4Cl$ > $NH_4NO_3$ > $KNO_3$ > $KHCO_3$ > $NH_4HCO_3$ > $NH_4H_2PO_4$ > $(NH_4)_2HPO_4$의 순서로 나타났으며, KCl을 유도용액으로 사용하였을 때, 평균 수투과선속은 13.49 LMH이었다. 하수처리장 2차 침전지 유출수의 삼투압은 탈이온수의 삼투압에 비해 큰 차이가 없었다. 역용질선속은 $NH_4H_2PO_4$ < $NH_4Cl$ < $(NH_4)_2HPO_4$ < $KNO_3$ < $NH_4HCO_3$ < $NH_4NO_3$의 순서로 나타났으며, $NH_4H_2PO_4$를 유도용액으로 사용하였을 때, 역용질선속은 $4.96{\times}10^{-3}mmol/m^2{\cdot}sec$이었다.

압력지연삼투 (PRO) 공정에서 유도용액에서의 압력이 유기물 파울링에 미치는 영향 (Effect of Hydraulic Pressure on Organic Fouling in Pressure Retarded Osmosis (PRO) Process)

  • 서동우;윤홍식;윤제용
    • 상하수도학회지
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    • 제29권1호
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    • pp.133-138
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    • 2015
  • Pressure retarded osmosis (PRO) process is one of membrane processes for harvesting renewable energy by using salinity difference between feed and draw solutions. Power is generated by permeation flux multiplied by hydraulic pressure in draw side. Membrane fouling phenomena in PRO process is presumed to be less sever, but it is inevitable. Membrane fouling in PRO process decreases water permeation through membrane, resulting in significant power production decline. This study intended to investigate the effect of hydraulic pressure in PRO process on alginate induced organic fouling as high and low hydraulic pressures (6.5 bar and 12 bar) were applied for 24 h under the same initial water flux. In addition, organic fouling in draw side from the presence of foulant (sodium alginate) in draw solution was examined. As major results, hydraulic pressure was found to be not a significant factor affecting in PRO organic fouling as long as the same initial water flux is maintained, inidicating that operating PRO process with high hydraulic pressure for efficient energy harvesting will not cause severe organic fouling. In addition, flux decline was negligible from the presence of organic foulant in draw side.

살만한 집(건축) .살만한 도시로의 꿈 (An Earnest Dream for Survival Development of Housing / Urban area -Reflection on Rebuilt ann Redevelopment conducts-)

  • 전상백
    • 기술사
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    • 제33권2호
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    • pp.12-17
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    • 2000
  • The rebuilt and redevelopment projects conducted these days surely have invited overpopulation. Its one of the culprits is the municipal ordinances which allow the floor to site area ratio to increase from 200% to 400% in a decade and the adjacent distance ratio from 1.25 to 0.8 times of height of building. Possible solutions for the overpopulation problem are as below. - The floor to site area ratio should be regulated adaptively according to various regional localities. - Draw back the capital gains coming from a rebuilding project For evaluation process; - Select a suitable plan from plurality of proposals - Gradually encourage projects towards remodeling system in the near future

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APT 공격 탐지를 위한 공격 경로 및 의도 인지 시스템 (Attack Path and Intention Recognition System for detecting APT Attack)

  • 김남욱;엄정호
    • 디지털산업정보학회논문지
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    • 제16권1호
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    • pp.67-78
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    • 2020
  • Typical security solutions such as intrusion detection system are not suitable for detecting advanced persistent attack(APT), because they cannot draw the big picture from trivial events of security solutions. Researches on techniques for detecting multiple stage attacks by analyzing the correlations between security events or alerts are being actively conducted in academic field. However, these studies still use events from existing security system, and there is insufficient research on the structure of the entire security system suitable for advanced persistent attacks. In this paper, we propose an attack path and intention recognition system suitable for multiple stage attacks like advanced persistent attack detection. The proposed system defines the trace format and overall structure of the system that detects APT attacks based on the correlation and behavior analysis, and is designed with a structure of detection system using deep learning and big data technology, etc.

새로운 위상 기반의 Particle Swarm Optimization 알고리즘 : 정보파급 PSO (A Modified Particle Swarm Optimization Algorithm : Information Diffusion PSO)

  • 박준혁;김병인
    • 대한산업공학회지
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    • 제37권3호
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    • pp.163-170
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    • 2011
  • This paper proposes a modified version of Particle Swarm Optimization (PSO) called Information Diffusion PSO (ID-PSO). In PSO algorithms, premature convergence of particles could be prevented by defining proper population topology. In this paper, we propose a variant of PSO algorithm using a new population topology. We draw inspiration from the theory of information diffusion which models the transmission of information or a rumor as one-to-one interactions between people. In ID-PSO, a particle interacts with only one particle at each iteration and they share their personal best solutions and recognized best solutions. Each particle recognizes the best solution that it has experienced or has learned from another particle as the recognized best. Computational experiments on the benchmark functions show the effectiveness of the proposed algorithm compared with the existing methods which use different population topologies.