• Applied Biological Chemistry
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• v.48 no.3
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• pp.267-272
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• 2005

trans-Cinnamaldehyde, a major component of Cinnamomum cassia, was quantitatively analyzed using the $^1H-NMR$ spectrometry. Applicability of this method was confirmed through observing the variation of chemical shift in the $^1H-NMR$ spectrum of t-cinnamaldehyde and the integration value according to various sample concentrations or running temperatures. When the $^1H-NMR$ spectrometry was run for t-cinnamaldehyde (7.1429 mg/ml) at 19, 25, 30, 40 and $50^{\circ}C$, the chemical shifts of the doublet methine signal due to an aldehyde group were observed at 9.7202, 9.7184, 9.7169, 9.7142 and 9.7124 ppm, respectively, to imply that the running temperature had no significant variation in the chemical shift of the signal. The integration values of the signal were $1.37\;(19^{\circ}C),\;1.37\;(25^{\circ}C),\;1.37\;(30^{\circ}C),\;1.37(40^{\circ}C)$ and $1.37(50^{\circ}C)$, respectively, to also indicate running temperature gave no effect on the integration value. When the sample solutions with various concentrations such as 0.4464, 0.8929, 1.7857, 3.5714, 7.1429 and 14.286 mg/ml were respectively measured for the $^1H-NMR$ at $25^{\circ}C$, the chemical shifts of the aldehyde group were observed at 9.7206, 9.7201, 9.7196, 9.7192, 9.7185 and 9.7174 ppm. Even though the signal was slightly shifted to the high field in proportion to the increase of sample concentration, the alteration was not significant enough to applicate this method. The calibration curve for integration values of the doublet methine signal due to the aldehyde group vs the sample concentration was linear and showed very high regression rate ($r^2=1.0000$). Meantime, the $^1H-NMR$ spectra (7.1429 mg/ml $CDCl_3,\;25^{\circ}C$) of t-cinnamaldehyde and t-2-methoxycinnamaldehyde, another constituent of Cinnamomum cassia, showed the chemical shifts of the aldehyde group as ${\delta}_H$ 9.7174 (9.7078, 9.7270) for the former compound and ${\delta}_H$ 9.6936 (9.6839, 9.7032) for the latter one. The difference of the chemical shift between two compounds was big enough to be distinguished using the NMR spectrometer with 0.45 Hz of resolution. The contents of cinnamaldehyde in Cinnamomum cassia, which were respectively extracted with n-hexane, $CHCl_3$, and EtOAc, were determiend as 94.2 \;mg/g (0.94%), 137.6 mg/g (1.38%) and 140.1 mg/g(1.40%) t-cinnamaldehyde in each extract, respectively, by using the above method.

• Journal of the Korean Chemical Society
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• v.56 no.1
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• pp.14-19
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• 2012

We investigate the doublet and quartet potential energy surfaces associated with the gas-phase reaction between $Ti^+$ and $CF_3COCH_3$ for two plausible reaction pathways, $TiF_2^+$ and $TiO^+$ formation pathways by using the density functional theory (DFT) method. The molecular structures of intermediates and transition states involved in these reaction pathways are optimized at the DFT level by using the PBE0 functional. All transition states are identified by using the intrinsic reaction coordinate (IRC) method, and the resulting reaction coordinates describe how $Ti^+$ activates $CF_3COCH_3$ and produces $TiF_2^+$ and $TiO^+$ as products. On the basis of presented results, we propose the most favorable reaction pathway in the reaction between $Ti^+$ and $CF_3COCH_3$.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2005.04a
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• pp.253-256
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• 2005

Nonlinear aeroelastic analyses of composite wing with flap are performed considering free-play and dynamic stiffness of actuator. Doublet-Hybrid method is used for the calculation of subsonic unsteady aerodynamic forces. Free-play is modeled as an asymmetric bilinear spring and is linearized by using the describing function method. The linear and nonlinear flutter analyses show that the flutter characteristics are significantly dependent on the free-play and dynamic stiffness. From the nonlinear flutter analysis, various types of limit cycle oscillations are observed in a range of air speeds below or above the linear divergent flutter boundary.

• Journal of the Korean Society for Aviation and Aeronautics
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• v.14 no.1
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• pp.22-27
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• 2006

The linear and nonlinear aeroelastic analyses of a flat plate wing with flaperon have been performed by using frequency-domain and time-domain analyses. Natural modes from free vibration analysis and a doublet-hybrid method (DHM) are used for the computation of subsonic unsteady aerodynamic forces. The flaperon hinge is represented by a free-play spring and is linearized by the described function method. The linear and nonlinear flutter analyses indicate that flapping mode of the flaperon, the hinge stiffness and free-play of hinge have significant effects on the aeroelastic characteristics. From the nonlinear flutter analysis, different modes like stable and unstable limit-cycle-oscillation are observed in same flutter velocity depending on initial conditions.

• Proceedings of the PSK Conference
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• 2002.10a
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• pp.227.2-228
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• 2002

ZD1839 is a new anticancer agent which selectively inhibits EGFR tyrosine kinase. Oxaliplatin (LOHP), 5-FU (FU), and paclitaxel (PTX) have shown to be highly active against the gastric carcinomas. and ZD1839 is considered as a good candidate for the treatment of gastric cancers when combined with cytotoxic agents. In this study, we evaluated the antitumor effects of these agents in SNU-l human gastric cancer cells either alone or when given as a doublet. (omitted)

• Selected Papers of The Society of Naval Architects of Korea
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• v.2 no.1
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• pp.1-17
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• 1994

For a planar curve-sided panel with constant or linear density distributions of source or doublet in the singularity methods, Cantaloube and Rehbach show that the surface integral can be transformed into contour integral by using Stokes'formulas. As an extension of their formulations, this paper deals with a planar polygonal panel for which we derive the closed-forms of the potentials and the velocities induced by the singularity distributions. Test calculations show that the analytical evaluation of the closed-forms is superior to numerical integration (suggested by Cantaloube and Rehbach) of the contour integral. The compact and explicit expressions may produce accurate values of matrix elements of simultaneous linear equations in the singularity methods with much reduced computer time.

• Korean Journal of Optics and Photonics
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• v.7 no.4
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• pp.305-313
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• 1996

Lens design method by using equivalent lenses was already introduced, but the method has a limitaion that all lenses should be in the air. Therefore, we often get improper solution in designing cemented lenses. In this study, the lens conversion from thick lens to equivalent lens and its reversal was generalized without any preconditions, and the third order aberration fomulrae were derived for the generalized equivalent lens system. The generalized equivalent lens conversion were applied to typical cemented doublet and triplet, and they show that the third order aberrations of the generalized equivalent lenses have better agreements with their corresponding thick lenses than the previous conversion method.

• 한국전산유체공학회:학술대회논문집
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• 2006.10a
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• pp.22-25
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• 2006

Direct simulations of aerodynamic sound, especially sound emitted by rapidly rotating elliptic cylinder by the finite difference lattice Boltzmann method (FDLBM). Effect of pile-fabrics for noise reduction is also studied by the finite volume LBM (FVLBM) using an unstructured grid. Second order time integration and third order upwind scheme are shown to be enough for these simulations. Sound sources are detected to be doublets for both cases. For the elliptic cylinder, the doublet is generated in the interaction between the vortex and the edge. For the circular cylinders, they are generated synchronizing with the Karman vortex street, and it is also shown that the pile-fabrics covering the surface of the cylinder reduces the strength of the source.

• Journal of Mechanical Science and Technology
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• v.20 no.7
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• pp.1043-1050
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• 2006

The aerodynamic interaction between a wing and a rail is investigated using a boundary-element method. The source and doublet singularities are distributed on the wing and its guide-way rail surface. The unknown strengths of the singularities are determined by inverting the aerodynamic influence coefficient matrices. Present method is validated by comparing computed results with the other numerical data. Rail width and rail height affect the aerodynamic characteristics of the wing only if the rail is narrower than the wing span. Although the present results are limited to the inviscid, irrotational flows, it is believed that the present method can be applied to the conceptual design of the high speed ground transporters moving over the rail.

• Journal of ILASS-Korea
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• v.15 no.3
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• pp.109-114
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• 2010

The implementation of gelled propellants systems offers high performance, energy management of liquid propulsion, storability, and high density impulse of solid propulsion. The present study focused on the macroscopic spray characteristics of liquid sheets formed by triplet impinging jets of non-Newtonian liquids which are mixed by Carbopol 941 0.5%wt. The results are compared to experiments conducted on spray images which formed by triplet impinging jets concerning with airassist effect at center orifice. When gel propellants are injected by doublet impinging jets at low pressure and high pressure, closed rim pattern shape appeared by polymeric effect from molecular force and showed inactive atomization characteristics, because of extensional viscosity related by restriction of atomization process and breakup time delay of turbulence transition. As increasing mass flow rate of the air(increasing GAR), spray breakup level is also increased.