• Title/Summary/Keyword: dispersion stability

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Effect of oil particle size on dispersion stability in oil in water emulsion (Oil in Water 에멀전에서 오일 입자 크기가 분산 안정성에 미치는 영향)

  • Hwangbo, Sunae;Chu, Minchul;Moon, Changkwan
    • Particle and aerosol research
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    • v.13 no.3
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    • pp.133-139
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    • 2017
  • In this paper, we proposed an emulsification method without using an emulsifier and investigated the effects of particle size distribution in fluids on dispersion stability. Surfactant-free oil in water emulsion was prepared with 1 % (w/w) of olive oil by using high speed agitation, high pressure and ultrasonic dispersion methods. The particle size, microscopic observation, and dispersion stability of each sample were evaluated and dispersion stability according to various dispersion methods was compared. As a result, the emulsion dispersed by the ultrasonic dispersion method showed the smallest particle size and uniform distribution of $0.07{\sim} 0.3{\mu}m$ and was the most stable in a 7 days stability evaluation. In the above experiment, four olive oil emulsions having different particle sizes were prepared using ultrasonic dispersion technology that was capable of producing stable emulsions. The dispersion stability of each samples with oil droplet sizes of (A) 0.1 to $0.5{\mu}m$, (B) 0.3 to $4{\mu}m$, (C) 1 to $10.5{\mu}m$ and (D) 2 to $120{\mu}m$, was observed for 7 days, and the relationship between the stability and performance was studied. Emulsion (A) with particle size less than $0.5{\mu}m$ displayed the dispersion stability showing below 5 % change in a 7 days stability evaluation. In the case of (B), (C), and (D) that had larger particle than $0.5{\mu}m$, the changes of dispersion stability were 10 %, 13 % and 35 % respectively. From these results, it was proved that dispersion stability of emulsion with uniform particle size of $0.5{\mu}m$ or less was confirmed to be very stable.

Effect of Surfactant on the Dispersion Stability of Slurry for Semiconductor Silicon CMP (계면활성제가 반도체 실리콘 CMP용 슬러리의 분산안정성에 미치는 영향)

  • Yun, Hye Won;Kim, Doyeon;Han, Do Hyung;Kim, Dong Wan;Kim, Woo-Byoung
    • Journal of Powder Materials
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    • v.25 no.5
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    • pp.395-401
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    • 2018
  • The improvement of dispersion stability for the primary polishing slurry in a CMP process is achieved to prevent defects produced by agglomeration of the slurry. The dispersion properties are analyzed according to the physical characteristics of each silica sol sample. Further, the difference in the dispersion stability is confirmed as the surfactant content. The dispersibility results measured by Zeta potential suggest that the dispersion properties depend on the content and size of the abrasive in the primary polishing slurry. Moreover, the optimum ratio for high dispersion stability is confirmed as the addition content of the surfactant. Based on the aforementioned results, the long-term stability of each slurry is analyzed. Turbiscan analysis demonstrates that the agglomeration occurs depending on the increasing amount of surfactant. As a result, we demonstrate that the increased particle size and the decreased content of silica improve the dispersion stability and long-term stability.

MEASURES FOR STABILITY OF SLOPE ESTIMATION ON THE SECOND ORDER RESPONSE SURFACE AND EQUALLY-STABLE SLOPE ROTATABILITY

  • Park, Sung H.;Kang, Ho-Seog;Kang, Kee-Hoon
    • Journal of the Korean Statistical Society
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    • v.32 no.4
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    • pp.337-357
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    • 2003
  • This paper introduces new measures for the stability of slope estimation on the second order response surface at a point and on a sphere. As a measure of point stability of slope estimation, we suggest a point dispersion measure of slope variances over all directions at a point. A spherical dispersion measure is also proposed as a measure of spherical stability of slope estimation on each sphere. Some designs are studied to explore the usefulness of the proposed measures. Using the point dispersion measure, another concept of slope rotatability called equally-stable slope rotatability is proposed as a useful property of response surface designs. We provide a set of conditions for a design to have equally-stable slope rotatability.

Improvement of Dispersion Stability of Ink-jet Ink for Polyester Fiber (폴리에스터용 잉크젯 잉크의 분산안정성 개선에 관한 연구)

  • 최재홍;지병철;서인석
    • Textile Coloration and Finishing
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    • v.15 no.5
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    • pp.321-326
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    • 2003
  • In order for disperse dye based ink to be fitted with the critical requirements of ink jet printing, this study was undertaken to investigate the effects of 6 different dispersants on the milling efficiency of insoluble dye particles and dispersion stability of the final ink. It was found that a polystyrene dispersant with high molecular weight exerted relatively better dispersion stability which may be associated with its steric stabilization effect in the ink solution.

Analysis of Stability Condition and Wideband Characteristics of 3D Isotropic Dispersion(ID)-FDTD Algorithm (3차원 ID-FDTD 알고리즘의 Stability Condition과 광대역 특성 분석)

  • Kim, Woo-Tae;Koh, Il-Suek;Yook, Jong-Gwan
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.22 no.4
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    • pp.407-415
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    • 2011
  • The stability condition and wideband characteristics of 3D ID-FDTD algorithm which has low dispersion error with isotropic dispersion are presented in this paper. 3D ID-FDTD method was proposed to improve the defect of the Yee FDTD such as the anisotropy and large dispersion error. The published paper calculated the stability condition of 3D ID-FDTD algorithm by using numerical method, however, it is thought that the examples were not sufficient to verify the stability condition. Thus, in this paper, various simulations are included in order to hold reliability under the conditions that the plane wave propagation is assumed with a single frequency and a wideband frequency. Also, the 3D ID-FDTD algorithm is compared to those that have the similar FDTD algorithm with ID-FDTD such as Forgy's method and non-standard FDTD method in a wideband. Finally, the radar cross section(RCS) for the large sphere with high dielectric constant is calculated.

Effects of Viscosity on Dispersion Stability of Nano CoAl2O4 Ceramic Ink

  • Lee, Ji-Hyeon;Hwang, Hae-Jin;Kim, Jin-Ho;Hwang, Kwang-Taek;Han, Kyu-Sung
    • Journal of the Korean Ceramic Society
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    • v.52 no.6
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    • pp.497-501
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    • 2015
  • Inkjet printing is a widespread technology, offering advantages such as high-quality decoration, a continuous process, and the accurate direct reproduction of patterns or pictures. In inkjet printing technology, the dispersion stability of ceramic ink is one of the most important factors. In this study, the dispersion stability of blue $CoAl_2O_4$ ink for ceramic inkjet printing is systematically investigated. Blue $CoAl_2O_4$ pigment was synthesized by a solid-state reaction and then milled to less than 300nm in size. In order to investigate the influence of the viscosity on the dispersion stability, two types of $CoAl_2O_4$ ceramic inks (termed here Blue L and Blue H) were prepared using different volume ratios of ethylene glycol and ethanol. The Blue L and Blue H ink solutions contained cetyltrimethylammonium bromide(CTAB) as a dispersive agent. The viscosity, surface tension and jetting stability of the $CoAl_2O_4$ ceramic inks were analyzed using a rheometer, a surface tension meter and a dropwatcher. The dispersion stability of the $CoAl_2O_4$ ceramic ink was investigated by a multiple light-scattering method. Blue H, a ceramic ink with higher viscosity, showed much better dispersion stability than the Blue L ceramic ink.

A Study on the Dispersion Stability of Aluminum Slurry Fuel (알루미늄 슬러리 연료의 분산안정성 연구)

  • Cho, Min-Ho;Yang, Mun-Kyu;Jeong, Byung-Hun;Han, Jeong-Sik;Lee, Ik-Mo
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.163-166
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    • 2009
  • For the preparation of Aluminum-slurry fuel, the effects of process parameters on the aluminum dispersion stability in the liquid fuel have been investigated. The dispersion stability of aluminum-slurry fuels could be monitored by measurements through Turbiscan using the scattering of the Laser. Through the application of various additives, TPAB (Tetrapropyl ammonium bromide) showed more reasonable performance than others.

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Deaggregation and Ultradispersion of Detonation Nanodiamonds in Polar Solvent Using Physicochemical Treatments (물리화학적 처리를 통한 극성 용매 내 나노다이아몬드의 탈응집 및 분산성 향상 연구)

  • Kim, Changkyu;Lee, Gyoung-Ja;Rhee, Changkyu
    • Journal of Powder Materials
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    • v.20 no.6
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    • pp.479-486
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    • 2013
  • In the present work, physicochemical treatments were introduced for de-aggregation and stable dispersion of detonation nanodiamonds (DND) in polar solvents. The DNDs in water exhibited a particle size of 138 nm and high dispersion stability without particular treatment. However, the DNDs in ethanol were severely aggregated to several micrometers in size and showed poor dispersion stability with time. To break down aggregates of DNDs and enhance the dispersion stability of them in ethanol, mechanical force and chemical surfactant were introduced as functions of zirconia ball size, kind of surfactant and amount of surfactant added. From the analyses of average particle size and Turbiscan results, it was suggested that the size of DNDs in ethanol can be reduced by only mechanical force; however, the DNDs were re-aggregated due to high surface activity. The long-term dispersion stability can be achieved by applying mechanical force to break down the aggregates of DNDs and by preventing re-aggregation of them using proper surfactant.

Research on the Dispersion Stability and Scale up of Carbon Slurry Fuel (카본슬러리 연료의 분산안정성 개선 및 scale up 제조 연구)

  • Cho, Min-Ho;Yang, Mun-Kyu;Lee, Ik-Mo;Cho, Joon-Hyun;Kwon, Tae-Soo;Jeong, Byung-Hun;Han, Jeong-Sik
    • Journal of the Korean Society of Propulsion Engineers
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    • v.13 no.3
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    • pp.34-40
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    • 2009
  • For the preparation of carbon-slurry fuel, the effects of process parameters on the carbon dispersion stability in the liquid fuel have been investigated. The dispersion stability of carbon-slurry fuels could be monitored by measurements of particle size and carbon contents in the different positions, and observation of dispersion states after centrifuging. Through the application of various additives, it was found that NB463S84 based on polyolefin succinimde showed the best dispersion and longest stability life of carbon-slurry fuel. Also, PIBSI (polyisobutenyl succimide) with the similar functional groups to NB463S84 was effectively synthesized and same dispersion stability was verified by application to carbon-slurry fuel. Finally, the possibility of practical use of carbon-slurry fuels was confirmed by application of the mixing conditions obtained from g scale to kg scale preparation.

Turbulent Dispersion Behavior of a Jet Issued into Thermally Stratified Cross Flows(I) (열적으로 성층화된 횡단류에 분출된 제트의 난류확산 거동(I))

  • Kim, Kyung Chun;Kim, Sang Ki
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.2
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    • pp.218-225
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    • 1999
  • Flow visualization study has been conducted to simulate the turbulent dispersion behavior of a crossflow jet physically under the conditions of various thermal stratification in a wind tunnel. A smoke jet with the constant ratio of the jet to freestream velocity is injected normally to the cross flow of the thermally stratified wind tunnel(TSWT) for flow visualization. The typical natures of the smoke dispersion under different thermal stratifications such as neutral, weakly stable, strongly stable, weakly unstable, strongly unstable and inversion layer are successfully reproduced in the TSWT. The Instantaneous velocity and temperature fluctuations are measured by using a cold and hot-wire combination probe. The time averaged dispersion behaviors, the centerline trajectories, the spreading angles and the virtual origins of the cross jet are deduced from the edge detected images with respect to the stability parameter. All the general characteristics of the turbulent dispersion behavior reveal that the definitely different dispersion mechanisms are inherent in both stable and unstable conditions. It is conjectured that the turbulent statistics obtained in the various stability conditions quantitatively demonstrate the vertical scalar flux plays a key role in the turbulent dispersion behavior.