• Title/Summary/Keyword: dispersion parameters

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A Study on Transport Characteristics of Fe in Soil (토양 내 철의 이동특성에 관한 연구)

  • Cho, Ki-Chul;Lee, Kyeong-Ho;Choung, Young-Heon;Cho, Sang-Won;Oh, Kwang-Joong
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.10
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    • pp.1043-1051
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    • 2005
  • In this stduy, adsorption and transport characteristics of Fe in the soil were investigated using convection-dispersion local equilibrium sorption model and two-site non-equilibrium sorption model. In batch experiments with different Fe concentration, characteristics of Fe adsorption was investigated using Freundlich and linear isotherm. Column experiments with different flow rate, organic matter content md Fe concentration were also carried out. We measured Fe concentrations in injection-liquid and in effluent, and then applied them to CXTFIT program. As a result of column experiments, some parameters(D, R, ${\beta}$, ${\omega}$) used in two-site non-equilibrium adsorption model were obtained. Characteristics of Fe transport were analyzed using the parameters(D, R, ${\beta}$, ${\omega}$) obtained from the CXTFIT program, Consequently, characteristics of Fe transport in the soil were predicted through two-site non-equilibrium adsorption model.

THE EVOLUTION OF THE GALACTIC GLOBULAR CLUSTERS.: I. METAL ABUNDANCE CALIBRATIONS

  • Lee, See-Woo;Park, Nam-Kyu
    • Journal of The Korean Astronomical Society
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    • v.17 no.2
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    • pp.69-103
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    • 1984
  • Five different calibrations of metal abundances of globular clusters are examined and these are compared with metallicity ranking parameters such as $(Sp)_c$, . Q39 and IR-indices. Except for the calibration $[Fe/H]_H$ by the high dispersion echelle analysis. the other calibration scales are correlated with the morphological parameters of red giant branch. In the $[Fe/H]_H$-scale. the clusters later than ${\sim}F8$ have nearly a constant metal abundance. $[Fe/H]_H{\simeq}-1.05$, regradless of morphological characteristics of horizontal branch and red giant branch. By the two fundamental calibration scales of $[Fe/H]_L$ (derived by the low dispersion analysis) and $[Fe/H]_{{\Delta}s}$ (derived by the spectral analysis of RR Lyrae stars). the globular clusters are divided into the halo clusters with [Fe/H]<-1.0 and the disk clusters confined within the galactocentric distance ${\tau}_G=10\;kpc$ and galactic plane distance |z|=3 kpc. In this case the abundance gradient is given by d[Fe/H]/$dr_G{\approx}-0.05\;kpc^{-1}$ and d[Fe/H]/$d|z|{\simeq}-0.08\;kpc^{-1}$ within ${\tau}_G=20\;kpc$ and |z|=10 kpc, respectively. According to these characteristics of the spatial distribution of globular clusters. the chemical evolution of the galactic globular clusters can be accounted for by the two-zone (disk-halo) slow collapse model when the $[Fe/H]_L$-or $[Fe/H]_{{\Delta}s}$-scale is applied. In the case of $[Fe/H]_H$-scale, the one-zone fast collapse model is preferred for the evolution of globular clusters.

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Analysis of Measuring Error for Particle Size Analysis by Laser Diffraction Spectrometer (입자크기분석을 위한 레이저회절 분광계의 측정오차 분석)

  • Ha, Sang-An;Son, Heui-Jeong
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.713-722
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    • 2000
  • This study analysed error of measurement and reproducibility for particle size analysis by the laser diffraction spectrometer. Laser diffraction spectrometers has become a very important method of particle size analysis. This measuring method has the advantage of simple operation, good reproducibility and rapid analysis. A feeding and dispersing system have been developed, which allows mass throughputs between 0.1~23 g/min in flowing air and 1.4~35% in flowing liquid. It has been used as a feeder unit for wet and dry particle size analysis from diffraction patterns. Relevant parameters, such as particle shape, particle size, dispersion, flow rate, concentration were analysed for measuring error. And system parameters of instruments for measurement of dynamic processes, eg, measuring time, focal plane, injection pressure drop and dispersion effect by the ultrasonic and mixing of preliminary treatment, were also discussed.

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Evaluation of Dispersion Stability and Absorption Performance Enhancement of Binary Nanoemulsion Fluids (이성분 나노에멀전 유체의 분산안정성 및 흡수성능 촉진실험)

  • Lee, Jin-Ki;Kim, Young-Jin;Shin, Myung-Chul;Kim, Se-Won;Kang, Yong-Tae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.9
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    • pp.895-900
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    • 2012
  • This paper aims to examine the effect of nanodroplets on pool-type absorption heat transfer enhancement and to find the relationship between the dispersion stability and the absorption performance. The concentrations of oil and surfactant are considered as the key parameters. $C_{12}E_4$ and Tween20 are used as the surfactants and N-decane oil is added to the $NH_3/H_2O$ solution to make the binary nanoemulsion fluids. Binary nanoemulsion fluids are dispersed by the ultrasonic vibrator and the stirrer under specific conditions. The dispersion stability of binary nanoemulsion fluids for each oil concentrations is evaluated from the droplet size and Tyndall effect analysis. The absorption performance of binary nanoemulsion fluids is compared with the result of dispersion stability. In addition, it is found that the binary nanoemulsion fluid is a strong candidate as a new working fluid for absorption applications.

Determination of Optical Constants of Organic Light-Emitting-Material Alq3 Using Jellison-Modine Dispersion Relation (Jellison Modine 분산식을 이용안 유기발광물질 Alq3의 광학상수 결정)

  • Park, Myung-Hee;Lee, Soon-Il;Koh, Ken-Ha
    • Journal of Korean Ophthalmic Optics Society
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    • v.10 no.4
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    • pp.267-272
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    • 2005
  • We deposited thin films of organic light-emitting-material $Alq_3$(alumina quinoline) on silicon and slide-glass substrates using thermal evaporation method, and measured spectra of ellipsometry angles ${\Delta}$ and ${\Psi}$ in the photon-energy range of 1.5~5.0 eV using a variable angle spectroscopic ellipsometer. The optical constants, refractive index and extinction coefficient, of $Alq_3$ were determined via the dispersion parameters extracted from the curve-fitting process based on Jellison-Modine dispersion function. The reliability of determined optical constants were verified through the comparison of measured and simulated transmittance curves and the good agreement between simulated absorption-coefficient curves and absorbance spectra measured using a spectrophotometer.

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Determination of Optical Constants of TiNx was Sputtered with RF Magnetron Sputtering Method (RF 마그네트론 스퍼터링 방법으로 증착한 TiNx 박막의 광학상수 결정)

  • Park, Myung Hee;Kim, Sang Yong;Lee, Soonil;Koh, Ken Ha
    • Journal of Korean Ophthalmic Optics Society
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    • v.12 no.3
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    • pp.77-81
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    • 2007
  • We sputtered $TiN_x$ (titanium nitride) thin films on silicon substrates using ultra high vacuum RF magnetron sputtering method, and measured spectra of ellipsometry angles ${\Delta}$ and ${\Psi}$ in the photon-energy range of 1.5-5.0 eV using a variable angle spectroscopic ellipsometer. The optical constants, refractive index and extinction coefficient of the $TiN_x$ films were determined via the dispersion parameters extracted from the curve-fitting process based on Drude+Lorentz oscillator dispersion function. The reliability of determined optical constants were verified through the comparison of between simulated reflectance and reflectance spectra measured using a spectrophotometer.

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Effect of Geometric and Dynamic Parameters on Mixing Characteristic in an Internal-Loop Apparatus (내부 순환 장치의 크기 및 유속 변화에 따른 혼합특성)

  • 최윤찬;김동석
    • KSBB Journal
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    • v.11 no.4
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    • pp.405-410
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    • 1996
  • This paper discussed the dispersion effect according to the geometrical variation of an internal-loop spparatus by the method of pulse injection of a tracer. The Bodenstein number, which is the dimensionless group characterizing the effect of dispersion, was decreased with increasing the superficial gas velocity in the 50L and the 500L apparatus. But, in the 5L apparatus, the Bodenstein number was increased with increasing the superficial gas velocity in the range of 0 to 2cm/sec but above that range the rate of increase was dropped down to give a constant value because of the phenomenon of gas disengagement. The principle of similarity based on dimensional analysis was applied to design a pilot scale internal-loop apparatus. The effect of dispersion was examined in three different internal-loop apparatus to give the following correlation with major geometric and fluid dynamic properties as variables. B0=4.4014ReG0.117 ReL-0.0065(Hr/Dr)0.76(Dd/Dr)-0.76

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Synthesis of Polymers in Supercritical Carbon Dioxide (초임계 유체를 이용한 고분자 합성 연구)

  • Lee, Hyun-Suk;Kim, Jin-Woong
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.36 no.1
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    • pp.17-32
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    • 2010
  • This review shows the design and the development of new $CO_2$-soluble hydrocarbon copolymers which can be used as effective stabilizers for successful dispersion polymerizations of bio-compatible materials in supercritical carbon dioxide ($scCO_2$). The basic concepts of supercritical fluid including its solvent properties and applications in polymer synthesis are described. We report the facile synthesis of highly soluble hydrocarbon based copolymers, prepared with good control via controlled free radical polymerization from readily accessible and commercially available monomers. The phase behaviour of these materials was monitored in pure $CO_2$ to investigate how the molecular weights and the composition of the copolymers affect their solubility in $CO_2$. Their activity as a stabilizer was then tested in dispersion polymerization of N-vinyl pyrrolidone in $CO_2$ at various reaction conditions to identify the key parameters required for a successful dispersion stabilization of growing PVP particles. Some prospective potentials of this research which can be applied in developing new polymer materials in an environmentally-friendly fashion for use in cosmetics are also discussed.

Experimental, Theoretical and Numerical Studies for Concentrations and Velocities of Gas Jets (가스 제트 누출의 농도 및 속도에 대한 실험, 이론 및 수치해석 연구)

  • Bang, Boo-Hyoung;Kim, Hong-Min;Kim, Sung-Hoon;Lee, Keun-Won
    • Journal of the Korean Institute of Gas
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    • v.26 no.1
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    • pp.20-26
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    • 2022
  • The results of experimental, theoretical, and numerical analysis were compared regarding the concentrations and velocities of flammable gas jets generated by pressurized leakage of methane gas. The concentration was measured through experiments for the jet dispersion process, and the velocities was calculated by applying the self-similarity theory. And the velocities and concentrations were calculated using CFD tools - FLACS and CFX- compared with the results. The difference between self-similarity model and CFD is due to the buoyancy term, which increases as the distance from a leak source increases. The results are compared with dimensionless parameters using the leak source radius and velocity components along the leak axis.

Study of the mechanical properties and effects of particles for oxide dispersion strengthened Zircaloy-4 via a 3D representative volume element model

  • Kim, Dong-Hyun;Hong, Jong-Dae;Kim, Hyochan;Kim, Jaeyong;Kim, Hak-Sung
    • Nuclear Engineering and Technology
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    • v.54 no.5
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    • pp.1549-1559
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    • 2022
  • As an accident tolerant fuel (ATF) concept, oxide dispersion strengthened Zircaloy-4 (ODS Zry-4) cladding has been developed to enhance the mechanical properties of cladding using laser processing technology. In this study, a simulation technique was established to investigate the mechanical properties and effects of Y2O3 particles for the ODS Zry-4. A 3D representative volume element (RVE) model was developed considering the parameters of the size, shape, distribution and volume fraction (VF) of the Y2O3 particles. From the 3D RVE model, the Young's modulus, coefficient of thermal expansion (CTE) and creep strain rate of the ODS Zry-4 were effectively calculated. It was observed that the VF of Y2O3 particles had a significant effect on the aforementioned mechanical properties. In addition, the predicted properties of ODS Zry-4 were applied to a simulation model to investigate cladding deformation under a transient condition. The ODS Zry-4 cladding showed better performance, such as a delay in large deformation compared to Zry-4 cladding, which was also found experimentally. Accordingly, it is expected that the simulation approach developed here can be efficiently employed to predict more properties and to provide useful information with which to improve ODS Zry-4.