• Journal of the Korean Ceramic Society
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• v.54 no.1
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• pp.49-54
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• 2017

In this study, based on hydrolysis and condensation via $St{\ddot{o}}ber$ process of sol-gel method, synthesis of mono-dispersed silica nanoparticles was carried out with hydrophilic solvent. This operation was expected to be a more simplified process than that with organic solvent. Based on the sol-gel method, which involves simply controlling the particle size, the particle size of the synthesized silica specimens were ranged from 30 to 300 nm by controlling the composition of tetraethylorthosilicate (TEOS), DI water and ammonia solution, and by varying the stirring speeds while maintaining a fixed amount of ethanol. Increasing the content of DI water and decreasing the content of ammonia caused the particle size to decrease, while controlling the stirring speed at a high level of RPMs enabled a decrease of the particle size. X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR) were utilized to investigate the success factors for synthesizing process; Field emission scanning electron microscopy (FE-SEM) was used to study the effects of the size and morphology of the synthesized particles. To analyze the dispersion properties, zeta potential and particle size distribution (PSD) analyses were utilized.

• Applied Chemistry for Engineering
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• v.7 no.3
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• pp.410-415
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• 1996

It is well known that the heavy water separation process using hydrogen isotope exchange reaction over the platinum catalyst is the most efficient. In this study, the Pt/silicalite catalysts were prepared and characterized by hydrogen adsorption in order to develop the hydrophobic platinum catalyst for hydrogen isotope exchange reaction. Silicalite was synthesized as support material and it was verified that silicalite is more hydrophobic than activated carbon and ZSM-5. Also the platinum was loaded on silicalite by conventional impregnation and ion-exchange method respectively. The platinum dispersion of Pt/silicalite catalysts was measured through hydrogen adsorption experiment. The dispersion is very low in the catalyst prepared by the impregnation method while it is very high with limited platinum content in the catalyst prepared by the ion-exchange method.

• Korean Journal of Materials Research
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• v.23 no.10
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• pp.592-598
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• 2013

Graphene oxide powders prepared by two different drying processes, freeze drying and spray drying, were studied to compare the effect of the drying method on the physical properties of graphene oxide powder. The graphene oxide dispersion was prepared from graphite by chemical delamination with the aid of sulfuric acid and permanganic acid, and the dispersion was further washed and re-dispersed in a mixed solvent of water and isopropyl alcohol. A freeze drying method can feasibly minimize damage to the sample, but it requires a long process time. In contrast, spray drying is able to remove a solvent in a relatively short time, though this process requires exposure to a high temperature for a rapid evaporation of the solvent. The powders prepared by freeze drying and spray drying were characterized and compared by Raman spectroscopy, X-ray diffraction, field-emission scanning electron microscopy, transmission electron microscopy, and by an elemental analysis. The graphene oxide powders showed similar chemical compositions; however, the morphologies of the powders differed in that the graphene oxide prepared by spray drying had a winkled morphology and a higher apparent density compared to the powder prepared by freeze drying. The graphene oxide powders were reduced at $900^{\circ}C$ in an atmosphere of $N_2$. The effect of the drying process on the properties of the reduced graphene oxide was examined by SEM, TEM and Raman spectroscopy.

• Polymer(Korea)
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• v.26 no.6
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• pp.803-811
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• 2002

In this study the wear behavior of ultra high molecular polyethylene (UHMWPE) filled with kaolin particles by different methods was investigated. UHMWPE/kaolin composites were prepared by two different methods: polymerization-filling and powder mixing. Particularly in a powder mixing method. Particle dispersion and wear property according to powder mining method were examined. It was found from wear test that filling of inorganic filler into UHMWPE by polymerization filling was more effective way than by powder mixing method in improving Wear resistance of UHMWPE. It was also confirmed that abrasive wear was dominant wear mechanism and particle dispersion in the composite as well as interface property was an important factor in controlling the wear behavior of the resulting composites.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.12 no.4
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• pp.576-585
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• 2001

In this paper, we investigated the method of compensation for optical pulse shape distortion due to both chromatic dispersion and SPM(self phase modulation) in a single mode fiber We selected MSSI(mid-span spectral inversion) as compensation method using OPC(optical phase conjugator). We used EOP(eye-opening penalty) parameter in order to evaluate the efficiency of waveform distortion compensation. In this paper, we induced optimum pump power level in optical phase conjugator through analytic method of computer simulation. And we investigated input signal power range being able to maintain stable reception performance under the condition of optimum pump power. We verified the possibility of high performance optical transmission system realization through the inducement and application of optimum pump power, input signal power and in-line amplifier spacing, because power control is important in the compensation for optical pulse distortion.

• Polymer(Korea)
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• v.37 no.4
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• pp.442-448
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• 2013

In this study, we developed and optimized hydrophilic polymer-based solid dispersion formulations (SDs) using a spray drying method for improving the aqueous solubility of eprosartan, one of poorly soluble drugs that has been broadly used for the treatment of high blood pressure. Hydroxylpropylcellulose (HPC) and poly(vinyl pyrrolidone) (PVP) were used as hydrophilic polymer matrices and poloxamer 407 (P407) added as a polymeric surfactant. Various kinds of solid dispersions with different drug/polymer compositions were prepared and their physico-chemical properties were compared. As the polymer content increased, the drug crystallinity in the SDs significantly decreased and the dissolution properties were enhanced. The PVP based SDs were observed to have relatively reduced crystallinity and an enhanced dissolution rate than HPC-based SDs, due to better miscibility between drug and polymer matrix. For PVP based SDs, the drug crystallinity almost disappeared and the dissolution properties significantly increased by more than 3~7 times.

• Polymer(Korea)
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• v.37 no.6
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• pp.764-769
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• 2013

Starch was grafted by poly(methyl methacrylate) through the emulsion polymerization method. Modified starch/(acrylonitrile-butadiene rubber) (NBR) compounds were prepared by a latex blend method. The morphology, thermal properties and mechanical properties of the modified starch/carbon black/NBR composites were investigated with the change of starch concentration. The mechanical properties of the composites were improved by the addition of modified starch. But, when the concentration of modified starch was higher than 40 phr, the mechanical properties were deteriorated due to the poor dispersion of modified starch. At the same ratio of starch to carbon black, the composite showed a synergistic reinforcing effect by the good dispersion and high cross-linking density. In addition, the tensile strength, storage modulus, hardness, swelling and other properties were the best.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.20 no.5
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• pp.460-469
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• 2010

This paper presents the analysis of a time reversal process for $A_0$ Lamb wave mode($A_0$ mode) on a rectangular plate. The dispersion characteristic equation of the $A_0$ mode is approximated using the Timoshenko beam theory. A virtual sensor array model is developed to consider the effects of reflections occurring on the plate boundary on the time reversal process. The time reversal process is formulated in the frequency domain using the virtual sensor array model. The reconstructed signal is obtained in the time domain through an inverse fast Fourier transform. The validity of the proposed method is demonstrated through the comparison to the numerical simulation results computed by the finite element analysis.

• Journal of Korean Institute of Industrial Engineers
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• v.32 no.1
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• pp.42-50
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• 2006

The multi-criteria group decision making (MCGDM) problem is to determine the best compromise solution in a set of competing alternatives that are evaluated under conflicting criteria by decision maker (DM)s. In this paper, we propose a mixed-integer programming (MIP) model to solve MCGDM. The existing method based on minimizing a distance measure such as Median Approach can not guarantee the best compromise solution because the element of median point vector is defined with respect to each criteria separately. However, by considering all criteria simultaneously, we generate median point that is better for locating the best compromise solution. We also utilize the concept of spatial dispersion index (SDI) to produce a threshold value, which is used as a guideline to choose either the Utopian Approach or the Median Approach. And we suggest using CBITP (Convex hull of individual maxima Based Interactive Tchebycheff Procedure) to provide DMs with various Pareto-optimal solutions so that DMs have broad range of selection.

• Transactions of the Korean Society of Mechanical Engineers
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• v.15 no.1
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• pp.241-251
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• 1991

The present simulation model relies on a new approach of the heavy particle motion in a turbulent flow considering the time and space correlation to the Lagrangian point of view. The turbulent field is, here, assumed that its characteristic scales are random and follow a Poisson's distribution. Using this model, we have computed the trajectory of each particle, that is, its velocity and position at each time in order to study the dispersion of particles in a grid turbulent flow. The computed results have been compared to the corresponding experimental data. Due to the complex mechanism of turbulence and the theoretically and experimentally lacking information, we had to make some assumptions for simplifying the situation, but we have found the good agreement between simulated and measured results. In particular, the application of the present method on the Lagrangian correlation of particle provides an interesting alternative to the usual computational methods.