• 제목/요약/키워드: dispersion method

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수산화마그네슘 분산상의 제조와 PET 부직포 섬유의 난연 코팅제 적용 (Preparation of Mg(OH)2 Dispersion and its Application to PET Non-woven Textile as Flame Retardant Coating)

  • 임형미;현미경;정상옥;이동진;이승호
    • 한국세라믹학회지
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    • 제48권6호
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    • pp.537-542
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    • 2011
  • Magnesium hydroxide as a non-halogen flame retardant has increasing attention due to its non-toxicity, high decomposition temperature and smoke suppressant ability during combustion. For the application of magnesium hydroxide retardant to the textile by soaking and coating method, the prerequisite for the coating is a small particle size, stable dispersion, and adhesion to the textile. The dispersion of $Mg(OH)_2$ particles and stability of the coating was checked by monitoring the change of transmittance and backscattering by varying the types of dispersion agents, binder, solvent, and $Mg(OH)_2$ source, and their compositions in the coating. The $Mg(OH)_2$ dispersion coating was applied to PET(poly(ethylene terephthalate)) non-woven textile. The physical properties are characterized by surface morphology, amount of coating, particle dispersion, and adhesion test. The flame retardant $Mg(OH)_2$ coated textile has been compared by limited oxygen index(LOI) and thermal gravimetry and differential scanning calorimetry(TG-DSC). It was found that phosphorous additive may give synergistic effect on $Mg(OH)_2$ flame retardant coating to make the flame retardant PET non-woven textile.

WDM 채널수에 따른 최적의 OPC 위치 및 광섬유 분산 계수 (Optimal OPC Position and Fiber Dispersion Coefficients depending on WDM Channel Numbers)

  • 이성렬;정재필
    • 한국항행학회논문지
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    • 제11권2호
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    • pp.177-186
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    • 2007
  • 본 논문에서는 광 위상 공액기 (OPC ; optical phase conjugator)를 중심으로 광 전력과 색 분산량을 대칭화 하는 방법을 대체할 수 있는 OPC의 최적 위치 편차와 그에 따른 광섬유 구간의 최적 분산 계수 편차를 WDM 시스템의 채널수에 따라 살펴보았다. 본 논문에서 고려한 WDM 시스템의 채널수는 8, 12, 16, 20, 24로 가정하였고, 각 채널의 비트율은 40 Gbps로 가정하였다. 모든 WDM 채널의 보상을 위한 최적 OPC 위치 편차와 광섬유 구간의 최적 분산 계수 편차는 채널수가 증가할수록 커져야 한다는 것을 확인하였다. 그러나 최적 OPC 위치 편차와 광섬유 구간의 최적 분산 계수 편차가 동시에 증가하기 때문에 OPC 위치 이동 1 km 당 최적 분산 계수 값은 WDM 채널수에 크게 의존하지 않는다는 것을 알 수 있었다. 그리고 이들 최적 파라미터 값들은 WDM 채널수가 적은 시스템에서보다 채널수가 많은 시스템에 더욱 효과적이라는 것을 알 수 있었다.

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The Modified Eulerian-Lagrangian Formulation for Cauchy Boundary Condition Under Dispersion Dominated Flow Regimes: A Novel Numerical Approach and its Implication on Radioactive Nuclide Migration or Solute Transport in the Subsurface Environment

  • Sruthi, K.V.;Suk, Heejun;Lakshmanan, Elango;Chae, Byung-Gon;Kim, Hyun-su
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제20권2호
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    • pp.10-21
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    • 2015
  • The present study introduces a novel numerical approach for solving dispersion dominated problems with Cauchy boundary condition in an Eulerian-Lagrangian scheme. The study reveals the incapability of traditional Neuman approach to address the dispersion dominated problems with Cauchy boundary condition, even though it can produce reliable solution in the advection dominated regime. Also, the proposed numerical approach is applied to a real field problem of radioactive contaminant migration from radioactive waste repository which is a major current waste management issue. The performance of the proposed numerical approach is evaluated by comparing the results with numerical solutions of traditional FDM (Finite Difference Method), Neuman approach, and the analytical solution. The results show that the proposed numerical approach yields better and reliable solution for dispersion dominated regime, specifically for Peclet Numbers of less than 0.1. The proposed numerical approach is validated by applying to a real field problem of radioactive contaminant migration from radioactive waste repository of varying Peclet Number from 0.003 to 34.5. The numerical results of Neuman approach overestimates the concentration value with an order of 100 than the proposed approach during the assessment of radioactive contaminant transport from nuclear waste repository. The overestimation of concentration value could be due to the assumption that dispersion is negligible. Also our application problem confirms the existence of real field situation with advection dominated condition and dispersion dominated condition simultaneously as well as the significance or advantage of the proposed approach in the real field problem.

분산응력법을 이용한 곡선수로에서의 천수흐름 해석 (Analysis of Shallow Water Flow in Curved Channel Using Dispersion Stresses Method)

  • 송창근;서일원;김태원;안정규
    • 대한토목학회논문집
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    • 제33권5호
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    • pp.1785-1795
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    • 2013
  • 기존 대부분의 천수흐름 해석모형에서는 연직방향으로 균일한 유속을 가정하였기 때문에 하천 만곡부에서 이차류의 영향을 고려하지 못하고 부정확한 흐름해석 결과를 도출하였다. 본 연구에서는 종횡방향 유속의 연직분포를 평균값과 이로부터의 변동량으로 분할하여 이 값들을 운동량 방정식에 대입하여 생성되는 추가적인 항인 분산응력을 포함하는 수치모형을 개발하였다. 제안된 모형을 $30^{\circ}$, $90^{\circ}$, $270^{\circ}$의 곡률을 가지는 수로에 적용하여 분산응력을 이용한 곡선수로에서의 천수흐름을 수치모의 하였다. 모의 결과, 운동량방정식에 포함된 분산응력항은 생성/소멸과 같은 역할을 하여, 만곡의 내측에서 외측으로 횡방향 운동량을 이동시키게 되므로 분산응력을 포함하지 않는 경우 보다 정확한 수치모의 결과를 제시하는 것으로 밝혀졌다.

의료용 초음파 위상배열 트랜스듀서의 열 분산 방안 (Thermal Dispersion Method for a Medical Ultrasonic Phased Array Transducer)

  • 이원석;노용래
    • 한국음향학회지
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    • 제34권3호
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    • pp.210-218
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    • 2015
  • 초음파 영상 품질의 향상을 위해 트랜스듀서의 구동전압을 높이게 되면 트랜스듀서에서 열이 발생하여 환자의 피부 화상 및 트랜스듀서의 성능 저하를 초래할 수 있다. 따라서, 이렇게 온도가 상승하지 않도록 트랜스듀서 내의 열을 효율적으로 분산할 수 있는 방안에 대해 연구하였다. 이때 열 분산 해석 대상으로 중심주파수가 3 MHz이고 32채널을 가진 위상배열 트랜스듀서를 선정하였다. 먼저 트랜스듀서의 동작에 따른 발열 구조를 이론적으로 분석하였고, 그 결과로서 재료의 감쇠와 음압의 크기가 발열에 영향을 미치는 것을 확인하였다. 나아가 유한요소 해석을 통해 트랜스듀서 구성소자의 물성이 열 분산에 미치는 영향을 분석하였다. 분석된 결과를 바탕으로 트랜스듀서 내 열이 잘 분산되기 위한 구성소자의 열물성을 정하였다. 도출된 열 물성을 유한요소 해석 모델에 적용한 결과 환자와 접촉되는 부분인 음향렌즈의 최고온도가 원래 값의 51 %로 저하되었다.

APSM의 예측능 평가에 관한 연구 (A study on the Assessment of the Predictability of the APSM)

  • 박기하;윤순창
    • 한국환경과학회지
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    • 제12권3호
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    • pp.265-274
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    • 2003
  • The Pasquill-Gifford stability category is a very important scheme of the Gaussian type dispersion model defined the complex turbulence state of the atmosphere by A grade(very unstable) to F grade(very stable). But there has been made a point out that this stability category might decrease the predictability of the model because it was each covers a broad range of stability conditions, and that they were very site specific. The APSM (Air Pollution Simulation Model) was composed of the turbulent parameters, i.e. friction velocity(${\mu}$$\_$*/), convective velocity scale($\omega$$\_$*/) and Monin-Obukhov length scale(L) for the purpose of the performance increasing on the case of the unstable atmospheric conditions. And the PDF (Probability Density Function)model was used to express the vertical dispersion characteristics and the profile method was used to calculate the turbulent characteristics. And the performance assessment was validated between APSM and EPA regulatory models(TEM, ISCST), tracer experiment results. There were very good performance results simulated by APSM than that of TEM, ISCST in the short distance (<1415 m) from the source, but increase the simulation error(%) to stand off the source in others. And there were differences in comparison with the lateral dispersion coefficient($\sigma$$\_$y/) which was represent the horizontal dispersion characteristics of a air pollutant in the atmosphere. So the different calculation method of $\sigma$$\_$y/ which was extrapolated from a different tracer experiment data might decrease the simulation performance capability. In conclusion, the air pollution simulation model showed a good capability of predict the air pollution which was composed of the turbulent parameters compared with the results of TEM and ISCST for the unstable atmospheric conditions.

The Annual Averaged Atmospheric Dispersion Factor and Deposition Factor According to Methods of Atmospheric Stability Classification

  • Jeong, Hae Sun;Jeong, Hyo Joon;Kim, Eun Han;Han, Moon Hee;Hwang, Won Tae
    • Journal of Radiation Protection and Research
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    • 제41권3호
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    • pp.260-267
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    • 2016
  • Background: This study analyzes the differences in the annual averaged atmospheric dispersion factor and ground deposition factor produced using two classification methods of atmospheric stability, which are based on a vertical temperature difference and the standard deviation of horizontal wind direction fluctuation. Materials and Methods: Daedeok and Wolsong nuclear sites were chosen for an assessment, and the meteorological data at 10 m were applied to the evaluation of atmospheric stability. The XOQDOQ software program was used to calculate atmospheric dispersion factors and ground deposition factors. The calculated distances were chosen at 400 m, 800 m, 1,200 m, 1,600 m, 2,400 m, and 3,200 m away from the radioactive material release points. Results and Discussion: All of the atmospheric dispersion factors generated using the atmospheric stability based on the vertical temperature difference were shown to be higher than those from the standard deviation of horizontal wind direction fluctuation. On the other hand, the ground deposition factors were shown to be same regardless of the classification method, as they were based on the graph obtained from empirical data presented in the Nuclear Regulatory Commission's Regulatory Guide 1.111, which is unrelated to the atmospheric stability for the ground level release. Conclusion: These results are based on the meteorological data collected over the course of one year at the specified sites; however, the classification method of atmospheric stability using the vertical temperature difference is expected to be more conservative.

이종 강화재를 첨가한 폴리우레탄 폼의 기계적 및 열적 특성과 제작 시 초음파 분산의 영향 (Mechanical and Thermal Characteristics of Polyurethane Foam with Two Different Reinforcements and the Effects of Ultrasonic Dispersion in Manufacturing)

  • 김진연;김정대;이제명
    • 대한조선학회논문집
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    • 제56권6호
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    • pp.515-522
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    • 2019
  • Since Liquefied Natural Gas (LNG) is normally carried at 1.1 bar pressure and at -163℃, special Cargo Containment System (CCS) are used. As LNG carrier is becoming larger, typical LNG insulation systems adopt a method to increase the thickness of insulation panel to reduce sloshing load and Boil-off Rate (BOR). However, this will decrease LNG cargo volume and increase insulation material costs. In this paper, silica aerogel, glass bubble were synthesized in polyurethane foam to increase volumetric efficiency by improving mechanical and thermal performance of insulation. In order to increase dispersibility of particles, ultrasonic dispersion was used. Dynamic impact test, quasi-static compression test at room temperature (20℃) and cryogenic temperature (-163℃) was evaluated. To evaluate the thermal performance, the thermal conductivity at room temperature (20℃) was measured. As a result, specimens without ultrasonic dispersion have a little effect on strength under the compressive load, although they show high mechanical performance under the impact load. In contrast, specimens with ultrasonic dispersion have significantly increased impact strength and compressive strength. Recently, as the density of Polyurethane foam (PUF) has been increasing, these results can be a method for improving the mechanical and thermal performance of insulation panel.

[Retraction]Characterization of carbon black nanoparticles using asymmetrical flow field-flow fractionation (AsFlFFF)

  • Kim, Kihyun;Lee, Seungho;Kim, Woonjung
    • 분석과학
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    • 제32권3호
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    • pp.77-87
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    • 2019
  • High viscosity carbon black dispersions are used in various industrial fields such as color cosmetics, rubber, tire, plastic and color filter ink. However, carbon black particles are unstable to heat due to inherent characteristics, and it is very difficult to keep the quality of the product constant due to agglomeration of particles. In general, particle size analysis is performed by dynamic light scattering (DLS) during the dispersion process in order to select the optimum dispersant in the carbon black dispersion process. However, the existing low viscosity analysis provides reproducible particle distribution analysis results, but it is difficult to select the optimum dispersant because it is difficult to analyze the reproducible particle distribution at high viscosity. In this study, dynamic light scattering (DLS) and asymmetrical flow field-flow fractionation (AsFlFFF) analysis methods were compared for reproducible particle size analysis of high viscosity carbon black. First, the stability of carbon black dispersion was investigated by particle size analysis by DLS and AsFlFFF according to milling time, and the validity of analytical method for the selection of the optimum dispersant useful for carbon black dispersion was confirmed. The correlation between color and particle size of particles in high viscosity carbon black dispersion was investigated by using colorimeter. The particle size distribution from AsFlFFF was consistent with the colorimetric results. As a result, the correlation between AsFlFFF and colorimetric results confirmed the possibility of a strong analytical method for determining the appropriate dispersant and milling time in high viscosity carbon black dispersions. In addition, for nanoparticles with relatively broad particle size distributions such as carbon black, AsFlFFF has been found to provide a more accurate particle size distribution than DLS. This is because AsFlFFF, unlike DLS, can analyze each fraction by separating particles by size.

Improvement in Plume Dispersion Formulas for Stack Emissions Using Ground-based Imaging-DOAS Data

  • Lee, Hanlim;Ryu, Jaeyong;Jeong, Ukkyo;Noh, Youngmin;Shin, Sung Kyun;Hong, Hyunkee;Kwon, Soonchul
    • Bulletin of the Korean Chemical Society
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    • 제35권12호
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    • pp.3427-3432
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    • 2014
  • This study introduces a new method of combining Imaging Differential Optical Absorption Spectroscopy (Imaging-DOAS) data and plume dispersion formulas for power plant emissions to determine the three-dimensional structure of a dispersing pollution plume and the spatial distributions of trace gas volume mixing ratios (VMRs) under conditions of negligible water droplet and aerosol effects on radiative transfer within the plume. This novel remote-sensing method, applied to a power plant stack plume, was used to calculate the two-dimensional distributions of sulfur dioxide ($SO_2$) and nitrogen dioxide ($NO_2$) VMRs in stack emissions for the first time. High $SO_2$ VMRs were observed only near the emission source, whereas high $NO_2$ VMRs were observed at locations several hundreds of meters away from the initial emission. The results of this study demonstrate the capability of this new method as a tool for estimating plume dimensions and trace gas VMRs in power plant emissions.