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http://dx.doi.org/10.4191/kcers.2011.48.6.537

Preparation of Mg(OH)2 Dispersion and its Application to PET Non-woven Textile as Flame Retardant Coating  

Lim, Hyung-Mi (Eco-Composite Materials Center, Green Ceramics Division, Korea Institute of Ceramic Engineering and Technology)
Hyun, Mi-Kyung (Eco-Composite Materials Center, Green Ceramics Division, Korea Institute of Ceramic Engineering and Technology)
Jeong, Sang-Ok (Nanotech Ceramics Co. Ltd.)
Lee, Dong-Jin (Eco-Composite Materials Center, Green Ceramics Division, Korea Institute of Ceramic Engineering and Technology)
Lee, Seung-Ho (Eco-Composite Materials Center, Green Ceramics Division, Korea Institute of Ceramic Engineering and Technology)
Publication Information
Abstract
Magnesium hydroxide as a non-halogen flame retardant has increasing attention due to its non-toxicity, high decomposition temperature and smoke suppressant ability during combustion. For the application of magnesium hydroxide retardant to the textile by soaking and coating method, the prerequisite for the coating is a small particle size, stable dispersion, and adhesion to the textile. The dispersion of $Mg(OH)_2$ particles and stability of the coating was checked by monitoring the change of transmittance and backscattering by varying the types of dispersion agents, binder, solvent, and $Mg(OH)_2$ source, and their compositions in the coating. The $Mg(OH)_2$ dispersion coating was applied to PET(poly(ethylene terephthalate)) non-woven textile. The physical properties are characterized by surface morphology, amount of coating, particle dispersion, and adhesion test. The flame retardant $Mg(OH)_2$ coated textile has been compared by limited oxygen index(LOI) and thermal gravimetry and differential scanning calorimetry(TG-DSC). It was found that phosphorous additive may give synergistic effect on $Mg(OH)_2$ flame retardant coating to make the flame retardant PET non-woven textile.
Keywords
Magnesium hydroxide dispersion; Phosphorous compound; Flame retardant; PET non-woven textile;
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Times Cited By KSCI : 2  (Citation Analysis)
Times Cited By SCOPUS : 0
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1 H. M. Lim, J. Yun, M. Hyun, Y. Yoon, D. J. Lee, C. M. Whang, S. O. Jeong, and S. H. Lee, "Magnesium Hydroxide Flame Retardant and its Application to a Low-density Polyethylene/ ethylene Vinyl Acetate Composite," J. Ceram. Process. Res., 10 [4] 571-76 (2009).
2 F. Carosio, G. Laufer, J. Alongi, G. Camino, and J. C. Grunlan, "Layer-by Layer Assembly of Silica-based Flame Retardant thin Film on PET Fabric," Progress in Polym. Sci., 96 745-50 (20110).
3 P. Kiliaris and C. D. Papaspyrides, "Polymer/layered Silicate(Clay) Nanocomposites: An Overview of Flame Retardancy," Progress in Poly. Sci., 35 902-58 (2010).   DOI
4 M. Qu, Y. Wang, C. Wang, X. Ge, D. Wang, and Q. Zhou, "A Novel Method for Preparing Poly(ethylene terephthalate)/ $BaSO_4$ Nanocomposites," Europ. Polymer J., 41 [11] 2569-74 (2005).   DOI
5 W. Liu, X. Tian, P. Cui, Y. Li, K. Zheng, and Y. Yang, "Preparation and Characterization of PET/silica Nanocomposites," J. Appl. Polymer Sci., 91 [2] 1229-32 (2004).   DOI
6 D. Y. Wang, X. Q. Liu, J. S. Wang, Y. Z. Wang, A. A. Stec, and R. Hull, "Preparation and Characterisation of a Novel Fire Retardant PET/${\alpha}$-zirconium Phosphate Nanocomposite," Polymer Degradation Stability, 94 [4] 544-49 (2009).   DOI
7 Y. H. Shin, W. D. Lee, and S. S. Im, "Effect of A-zeolite on the Crystallization Behavior of In-situ Polymerized Poly(ethylene terephthalate) (PET) Nanocomposites," Macromolecular Res., 15 [7] 662-70 (2007).   과학기술학회마을   DOI
8 Zeng Ke and Bai Yongping, "Improve the Gas Barrier Property of PET Film with Montmorillonite by in Situ Interlayer Polymerization," Mater. Lett., 59 [27] 3348-51 (2005).   DOI
9 H. M. Lim, J. Yoon, S. O. Jeong, D. J. Lee, and S.-H. Lee, "Preparation of $Mg(OH)_2$-melamine Core-shell Particle and its Flame Retardant Property (in Korean)," Kor. J. Mater. Res., 20 [12] 691-98(2010).   과학기술학회마을   DOI
10 A. R. Horrocks, "Flame Retardant Chanllenges for Textiles and Fibers: New Chemistry Versus Innovatory Solutions," Polymer Degradation Stability, 96 377-92 (2001).