• 제목/요약/키워드: dispersion effect

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CaCO3 안료의 분산 안정성에 대한 용제의 영향 (Effect of Solvent on the Dispersion Stability of CaCO3 Pigment)

  • 이근대;류영철;서차수;홍성수;안병현;문명준
    • 공업화학
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    • 제8권2호
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    • pp.252-261
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    • 1997
  • 여러 종류의 용제와 수지용액에 있어서의 $CaCO_3$ 안료의 분산 안정성을 Dynometer를 이용하여 조사하였다. Dynometer를 이용하여 비교적 단시간에 분산계의 분산 안정성을 평가할 수 있었으며, Dynometer를 이용한 분산 안정성 평가로부터 구한 $CaCO_3$ 안료의 용해성 파라미터, ${\delta}$는 11.62(${\delta}_d=8.04$, ${\delta}_p=5.05$, ${\delta}_h=6.70$)이었다. 안료와 친화력이 약한 용제가 첨가되는 경우 수지 용액내에서의 안료표면에의 수지 흡착층을 증가시켜 수지 용액내에서의 분산 안정성을 증가시켰다. 수지 용액 제조시 소량 첨가된 용제도 안료를 포함한 전체 분산계의 유동성과 분산 안정성에 큰 영향을 미친다는 것을 알 수 있었다.

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지진해일 전파 분산보정 유한차분모형의 정밀도 평가 (Accuracy Evaluation of Dispersion-Correction Finite Difference Model for Tsunami Propagation)

  • 윤성범;임채호;조용식;최철순
    • 한국해안해양공학회지
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    • 제14권2호
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    • pp.116-127
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    • 2002
  • 대부분의 지진해일에 대한 수치모의는 천수방정식을 지배방정식으로 하고 leap-frog 유한차분기법을 주로 적용한다. 이 기법은 격자간격을 적절히 선정하면 분산효과를 옳게 고려할 수 있으나, 수심이 변하는 경우 전 계산영역에서 분산효과를 모두 만족시킬 수는 없다. 본 연구에서는 균일한 격자와 계산시간간격을 사용하면서도 수심이 완만하게 변하는 지형상을 전파하는 지진해일의 국부적인 분산관계를 만족시키기 위해 기존의 2차원 완 변수심상 분산보정 유한차분기법을 개선하고, 이 수치모형의 현장 적용성을 검증하기 위해 1983년 동해중부 지진해일을 검조기록이 있는 동해안의 속초, 묵호, 포항 그리고 울산항에 대하여 수치모의하였다. 또한 1983년 지진해일에 대해 각 항만에서 측정된 검조기록과 수치모의에 의해 계산된 값을 비교 분석하여 수치모형의 정밀도를 평가하였다.

CSRZ 신호의 클럭 성분을 이용한 색분산 감시법에서 송수신단 대역폭의 영향 분석 (Bandwidth Effect on the Dispersion Monitoring of CSRZ Signal Based on Clock Component)

  • 김성만
    • 한국전자통신학회논문지
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    • 제8권9호
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    • pp.1343-1349
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    • 2013
  • 광통신 시스템에서는 제한된 대역폭에서 최상의 성능을 얻기 위해 다양한 신호형태가 사용되고 있다. 그중에서도 CSRZ (carrier-suppressed return-to-zero) 신호는 스펙트럼 효율이 높으면서도 색분산에 대해 비교적 강인한 특성을 지니고 있어 많이 사용되고 있다. 우리는 이러한 CSRZ 신호의 중요성을 파악하고, 이전의 연구에서 CSRZ 신호의 클럭 (clock) 성분을 이용하여 색분산을 감시하는 방법을 제시한 바가 있다. 하지만, 클럭 성분을 이용하여 색분산을 감시하는 방법은 송수신단의 대역폭에 의해 그 영향을 받을 수 있다. 따라서, 본 논문에서는 CSRZ 신호에서 송수신단의 대역폭이 클럭 성분을 이용한 색분산 감시법에 미치는 영향을 분석하고, 송수신단의 대역폭이 변하더라도 그 성능이 유지될 수 있는 강인한 클럭 추출법을 제시한다.

Effect of Multi-walled Carbon Nanotube Dispersion on the Electrical, Morphological and Rheological Properties of Polycarbonate/Multi-walled Carbon Nanotube Composites

  • Han, Mi-Sun;Lee, Yun-Kyun;Kim, Woo-Nyon;Lee, Heon-Sang;Joo, Jin-Soo;Park, Min;Lee, Hyun-Jung;Park, Chong-Rae
    • Macromolecular Research
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    • 제17권11호
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    • pp.863-869
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    • 2009
  • The effect of a multiwalled carbon nanotube (MWCNT) dispersion on the electrical, morphological and rheological properties of polycarbonate (PC)/MWCNT composites was investigated, with and without pretreating the MWCNTs with hydrogen peroxide oxidation and lyophilization. The resulting PC/treated MWCNT composites showed higher electrical conductivity than the PC/untreated MWCNT composites. The morphological behavior indicated the treated composites to have greater dispersion of MWCNTs in the PC matrix. In addition, the electromagnetic interference shielding efficiency (EMI SE) of the treated composites was higher than that of the untreated ones. Rheological studies of the composites showed that the complex viscosity of the treated composites was higher than the untreated ones due to increased dispersion of the MWCNTs in the PC matrix, which is consistent with the electrical conductivity, EMI SE and morphological studies of the treated composites. The latter results suggested that the increased electrical conductivity and EMI SE of the treated composites were mainly due to the increased dispersion of MWCNTs in the PC matrix.

Numerical Simulation of Buoyant flume Dispersion in a Stratified Atmosphere Using a Lagrangian Stochastic Model

  • Kim, Hyun-Goo;Noh, Yoo-Jeong;Lee, Choung-Mook;Park, Don-Bum
    • Journal of Mechanical Science and Technology
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    • 제17권3호
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    • pp.440-448
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    • 2003
  • In the present paper, numerical simulations of buoyant plume dispersion in a neutral and stable atmospheric boundary layer have been carride out. A Lagrangian Stochastic Model (LSM) with a Non-Linear Eddy Viscosity Model (NLEVM) for turbulence is used to generate a Reynolds stress field as an input condition of dispersion simulation. A modified plume-rise equation is included in dispersion simulation in order to consider momentum effect in an initial stage of plume rise resulting in an improved prediction by comparing with the experimental data. The LSM is validated by comparing with the prediction of an Eulerian Dispersion Model (EDM) and by the measured results of vertical profiles of mean concentration in the downstream of an elevated source in an atmospheric boundary layer. The LSM predicts accurate results especially in the vicinity of the source where the EDM underestimates the peak concentration by 40% due to inherent limitations of gradient diffusion theory. As a verification study, the LSM simulation of buoyant plume dispersions under a neutral and stable atmospheric condition is compared with a wind-tunnel experiment, which shows good qualitative agreements.

폴리아크릴산 소다에 의한 중질 탄산칼슘의 분산효과 (Effects of Ground Calcium Carbonate Dispersion by Sodium Polyacrylate)

  • 노윤찬;정태영;조경행;노승호;남기대
    • 한국응용과학기술학회지
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    • 제10권1호
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    • pp.49-55
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    • 1993
  • Ground Calcium Carbonate, among paper coating pigments, will influence less dispersant demand, less binder demand, increase coating solids from 58% to 70%, which means high speed coating, less shrinkage during drying, less energy consumption, more uniform coverage of fibers. The quality point of view of Ground Calcium Carbonate, brightness, particle size, Particle size distribution, hardness, impurities content are important. More important factors of Ground Calcium Carbonate which influence the paper coating process are dispersion mechanisms and their effects. The study was made to investigate the effect of Ground Calcium Carbonate dispersion by sodium salt of polyacrylate dispersant composition and dispersion condition. Basic tests such as physical, optical and chemical were perfumed, and dispersion effects were investigated by different conditions. The results showed that the type of dispersant affected the dispersion effects, and the Ground Calcium Carbonate has critical dispersant demand.

Mechanical Properties of Vapor Grown Carbon Fiber/Epoxy Nanocomposites With Different Dispersion Methods

  • Khuyen, Nguyen Quang;Kim, Byung-Sun;Kim, Jin-Bong;Lee, Soo
    • 한국응용과학기술학회지
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    • 제24권3호
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    • pp.264-271
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    • 2007
  • Effect of dispersion methods for Vapor Grown Carbon Fibers (VGCF) in epoxy caused the change in mechanical properties of VGCF/epoxy nanocomposites, such as tensile modulus and tensile strength. The influence of VGCF types - atmospheric plasma treated (APT) VGCF and raw VGCF - and their contents was discussed in detail. Treating VGCF with atmospheric plasma enhanced the surface energy, therefore improved the bonding strength with epoxy matrix. Two different methods used to disperse VGCF were ultrasonic and mechanical homogenizer methods. When using dispersion solutions, the VGCF demonstrated good dispersion in ethanol in both homogenizer and ultrasonic method. The uniform dispersion of VGCF was investigated by scanning electron microscopy (SEM) which showed well-dispersion of VGCF in epoxy matrix. The tensile modulus of raw VGCF/epoxy nanocomposites obtained by ultrasonic method was higher than that of one obtained by homogenizer method. APT VGCF/epoxy nanocomposites showed higher tensile strength than that of raw VGCF/epoxy nanocomposites.

A novel preparation and formation mechanism of carbon nanotubes aerogel

  • Li, Shaolong;He, Yan;Jing, Chengwei;Gong, Xiubin;Cui, Lianlei;Cheng, Zhongyue;Zhang, Chuanqi;Nan, Fei
    • Carbon letters
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    • 제28권
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    • pp.16-23
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    • 2018
  • A novel, unique, and effective method for carbon nanotube (CNT) dispersion by the free arc stimulation is proposed. CNTs are introduced as an aerogel into the air space via the dispersion method and can be utilized as a solution by adding it to solvents. The volume of the original generated CNT aerogel with a high-volume expansion ratio displays a performance two orders of magnitudes better than that of raw CNTs, which is considered a powerful characterization of the dispersion effect. The CNT aerogel, which was observed by scanning electron microscopy also showed a satisfactory dispersion morphology. Its structure and properties were tested before and after dispersion by Raman spectroscopy and great consistency was observed, which proved that the CNTs were undamaged. This approach may greatly promote the large-scale application of CNTs.

주파수 의존성이 표면탄성파의 속도 결정에 미치는 영향 (The Effect of Dispersion Relations on the Determination of Surface Acoustical Wave Velocity)

  • 권성덕;윤석수;이승희
    • 비파괴검사학회지
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    • 제19권5호
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    • pp.340-346
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    • 1999
  • 액체/고체 경계면에 표면파가 발생할 때 나타나는 최소반사 및 후방복사 현상을 이용하여 brass와 aluminum 시편 그리고 copper/stainless steel, nickel/brass, nickel/aluminum 도금시편에 대한 표면 탄성파 속도의 주파수 의존성이 측정되었다. 측정된 속도의 분산관계는 일반화 램 표면파의 분산 특성과 잘 일치하였다. 시편들의 분산 특징에 따라 최소반사와 후방복사에 의해 결정된 속도 차이의 경향이 다르게 나타났다. 이러한 대응 관계는 두 현상의 생성 메커니즘과 군속도의 도입으로 설명되었다.

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Dispersion and Flocculation Behavior of Metal Oxide in Organic Solvent

  • Fujii, Katsuya;Yamamoto, Hideki;Shibata, Junji
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.353-356
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    • 2001
  • The relation between the flocculation and dispersion of metal oxide powders and the properties of solvents, such as dielectric constant and solubility parameter, was investigated for TiO$_2$, $Al_2$O$_3$and Fe$_2$O$_3$particles. The particle size and median diameter of these metal oxides were measured in many organic solvents, from which the effect of solvents on the flocculation and dispersion of metal oxide powders was considered. The metal oxide powders of TiO$_2$, $Al_2$O$_3$and Fe$_2$O$_3$tend to disperse in a solvent of higher polarity, whereas they are apt to flocculate in a solvent of low dielectric constant, because the Hamaker constant between the particles becomes larger in such a solvent. There we, however, some solvents that do not obey these tendencies. It is possible to evaluate the flocculation and dispersion of these metal oxide powders in many solvents by using numeral balances of Hansen’s three-dimensional solubility parameter (f$_{d}$, f$_{p}$ and f$_{h}$). There exists a solvent giving the optimal dispersion for each metal oxide, and the optimal dispersion point of f$_{d}$, f$_{p}$ and f$_{h}$ is determined by the combination of various metal oxide powders and solvents.nts.nts.nts.

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