• Title/Summary/Keyword: dispersion effect

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Effect of Solvent on the Dispersion Stability of CaCO3 Pigment (CaCO3 안료의 분산 안정성에 대한 용제의 영향)

  • Lee, Gun Dae;Ryu, Young Cheal;Suh, Cha Soo;Hong, Seong Soo;Ahn, Byung Hyun;Moon, Myung Jun
    • Applied Chemistry for Engineering
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    • v.8 no.2
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    • pp.252-261
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    • 1997
  • The effect of solvent on the dispersion stability of $CaCO_3$ pigment in various solvents and resin solutions has been studied using Dynometer. Dispersion stability can be estimated in a relatively short time by means of Dynometer and the solubility parameter, ${\delta}$, of $CaCO_3$ determined from dispersion stability was 11.62(${\delta}_d=8.04$, ${\delta}_p=5.05$, ${\delta}_h=6.70$). The solvent showing weaker interaction with pigment increased the adsorption of resin on to the pigment, resulting in higher dispersion stability in resin solution. It was found that the rheological properties and dispersion stability of pigmented resin solution were depending strongly on the solvent added in small amount in the formulation.

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Accuracy Evaluation of Dispersion-Correction Finite Difference Model for Tsunami Propagation (지진해일 전파 분산보정 유한차분모형의 정밀도 평가)

  • 윤성범;임채호;조용식;최철순
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.14 no.2
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    • pp.116-127
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    • 2002
  • Most of finite difference numerical models for the simulation of tsunami propagation developed so for are based on the shallow-water equations which are frequently solved by the leap-frog scheme. If the grid size is properly selected, this numerical scheme gives a correct dispersion effect fur constant water depth. However, if the water depth changes, the dispersion effect of tsunamis can not be accurately considered at every grid point in the whole computational domain. In this study we improved the existing two-dimensional dispersion-correction finite difference numerical scheme. The present scheme satisfies the local dispersion relationships of tsunamis propagating over a slowly varying topography while using uniform grid size and time step. To verify the applicability of the improved numerical model, a tsunami due to 1983 East Sea central earthquake is simulated for Korean harbors with the tide gage records such as Sokcho, Mukho, Pohang and Ulsan in the East Sea. Numerical results of the 1983 tsunami are compared with the measured data and the accuracy of the present numerical model is evaluated.

Bandwidth Effect on the Dispersion Monitoring of CSRZ Signal Based on Clock Component (CSRZ 신호의 클럭 성분을 이용한 색분산 감시법에서 송수신단 대역폭의 영향 분석)

  • Kim, Sung-Man
    • The Journal of the Korea institute of electronic communication sciences
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    • v.8 no.9
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    • pp.1343-1349
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    • 2013
  • In optical fiber communications, several newly-developed signal formats are used to obtain the best performance within limited spectral bandwidth. CSRZ (carrier-suppressed return-to-zero) format is one of the new signal formats, which has better spectral efficiency and better robustness to dispersion than RZ (return-to-zero) format. Thus it is widely used for demonstrating high-speed optical communication systems. In an earlier research, we proposed a clock-extraction method of CSRZ signal to monitor chromatic dispersion. However, the clock-frequency component extracted by the clock-extraction method can be affected by the bandwidth of a transmitter or a receiver. Therefore, in this paper, we investigate the effect of bandwidth on the chromatic dispersion monitoring of CSRZ signal based on clock-frequency component. As a result, we propose a couple of robust clock-extraction methods to monitor chromatic dispersion in CSRZ signal.

Effect of Multi-walled Carbon Nanotube Dispersion on the Electrical, Morphological and Rheological Properties of Polycarbonate/Multi-walled Carbon Nanotube Composites

  • Han, Mi-Sun;Lee, Yun-Kyun;Kim, Woo-Nyon;Lee, Heon-Sang;Joo, Jin-Soo;Park, Min;Lee, Hyun-Jung;Park, Chong-Rae
    • Macromolecular Research
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    • v.17 no.11
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    • pp.863-869
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    • 2009
  • The effect of a multiwalled carbon nanotube (MWCNT) dispersion on the electrical, morphological and rheological properties of polycarbonate (PC)/MWCNT composites was investigated, with and without pretreating the MWCNTs with hydrogen peroxide oxidation and lyophilization. The resulting PC/treated MWCNT composites showed higher electrical conductivity than the PC/untreated MWCNT composites. The morphological behavior indicated the treated composites to have greater dispersion of MWCNTs in the PC matrix. In addition, the electromagnetic interference shielding efficiency (EMI SE) of the treated composites was higher than that of the untreated ones. Rheological studies of the composites showed that the complex viscosity of the treated composites was higher than the untreated ones due to increased dispersion of the MWCNTs in the PC matrix, which is consistent with the electrical conductivity, EMI SE and morphological studies of the treated composites. The latter results suggested that the increased electrical conductivity and EMI SE of the treated composites were mainly due to the increased dispersion of MWCNTs in the PC matrix.

Numerical Simulation of Buoyant flume Dispersion in a Stratified Atmosphere Using a Lagrangian Stochastic Model

  • Kim, Hyun-Goo;Noh, Yoo-Jeong;Lee, Choung-Mook;Park, Don-Bum
    • Journal of Mechanical Science and Technology
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    • v.17 no.3
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    • pp.440-448
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    • 2003
  • In the present paper, numerical simulations of buoyant plume dispersion in a neutral and stable atmospheric boundary layer have been carride out. A Lagrangian Stochastic Model (LSM) with a Non-Linear Eddy Viscosity Model (NLEVM) for turbulence is used to generate a Reynolds stress field as an input condition of dispersion simulation. A modified plume-rise equation is included in dispersion simulation in order to consider momentum effect in an initial stage of plume rise resulting in an improved prediction by comparing with the experimental data. The LSM is validated by comparing with the prediction of an Eulerian Dispersion Model (EDM) and by the measured results of vertical profiles of mean concentration in the downstream of an elevated source in an atmospheric boundary layer. The LSM predicts accurate results especially in the vicinity of the source where the EDM underestimates the peak concentration by 40% due to inherent limitations of gradient diffusion theory. As a verification study, the LSM simulation of buoyant plume dispersions under a neutral and stable atmospheric condition is compared with a wind-tunnel experiment, which shows good qualitative agreements.

Effects of Ground Calcium Carbonate Dispersion by Sodium Polyacrylate (폴리아크릴산 소다에 의한 중질 탄산칼슘의 분산효과)

  • Ro, Yoon-Chan;Jeong, Tae-Young;Cho, Kyoung-Haeng;Roh, Seung-Ho;Nam, Ki-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.10 no.1
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    • pp.49-55
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    • 1993
  • Ground Calcium Carbonate, among paper coating pigments, will influence less dispersant demand, less binder demand, increase coating solids from 58% to 70%, which means high speed coating, less shrinkage during drying, less energy consumption, more uniform coverage of fibers. The quality point of view of Ground Calcium Carbonate, brightness, particle size, Particle size distribution, hardness, impurities content are important. More important factors of Ground Calcium Carbonate which influence the paper coating process are dispersion mechanisms and their effects. The study was made to investigate the effect of Ground Calcium Carbonate dispersion by sodium salt of polyacrylate dispersant composition and dispersion condition. Basic tests such as physical, optical and chemical were perfumed, and dispersion effects were investigated by different conditions. The results showed that the type of dispersant affected the dispersion effects, and the Ground Calcium Carbonate has critical dispersant demand.

Mechanical Properties of Vapor Grown Carbon Fiber/Epoxy Nanocomposites With Different Dispersion Methods

  • Khuyen, Nguyen Quang;Kim, Byung-Sun;Kim, Jin-Bong;Lee, Soo
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.3
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    • pp.264-271
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    • 2007
  • Effect of dispersion methods for Vapor Grown Carbon Fibers (VGCF) in epoxy caused the change in mechanical properties of VGCF/epoxy nanocomposites, such as tensile modulus and tensile strength. The influence of VGCF types - atmospheric plasma treated (APT) VGCF and raw VGCF - and their contents was discussed in detail. Treating VGCF with atmospheric plasma enhanced the surface energy, therefore improved the bonding strength with epoxy matrix. Two different methods used to disperse VGCF were ultrasonic and mechanical homogenizer methods. When using dispersion solutions, the VGCF demonstrated good dispersion in ethanol in both homogenizer and ultrasonic method. The uniform dispersion of VGCF was investigated by scanning electron microscopy (SEM) which showed well-dispersion of VGCF in epoxy matrix. The tensile modulus of raw VGCF/epoxy nanocomposites obtained by ultrasonic method was higher than that of one obtained by homogenizer method. APT VGCF/epoxy nanocomposites showed higher tensile strength than that of raw VGCF/epoxy nanocomposites.

A novel preparation and formation mechanism of carbon nanotubes aerogel

  • Li, Shaolong;He, Yan;Jing, Chengwei;Gong, Xiubin;Cui, Lianlei;Cheng, Zhongyue;Zhang, Chuanqi;Nan, Fei
    • Carbon letters
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    • v.28
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    • pp.16-23
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    • 2018
  • A novel, unique, and effective method for carbon nanotube (CNT) dispersion by the free arc stimulation is proposed. CNTs are introduced as an aerogel into the air space via the dispersion method and can be utilized as a solution by adding it to solvents. The volume of the original generated CNT aerogel with a high-volume expansion ratio displays a performance two orders of magnitudes better than that of raw CNTs, which is considered a powerful characterization of the dispersion effect. The CNT aerogel, which was observed by scanning electron microscopy also showed a satisfactory dispersion morphology. Its structure and properties were tested before and after dispersion by Raman spectroscopy and great consistency was observed, which proved that the CNTs were undamaged. This approach may greatly promote the large-scale application of CNTs.

The Effect of Dispersion Relations on the Determination of Surface Acoustical Wave Velocity (주파수 의존성이 표면탄성파의 속도 결정에 미치는 영향)

  • Kwon, Sung-D.;Yoon, Seok-S.;Lee, Seung-H.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.19 no.5
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    • pp.340-346
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    • 1999
  • Minimum reflection and backward radiation methods on liquid/solid interrace were used to determine the velocity dispersion relation of acoustical surface wave for brass and aluminum substrates and copper/stainless steel nickel/brass, and nickel/aluminum layered substrates. Dispersion data agreed to dispersion characteristics of a generalized Lamb wave. The difference between velocities determined by two phenomena was closely related to the dispersion characteristics. This correspondence was explained by considering the generation mechanism of surface waves and the concept of group velocity.

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Dispersion and Flocculation Behavior of Metal Oxide in Organic Solvent

  • Fujii, Katsuya;Yamamoto, Hideki;Shibata, Junji
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.353-356
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    • 2001
  • The relation between the flocculation and dispersion of metal oxide powders and the properties of solvents, such as dielectric constant and solubility parameter, was investigated for TiO$_2$, $Al_2$O$_3$and Fe$_2$O$_3$particles. The particle size and median diameter of these metal oxides were measured in many organic solvents, from which the effect of solvents on the flocculation and dispersion of metal oxide powders was considered. The metal oxide powders of TiO$_2$, $Al_2$O$_3$and Fe$_2$O$_3$tend to disperse in a solvent of higher polarity, whereas they are apt to flocculate in a solvent of low dielectric constant, because the Hamaker constant between the particles becomes larger in such a solvent. There we, however, some solvents that do not obey these tendencies. It is possible to evaluate the flocculation and dispersion of these metal oxide powders in many solvents by using numeral balances of Hansen’s three-dimensional solubility parameter (f$_{d}$, f$_{p}$ and f$_{h}$). There exists a solvent giving the optimal dispersion for each metal oxide, and the optimal dispersion point of f$_{d}$, f$_{p}$ and f$_{h}$ is determined by the combination of various metal oxide powders and solvents.nts.nts.nts.

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