• Title/Summary/Keyword: dispersed mode

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Raman and Photoluminescence Study of Single-Walled Carbon Nanotubes Dispersed in Sodium Dodecyl Sulfate Aqueous Solution Using Ultrasonication (계면활성제를 이용한 단층 탄소나노튜브 분리에 따른 라만과 Photoluminescence 연구)

  • Park, June;Seong, Maeng-Je
    • Journal of the Korean Vacuum Society
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    • v.17 no.2
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    • pp.170-174
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    • 2008
  • We have studied, using Raman and photoluminescence (PL) spectroscopy, material property changes of single-walled carbon nanotubes (SWCNTs) dispersed in sodium dodecyl sulfate(SDS) aqueous solution by ultrasonication. Radial breathing mode Raman intensities of the dispersed SWCNTs shows different behavior depending on their chiralities as the sonication time increases. As the amount of SWCNTs dispersed in 1wt% SDS solution increases, both a downshift of the G-band Raman frequency and an enhancement in the PL intensity were observed.

Study on Morphological Properties of Dendrimer Using Multi-Mode SPM (다중 모드 SPM을 이용한 덴드리머의 모폴로지 특성에 대한 연구)

  • Jung, Kyung-Han;Shin, Hoon-Kyu;Kim, Chung-Kyun;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.192-195
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    • 2003
  • There has been increasing interest in the applications of synthesized molecules of nanometer scale in recent years due to their potential utilization in various fields such as biology, optoelectronics and molecular electronics. In this study, the terpyridine-platinum (II) complex on the periphery of the dendritic carbosilane has been prepared from the reaction of Pt(COD)Cl2 and the 4'-functionalized-(2,2':6',2"-terpyridine) on dendrimers. The self-assembly process was carried out to obtain indivially dispersed dendrimer on Au (111) substrate. It was found that STM was unsuitable to obtain a obvious image of dendrimers. Tapping-mode atomic force microscopy(AFM) has been used to investigate the shape and size of dendrimers individually dispersed on Au (111)substrate. As a result, the imaged single dendrimer show that dendrimer is dome shaped and its size can be measured by tapping-mode AFM.

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Monofunctional Monomer Effects of The Reflection Mode & Transmission Mode of Holographic Polymer Dispersed Liquid Crystals

  • Park, Min-Sang;Cho, Young-Hee;Kim, Byung-Kyu
    • KIEE International Transactions on Electrophysics and Applications
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    • v.11C no.3
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    • pp.75-80
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    • 2001
  • Holographic polymer dispersed liquid crystals (HPDLCs) have fabricated by irradiating an Ar-ion laser ( ${\lambda}$=514nm) at various intensity on LC/acrylate monomer mixtures which were sandwitched between two ITO coated glass plates. Monomer systems were composed of dipentaerythritol-hydroxy penta acrylate (DPHPA, f=5)/monofunctional acrylate monofunctional monomers. The LC used in this system was E7 (BL001, Merck). Gratings were fabricated by periodic interference of twobeams. Reflection efficiency-irradiation intensity-monomer type relationships were obtained from the UV-visible spectra of the HPDLC films. Peaks were found at a bit smaller wavelength than 514nm, due to the shrinkage of mixture volume upon polymerization. Real time measurements of diffraction efficiency have been obtained according to monomer types and LC contents.

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Study on the Electro-Optic Characteristics Depending on UV Condition in the Normally Scattering(NS)/Normally Transparent(NT) Polymer Dispersed Liquid Crystal Mode (Normally Scattering(NS)/Normally Transparent (NT) 고분자 분산형 액정 모드에서 UV 조건에 따른 전기 광학특성 연구)

  • Kim, M.S.;Seo, Y.H.;Lee, M.H.;Rhee, J.M.;Lee, T.S.;Lee, S.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.1050-1053
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    • 2003
  • Polymer dispersed liquid crystal mode can be classified into two cases, normally scattering mode (NS) and normally transparent (NT) mode according to an initial state. Electro-optic characteristic NS/NT PDLC mode can be improved by controlling the factors to influence the phase separation. In case of NS PDLC mode, we inspected change of a phase separation as a function of curing temperature for the mixture of E7 and NOA65 with different ratios. When the LC concentration is less than polymer such as LC : NOA65 = 40 : 60wt%, the PDLC cell is influenced strongly by the curing temperature. However, when LC concentration is much less than polymer such as LC : NOA65 : 80 : 20wt%, it is influenced slightly by the curing temperature. In case of NT PDLC mode, we observed change of a phase separation as a function of the ratio of the mixture and UV conditions such as curing temperature, UV intensity The cell made with strong UV intensity and curing temperature of $20^{\circ}C$, in case that the ratio of LC to polymer is 70:30wt%, showed good electro-optic characteristics.

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Placement and Operation of Dispersed Generation Systems using Fuzzy Goal Programming (Fuzzy Goal Programming을 응용한 분산형전원의 설치 및 운영)

  • 송현선;김규호
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.18 no.1
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    • pp.146-153
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    • 2004
  • This paper presents the method for the placement and operation of dispersed generator systems(DGs) using fuzzy goal programming in distribution systems. For the placement and operation of DGs the problem is formulated with reduction of search spaces and flexibility of system situations. Especially, the original objective function and constraints are transformed by fuzzy goal programming to evaluate their imprecise nature for the criterion of power loss minimization, the number or total capacity of DGs and the bus voltage deviation, and then solve the problem using genetic algorithm.

Carbon Nano Tube Dispersion Evaluation in B-stage Resin Films (B-stage 레진 필름의 카본나노튜브 분산도 평가 및 제조공정 최적화)

  • Oh, Young-Seok;Park, Tea-Hoon;Byun, Joon-Hyung;Yi, Jin-Woo;Kim, Byung-Sun;Joe, Chee-Ryong
    • Composites Research
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    • v.29 no.6
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    • pp.353-357
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    • 2016
  • An appropriate way to fabricate a hybrid composite containing evenly dispersed carbon nano tubes(CNTs) is to stacking B-stage resin films that contain evenly dispersed CNTs and various reinforcing fiber layers alternatively. In the present study, B-stage resin films are manufactured via shear mixing and three-roll milling. CNT dispersion in resin via these two processes are evaluated by SEM on their fracture surfaces. For more efficient process, the dispersivities are evaluated according to the number of calendering passes. Samples are made for different number of passes during calendering, and their dispersions are evaluated via SEM fractographs as well as by measuring their electrical conductivities. Additionally, the optimal process conditions are obtained by measuring the electrical conductivity and evaluating their dispersivity of the samples prepared by gap mode and force mode.

Microstructure of alumina-dispersed Ce-TZP ceramics (알루미나가 분산된 세리아 안정화 지르코니아 세라믹스의 미세구조)

  • 김민정;이종국
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.2
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    • pp.122-127
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    • 2000
  • Microstructural evolutions in ceria-stabilized zirconia (Ce-TZP) and alumina-dispersed Ce-TZP ceramics were investigated as functions of doping and annealing conditions. All of sintered specimens showed the relative density over 99 %. Sintered specimens had linear grain boundaries and normal grain shapes, but ceria-doped specimens had irregular grain shapes and nonlinear grain boundaries due to the diffusion-induced grain boundary migration during annealing at $1650^{\circ}C$ for 2 h. Mean grain boundary length of Ce-TZP with irregular grain shapes was higher than that of normal grain shapes, and was a value of 23pm at the maximum. Alumina particles dispersed in Ce-TZP inhibited the grain growth of zirconia particles. $Al_2O_3$Ce-TZP doped with ceria and annealed at $1650^{\circ}C$ for 2 h showed irregular grain shapes as well as small grain size. Added alumina particles showed the grain growth during sintering or annealing, and they changed the position from grain boundary to inside of the grains during the annealing. The specimens with normal grain shapes showed an intergranular fracture mode, whereas the specimens with irregular grain shapes showed a transgranular fracture mode during the crack propagation.

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Comparison of carbon nanotube growth mode on various substrate

  • I.K. Song;Y.S. Cho;Park, K.S.;Kim, D.J.
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.44-44
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    • 2003
  • Growth mechanism of carbon nanotubes(CNTs) synthesized by chemical vapor deposition is abided by two growth modes. These growth modes are classified by the position of activated catalytic metal particle in the CNTs. Growth mode can be also affected by interaction between substrate and catalytic metal and induced energy such as thermal and plasma. We studied the reaction of catalytic metal to the substrate and growth mode of CNTs. Various substrates such as Si(100), graphite plate, coming glass, sapphire and AAO membrane are used to study the relation between catalytic metal and substrate in the synthesis of CNTs. For catalytic metal, thin film was deposited on various substrate via sputtering technique with a thickness of ∼20nm and magnetic fluids with none-sized particles were dispersed on AAO membrane. After laying process on AAO membrane, it was dried at 80$^{\circ}C$ for 8 hour. Synthesizing of CNTs was carried out at 900$^{\circ}C$ in NH3/C2H2 mixture gases flow for 10minutes.

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Recent Trends on Wide-Viewing-Angle LC Modes and New Trials on CNT-LC System

  • Lee, Seung-Hee;Lee, Young-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.101-104
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    • 2005
  • Recently, competition between LC modes for LC TVs becomes high. In this paper, status of each mode is briefly reviewed with commenting on its electro-optic characteristics and possible application fields. Further, to understand effects of carbon nanotubes (CNTs) dispersed in nematic liquid crystal on electro-optic characteristic and orientation of the LC, CNT-doped NLC cells are made and evaluated. The hysterisis studies of voltage-dependent capacitance show that the amount of residual dc is greatly reduced due to ion trapping by CNTS.

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Heavy ion effects on mode conversion between electron and proton whistlers : A simulation study

  • 김은화;이동훈
    • Bulletin of the Korean Space Science Society
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    • 2003.10a
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    • pp.37-37
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    • 2003
  • Electron whistlers frequently excite proton whistlers. The proton whistlers appear on the dynamic spectrum as rising tones, which start after the reception of a short electron whistler, asymptotically approaching the local proton gyro-frequency. The proton whistlers are dispersed forms of lightning impulses and their dispersion can be explained by the effects of heavy ions such as H+ and He+ on the propagation of an electromagnetic wave in the ionosphere. In the ionosphere, a right-handed circularly-polarized electron whistler becomes coupled to a left-handed circularly-polarized proton whistler when the frequency becomes close to a cross-over frequency. By adopting the multi-fluid numerical wave model, we examine how the mode coupling varies as the ion composition changes along altitude in the mid-latitude ionosphere. The time histories and dynamic spectra of electric fields are presented. In addition, we compare our results with the previous theoretical and observational studies.

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