• Title/Summary/Keyword: dispersed matrix

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The Thermal Shock Behaviors of Y-TZP/Y-TZP-Al2O3 Composites having Dual Microstructure (이중조직을 갖는 Y-TZP/Y-TZP-$Al_2O_3$ 복합체의 열충격 거동)

  • Hwang, K.H.;Kim, E.H.;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.29 no.4
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    • pp.283-292
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    • 1992
  • Duplex composites such as Y-TZP/Y-TZP-20 wt.% Al2O3 and Y-TZP/Y-TZP- 40 wt.% Al2O3 were made by mixing the sieve-shaked granules followed by isostatic pressing and sintering at 150$0^{\circ}C$ for 1 hour. So Y-TZP became matrix region and Y-TZP-20 wt.% Al2O3 or Y-TZP-40 wt.% Al2O3 became dispersed regions. In these composites, propagating cracks due to thermal shock always run into the dispersed region because these regions act as compressive zone due to low thermal expansion than matrix region. So duplexes having dispersed regions of Y-TZP-40 wt.% Al2O3 showed higher retained strength after thermal shock than matrix only composites because crack propagations were stopped more or less in the dispersed region. But when crack propagations were much more easy than matrix like Y-TZP-20 wt.% Al2O3 region, retained strength was decreased than the matrix only composites despite of the low initial strength.

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Effect of Fe Magnetic Nanoparticles in Rubber Matrix

  • Uhm, Young-Rang;Kim, Jae-Woo;Jun, Ji-Heon;Lee, Sol;Rhee, Chang-Kyu;Kim, Chul-Sung
    • Journal of Magnetics
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    • v.15 no.4
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    • pp.173-178
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    • 2010
  • A new kind of magnetic rubber, Fe dispersed ethylene propylene monomer (EPM), was prepared by a conventional technique using a two roll mill. The magnetic fillers of Fe-nanoparicles were coated by low density polyethylene (LDPE). The purpose of surface treatment of nanoparticles by LDPE is to enhance wettability and lubricancy of the fillers in a polymer matrix. The mechanical strength and microstructure of the magnetic rubber were characterized by tensile strength test and scanning electron microscopy (SEM). Results revealed that the Fe nanoparticles were relatively well dispersed in an EPM matrix. It was found that the nano- Fe dispersed magnetic rubber showed higher coercivity and tensile strength than those of micron- Fe dispersed one.

Composite Structures of $SiC_p$/6063 Aluminum Alloy by Rheo-Compocasting. (Rheo-Compocasting에 의한 $SiC_p$/6063 Al합금의 복합조직)

  • Choe, Jeong-Cheol
    • Journal of Korea Foundry Society
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    • v.10 no.4
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    • pp.309-315
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    • 1990
  • Aluminum alloy matrix composites reinforced by SiC particles were prepared by rheocompocasting, a process which consists of the incoporation and distribution of reinforcement by stirring within a semi-solid alloy. When the volume fraction of SiCp and stirring speed were fixed, the dispersion of SiCp in Al-matrix alloy depended on stirring time and solid volume fraction in slurry. The results were as follows : 1) As a dispersed SiCp during stirring at $647^{\circ}C$ in 6063-Al alloy, SiC was better dispersed than that other temperature, where solid volume fraction was 43% in slurry. 2) When increased solid fraction in slurry, rate of dispersing SiC increased during stirring and porosities decreased in matrix alloy after casting. 3) Inspite of stirring with 800rpm, since solid particles of matrix alloy in slurry joined each other and occured joining growth, so that SiC was not dispersed into solid particle.

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Copper Oxide-Modified Polymeric Composite Elecrodes for Amperometric Detection of Carbohydrates in LCEC Analysis

  • 정혜경;박종만
    • Bulletin of the Korean Chemical Society
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    • v.18 no.9
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    • pp.952-957
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    • 1997
  • Modified polymeric composite electrodes having highly dispersed CuO particles through the electrode matrix were prepared for LCEC or flow injection analysis of carbohydrates. The composite electrodes were prepared by incorporating carbon black and highly dispersed copper oxide particles in polystyrene matrix cross-linked with divinylbenzene. The analytical characteristics of the electrodes for LCEC and flow injection analysis of carbohydrates were evaluated. Improved performance in LCEC and flow injection analysis of carbohydrates is demonstrated in terms of sensitivity, reproducibility, stability and surface renewability. It was possible to get improved performance of the electrodes as well as adaptability of the electrodes for practical applications by employing highly dispersed catalyst particles through the electrode matrix and robust polymeric electrode matrix.

A Model for Diffusion and Dissolution Controlled Drug Release from Dispersed Polymeric Matrix (고분자 분산 매트릭스로부터의 약물방출에 관한 확산 및 용출 제어 모델)

  • Byun, Young-Rho;Choi, Young-Kweon;Jeong, Seo-Young;Kim, Young-Ha
    • Journal of Pharmaceutical Investigation
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    • v.20 no.2
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    • pp.79-88
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    • 1990
  • A numerical model for diffusion and dissolution controlled transport from dispersed matrix is presented. The rate controlling process for transport is considered to be diffusion of drug through a concentration gradient coupled with time-dependent surface change and/or disappearance of the dispersed drug in response to the dissolution. The transport behavior of drug was explained in terms of ${\nu}$ parameter: ${\nu}$ value means a ratio of diffusion time constant and dissolution time constant. This general model has wide range of application from where release is controlled by the diffusion rate to where release is governed by the dissolution rate. Based on this model, theoretical drug concentration, particle size distributions in the polymer matrix system and the resulting release rate were also investigated.

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Evaluation of Elastic Modulus in a Particulate Reinforced Composite by Shape Memory Effect (형상기억입자 강화 복합체의 탄성계수 평가)

  • Kim, Hong-Geon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.1
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    • pp.25-31
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    • 2001
  • The theoretical modeling to predict the modulus of elasticity by the shape memory effect of dispersed particles in a metal matrix composite was studied. The modeling approach is based on the Eshelbys equivalent inclusion method and Mori-Tanakas mean field theory. The calculation was performed on the TiNi particle dispersed Al metal matrix composites(PDMMC) with varying volume fractions and prestrains of the particle. It was found that the prestrain has no effect on the Yonugs modulus of PDMMC but the volume fraction does affects it. This approach has an advantage of definite control of Youngs modulus in PDMMCs.

Synthesis and Thermoelectric Properties of Carbon Nanotube-Dispersed Bi2Te3 Matrix Composite Powders by Chemical Routes

  • Kim, Kyung Tae;Son, Injoon;Ha, Gook Hyun
    • Journal of Powder Materials
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    • v.20 no.5
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    • pp.345-349
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    • 2013
  • Carbon nanotube-dispersed bismuth telluride matrix (CNT/$Bi_2Te_3$) nanopowders were synthesized by chemical routes followed by a ball-milling process. The microstructures of the synthesized CNT/$Bi_2Te_3$ nanopowders showed the characteristic microstructure of CNTs dispersed among disc-shaped $Bi_2Te_3$ nanopowders with as an average size of 500 nm in-plane and a few tens of nm in thickness. The prepared nanopowders were sintered into composites with a homogeneous dispersion of CNTs in a $Bi_2Te_3$ matrix. The dimensionless figure-of-merit of the composite showed an enhanced value compared to that of pure $Bi_2Te_3$ at the room temperature due to the reduced thermal conductivity and increased electrical conductivity with the addition of CNTs.

Effects of the Interaction between Intercalant and Matrix Polymer in Preparation of Clay-dispersed Nanocomposite

  • Ko, Moon-Bae;Kim, Jyunkyung;Choe, Chul-Rim
    • Macromolecular Research
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    • v.8 no.3
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    • pp.120-124
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    • 2000
  • Clay-dispersed nanocomposites have been prepared by simple melt-mixing of two components, styrenic polymers with different content of functional groups and two different organophilic clays (Cloisite(R) 25A and Cloisite(R)30A) with a twin screw extruder. Dispersibility of 10-$\AA$-thick silicate layers of clay in the hybrid was investigated by using an X-ray diffraction method and a transmission electron microscope. It was found that if the interaction force between intercalant and matrix polymer is attractive, the matrix polymer intercalates more rapidly into the gallery of silicate layers. The faster intercalation of matrix polymer leads to the better dispersibility of silicate layers in the matrix polymer.

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Fabrication of Aluminum Matrix Composite Reinforced with Al0.5CoCrCuFeNi High-Entropy Alloy Particles

  • Min Sang Kim;Han Sol Son;Gyeong Seok Joo;Young Do Kim;Hyun Joo Choi;Se Hoon Kim
    • Archives of Metallurgy and Materials
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    • v.67 no.4
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    • pp.1543-1546
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    • 2022
  • The aluminum composite with dispersed high entropy alloy were developed by stir casting involving the powder-in-tube method. First, Al0.5CoCrCuFeNi high entropy alloy (HEA) powder was made by mechanical alloying, and the powder was extruded in a tube-type aluminum container to form HEA precursor. The extruded HEA precursor was then dispersed in the aluminum matrix via stir casting. As a result, Fe-Cr-Ni based high-entropy phases was uniformly formed in the aluminum matrix, revealing ~158, 166, 235% enhancement of tensile strength by incorporating 1, 3, and 5 wt% HEA particles, respectively.

The Fatigue Behavior of Mechanically Alloyed Al-4Mg Alloys Dispersed with Oxide Particles (기계적합금화된 분산형 Al-4Mg기 합금의 피로거동)

  • Pyun, J.W.;Cho, J.S.;Kwun, S.I.;Jo, Y.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.6 no.4
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    • pp.237-242
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    • 1993
  • The fatigue behaviors of mechanically alloyed Al-4Mg alloys dispersed with either $Al_2O_3$ or $MgAl_2O_4$ oxide particles were investigated. This study maily concerned with the role of coherency of dispersed particles with the matrix on the fatigue behavior of the alloys. The $MgAl_2O_4$ which has a spinel structure with the lattice parameter of exactly the twice of Al showed the habit relation with the matrix. The mechanically alloyed Al-4Mg alloys showed stable stress responses with fatigue cycles from start to failure regadless of strain amplitudes and of existence of dispersoids. The Al-4Mg alloy dispersed with $MgAl_2O_4$ showed not only the better static mechanical properties but also the better low cycle fatigue resistance than that with $Al_2O_3$, i.e., much higher plastic strain energy dissipated to failure, at low strain amplitude. However, this alloy showed inferior fatigue resistance to that dispersed with $Al_2O_3$ or that without dispersion at high strain amplitude. These results imply that $MgAl_2O_4$ may promote lowering the stacking fault energy of the alloy inherited from the coherency with the matrix so that dislocations shuttle back and forth on the same slip plane without cross slipping to other planes during fatigue at low strain amplitude resulting in long fatigue life.

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