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Synthesis and Thermoelectric Properties of Carbon Nanotube-Dispersed Bi2Te3 Matrix Composite Powders by Chemical Routes

  • Kim, Kyung Tae (Powder & Ceramic Materials Division, Korea Institute of Materials Science) ;
  • Son, Injoon (School of Materials Science and Engineering, Kyungpook National University) ;
  • Ha, Gook Hyun (Powder & Ceramic Materials Division, Korea Institute of Materials Science)
  • Received : 2013.10.01
  • Accepted : 2013.10.24
  • Published : 2013.10.28

Abstract

Carbon nanotube-dispersed bismuth telluride matrix (CNT/$Bi_2Te_3$) nanopowders were synthesized by chemical routes followed by a ball-milling process. The microstructures of the synthesized CNT/$Bi_2Te_3$ nanopowders showed the characteristic microstructure of CNTs dispersed among disc-shaped $Bi_2Te_3$ nanopowders with as an average size of 500 nm in-plane and a few tens of nm in thickness. The prepared nanopowders were sintered into composites with a homogeneous dispersion of CNTs in a $Bi_2Te_3$ matrix. The dimensionless figure-of-merit of the composite showed an enhanced value compared to that of pure $Bi_2Te_3$ at the room temperature due to the reduced thermal conductivity and increased electrical conductivity with the addition of CNTs.

Keywords

References

  1. F. J. Disalro: Science, 287 (2000) 1024. https://doi.org/10.1126/science.287.5455.1024
  2. R. J. Mehta, Y. Zhang, C. Karthik, B. Singh, R. W. Siegel, T. Borca-Tascuic and G. Ramanath: Nature Mater. 11 (2012) 233. https://doi.org/10.1038/nmat3213
  3. X. B. Zhao, X. H. Ji, Y. H. Zhang, T. J. Zhu, J. P. Tu and X. B. Zhang: Appl. Phys. Lett., 86 (2005) 062111. https://doi.org/10.1063/1.1863440
  4. Y. Q. Cao, X. B. Zhao, T. J. Zhu, X. B. Zhang and J. P. Tu: Appl. Phys. Lett., 92 (2008) 143106. https://doi.org/10.1063/1.2900960
  5. W. Xie, X. Tang, Y. Yan, Q. Zhang and T. M. Tritt: Appl. Phys. Lett., 94 (2009) 102111. https://doi.org/10.1063/1.3097026
  6. X. A. Fan, J. Y. Yang, R. G. Chen, W. Zhu and S. Q. Bao: Mat. Sci. Eng. A 438-440 (2006) 190. https://doi.org/10.1016/j.msea.2005.12.055
  7. B. Poudel et al,: Science, 320 (2008) 634. https://doi.org/10.1126/science.1156446
  8. L. Zhao, B. Zhang, J. Li, M. Zhou, W. Liu and J. Liu: J. Alloys Comp., 455 (2008) 259. https://doi.org/10.1016/j.jallcom.2007.01.015
  9. G. Zhan, J. D. Kuntz, A. K. Murkherjee, P. Zhu and K. Koumoto: Scripta Mater., 54 (2006) 77. https://doi.org/10.1016/j.scriptamat.2005.09.003
  10. Y. Zhang, X. L. Wang, W. K. Yeoh, R. K. Zeng and C. Zhang: Appl. Phys. Lett., 101 (2012) 031909. https://doi.org/10.1063/1.4737898
  11. K. T. Kim, S. Y. Choi, E. H. Shin, K. S. Moon, H. Y. Koo, G. Lee and G. H. Ha: Carbon., 52 (2013) 541. https://doi.org/10.1016/j.carbon.2012.10.008
  12. K. T. Kim, D. Kim and G. H. Ha: Res. Chem. Inter., 36 (2010) 835. https://doi.org/10.1007/s11164-010-0188-4
  13. K. T. Kim, H. M. Lee, D. W. Kim, K. J. Kim and G. H. Ha: J Kor Phys Soc., 57 (2010) 1037. https://doi.org/10.3938/jkps.57.1037
  14. J. Jiang, L. Chen, S. Bai, Q. Yao and Q. Wang: Scripta Mater., 52 (2005) 347. https://doi.org/10.1016/j.scriptamat.2004.10.038
  15. K. T. Kim, H. Y. Koo, G. Lee, G. H. Ha: Mater. Lett., 82 (2012) 141. https://doi.org/10.1016/j.matlet.2012.05.053
  16. M. Scheele, N. Oeschler, K. Meier, A. Kornowski, C. Klinke and H. Weller: Adv. Func. Mater., 19 (2009) 3476. https://doi.org/10.1002/adfm.200901261

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