• Title/Summary/Keyword: disperse blue

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Optimization of Anthraquinone Dyes Decolorization Conditions with Response Surface Methodology by Aspergillus

  • Ge, Yufeng;Wei, Bin;Wang, Siyu;Guo, Zhiguo;Xu, Xiaolin
    • Korean Chemical Engineering Research
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    • v.53 no.3
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    • pp.327-332
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    • 2015
  • A large amount of dye wastewater poses a threat to environmental safety. Disperse blue, an anthraquinone dye that is widely used in textile dyes, is difficult to degrade in wastewater. In this work, one fungus was screened according to the decolorization rate of disperse blue. The fungus was identified and named Aspergillus XJ-2 on the basis of its morphological characteristics and 18s rDNA. Response surface method was used to optimize culture conditions for A. XJ-2. The optimum values of obtained responses were as follows: temperature, $35^{\circ}C$; pH, 5.2; carbon-to-nitrogen ratio, 30:5.5; and rotation ratio, $175r{\cdot}min^{-1}$. Under optimized conditions, the decolorization rate of A. XJ-2 was up to 94.8% in 48 h.

Influence of Temperature and Affinity of Disperse Dye on Dyeing of PET(Polyethylene Terephthalate) Microfiber (PET 초극세사 염색에서 분산염료의 친화력과 온도 의존성)

  • Lee, Hun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.9
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    • pp.532-540
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    • 2019
  • PET microfibers with various diameters (0.5, 0.2, 0.06, and 0.01 dpf) were dyed with a dispersed dye (C.I. Disperse Blue 56) at various temperatures. The dyeing process was conducted under infinite dyebath conditions at constant temperatures. The effects of the dyeing temperature and diameter on the partition coefficient, affinity, and diffusion coefficient of disperse dyes were studied. The curve of isotherms was fitted well to Nernst-type model in a large range of initial dye concentrations. At the same temperature, the partition coefficient and affinity decreased with increasing sample diameter due to the increase in surface area. At all deniers, the partition coefficient and affinity decreased with increasing temperature because the dyeing process is an exothermic reaction. In addition, the decrease in radius of the sample gives rise to a decrease in the heat of dyeing. The fine diameter of the sample resulted in an increased surface area but decreased space between the microfibers. Consequently, decreasing the diameter of the microfibers leads to a decrease in the diffusion coefficient. At the same diameter, the diffusion coefficient increased with increasing temperature because of rapid dye movement and the large free volume of the sample inside. In addition, thermal dependence of the diffusion coefficient increased when the diameter of the sample increased.

A Study on the Dyeing of Polyester Fiber in Alkaline Dyebath ―Dyeing Properties of Disperse dyes According to variation of pH values― (폴리에스테르섬유의 알칼리욕염색에 관한 연구 -pH변화에 따른 분산염료의 염색성을 중심으로-)

  • Sung, Woo Kyung;Ryu, Ki Hyo;Park, Soo Min;Kim, Kyung Hwan
    • Textile Coloration and Finishing
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    • v.8 no.1
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    • pp.34-42
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    • 1996
  • This Study was made to investigate alkaline dyeing systems for a new dyeing applicable polyester fibers. Disperse dyes for dyeing of polyester fibers were C.I. Red 60, Blue 56 and Yellow 54 as three primary colors of E type which used widely on the scene. Dyeing properties of dispers dyes on the polyester fibers are discussed according to variation of pH values for application of alkaline dyeing method compared with to ordinary acidic dyebath. Alkaline pH of the dyebath was controlled to pH 9 and 10.5 with buffer solutions using each hydrochloride and disodiumtetraborate, disodiumtetraborate and sodium hydroxide to promote the reproducibility of dyeing. Dyeing properties of dispers dyes on the polyester fibers by alkaline dyeing method compared with to ordinary acidic dyebath were discussed by estimation of color, wash-fastness, bleeding and migration of dyed polyester fabric.

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Dyeability of Low-melting Hybrid Polyester at Low Temperature (저융점 폴리에스테르 복합사의 저온 염색성)

  • Hwang, Ji-Hyun;Kim, Chang-Nam;Ma, Jin-Suk;Oh, Hae-Sun;Yoon, Nam-Sik
    • Textile Coloration and Finishing
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    • v.24 no.2
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    • pp.113-120
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    • 2012
  • Jacquard floor covering could be prepared from low-melting/regular sheath-core hybrid polyester, where the fiber is dyed in yarn state. With regard that the expected high shrinkage of the hybrid polyester in water makes problems in yarn dyeing, low-temperature dyeing properties of the hybrid polyester were studied. The rate of shrinkage of low-melting hybrid polyester exceeds 9% in hot water above $90^{\circ}C$, at such condition, cheese yarn dyeing is very difficult. Although disperse dyes exhaust in a relatively high speed on low-melting hybrid polyester, diffusion of these dyes to the core regular polyester was extremely slow under $90^{\circ}C$. Foron Blue E-BL 150, an anthraquinone E-type disperse dye, showed appreciable diffusion after 48hrs dyeing at $90^{\circ}C$. The fastness to rubbing and drycleaning were improved by one grade after reduction cleaning.

Reduction Cleaning and Thermomigration Effects on Micro Polyester SUEDE (극세 폴리에스테르 스웨드의 환원세정과 열이행의 영향)

  • Choi, Kyung-Yeon;Han, Sam-Sook;Lee, Mun-Cheul
    • Textile Coloration and Finishing
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    • v.21 no.6
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    • pp.12-21
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    • 2009
  • The dyeing property of direct-spinning type and seaisland type 0.2D micro polyester nonwoven fabrics was characterized by three disperse dyes (Dorosperse Red KFFB, Blue KGBR, Yellow KRL) at $120^{\circ}C$ and $130^{\circ}C$. Before and after reduction cleaning, dyeing fastness was evaluated and the thermomigaration after heat setting at $180^{\circ}C$ for 60 min were also evaluated. Direct-spinning type fabric showed better dyeing property, wash fastness, and light fastness, but worse rub fastness than seaisland type fabric. The dyeing property and fastness of direct-spinning type fabric increased at higher dyeing temperature, whereas seaisland type fabric exhibited lower dyeing fastness and the increase of thermomigration at higher dyeing temperature. Non-fixed dye in fiber surface was removed by reduction cleaning process, then dyeing fastness was improved and thermomigration decreased. The higher dye uptake of direct-spinning type non-woven fabric caused the increase of dye molecule migration from fiber internal to fiber surface, so this fabric showed larger thermomigration than seaisland type non-woven fabric.

A Study on photoisomerization of cellulose acetate containing disperse red 1 (Disperse red 1을 함유하고 있는 셀룰로오스 아세테이트의 광이성화에 관한 연구)

  • Lee, Soo;Park, Keun-Ho;Jung, Dong-Soon
    • Journal of the Korean Applied Science and Technology
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    • v.16 no.4
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    • pp.273-279
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    • 1999
  • In order to study a reversible photoisomerization of disperse red l(DR 1) attached on natural polymers, cellulose acetate containing DR l(DR 1/CA adduct) was prepared, and the changes of UV/VIS spectra of its solution(benzene, DMAc). thick film, and LB film were investigated by alternate irradiation with two different wave length lights. DR 1/CA adduct was prepared through tosylation of partially hydrolyzed cellulose acetate followed by reaction with DR 1 at $100^{\circ}C$ in pyridine. From the UV/VIS spectra of DR 1/CA adduct dissolved in DMAc solvent including phosphoglyceride before and after irradiation at 360nm and 45Onm, we found out the changes of UV/VIS spectra were reversible. In addition, the change of UV/VIS spectra of this adduct solution was strongly depended on the sorts of solvents and temperature. As the temperature was increased, UV/VIS spectra of this adduct solution in DMF showed blue shift. These results provided this solution could be applied to a temperature sensor. In the thick film case, we also obtained similar results with solution case. LB monolayer and trilayer from DR 1/CA adduct was obtained by scattering the solution including phosphoglyceride on water surface at the surface pressure of 8mN/m. After irradiation on that LB monolayer and trilayer, the reversible photoisomerization was also detected. From these results we concluded DR 1/CA adduct was suitable for the application to data storage and optical switch, etc.

Colloidal Textile Dye-Based Dipstick Immunoassay for the Detection of Infectious Flacherie of Silkworm, Bombyx mori L.

  • Sivaprasad, V.;Nataraju, B.;Renu, S.;Datta, R.K.
    • International Journal of Industrial Entomology and Biomaterials
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    • v.6 no.1
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    • pp.27-31
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    • 2003
  • Infectious flacherie of silkworm Bombyx mori is caused by B. mori infectious flacherie virus (BmIFV) and causes severe crop loss to sericulturists. In the present study, a colloidal textile dye-based dipstick immunoassay is developed for the detection of infectious flacherie in silkworms. Colloidal textile dye (blue D2R) with Aλ$_{max}$ at 620 nm was sensitised with 500 $\mu\textrm{g}$/ml of purified anti-BmIFV IgG. The dye-antibody reagent detects purified antigen up to 10 ng/ml and BmIFV infection in diseased larval extracts $(up to a dilution of {10^-5})$ and faecal matter extracts $(up to a dilution of {10^-2})$ by forming clear blue dot within 30 min. It was observed to be stable for three months period at $4^{\circ}C$. The efficacy of textile dye-based dipstick immunoassay was on pay with HRP-based dipstick immunoassay and fluorescent antibody test, and better than latex agglutination and ouchterlony tests in the detection of BmIFV The dye-based dipstick immunoassay method provides a simple, sensitive and less expensive test for the detection of BmIFV infection in silkworms.s.

Dyeing of Flame Retardant Polyester Fabric developed by using Low-melting-point Bicomponent Filament (저융점 복합사를 이용한 난연 폴리에스터 직물의 염색)

  • Lee, Shin-Hee
    • Fashion & Textile Research Journal
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    • v.15 no.3
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    • pp.467-476
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    • 2013
  • This study investigates the dyeability and the fastness of flame retardant polyester fabric developed by a thermal bonding with a low melting component of flame retardant bicomponent filament (LMFRPC). The fabrics were prepared with flame retardant polyester filaments (FRP) as warp and blended filaments of FRP and LMFRPC as weft. The LMFRPC have a sheath and a core where the core comprises a flame retardant polyester and the sheath comprises a thermoplastic polyester with a low-melting point. The thermal bonding of fabric was conducted in a pin tenter at $170^{\circ}C$ for 60 seconds. Fabric dyeing was conducted with an infrared dyeing machine at various dyeing temperatures and dyeing times. The dyestuffs used in this study were CI disperse Yellow 54, Red 60 and Blue 56 of E-type dyestuff and Orange 30, Red 167 and Blue 79 of S-type dyestuff. This study investigated the morphology of thermal bonded fabric, dyeability and fastness of dyed fabric. Dyeability increased with an increased dyeing temperature. The thermal bonded area increased with the increased LMFRPC content. The dyeability of S-type dyestuff was higher than E-type dyestuff; in addition, the saturated dyeing time was about 20minutes at $130^{\circ}C$ for E and S-type dyestuff. The fastness to washing and rubbing were excellent at a 4-5 Grade.

One-bath Dyeing of Blend fabric with Reactive Disperse Dyes (반응성 분산염료를 이용한 혼방섬유의 일욕염색)

  • 김지수;이정진;윤양수;김재필
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.225-226
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    • 2003
  • 일시적 수용성 반응성 분산염료는 염료합성시에 분산제를 사용하지 않기 때문에 원가절감 및 밀링공정 생략에 의한 생산성 증대효과가 있다[1-2l. 또한 혼방섬유를 단일염료로 일욕에서 염색할 수 있기 때문에 공정단축의 효과, 염색공정시에도 분산제를 사용하지 않아도 되므로 조제절감 및 염색폐수의 환경문제 개선 둥의 장점이 있다. 3원색(yellow, red, blue)의 일시적 수용성 반응성 분산염료를 이용하여, Acetate/Nylon(A/N), Acetate/polyester(A/P), Polyester/Nylon(P/N) 혼방섬유를 일욕에서 염색하였으며, 염색성, 견뢰도 및 염색폐수의 환경성을 평가하였다. (중략)

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An Evaluation of Application Possibility of Window System in the Building based on Optical Characteristics Analysis of DSSC (염료감응태양전지의 광학특성분석을 통한 건축창호 적용가능성 평가 연구)

  • Sim, Se-Ra;Yoon, Jong-Ho;Jeong, Seon-Yeong;Baek, Nam-Choon
    • Journal of the Korean Solar Energy Society
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    • v.31 no.3
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    • pp.109-115
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    • 2011
  • It can gain both the electric energy production and disperse of light at the same time if DSSC is applied in the building as window system. It means to help facade design and to be used in lighting, heating, cooling energy directly by applicating DSSC BIPV window that is possible to daylighting and materialization of color. For this, optical characteristics analysis that is basic step must take precedence. So, basic databases of DSSC are builded and optical performances according to the double and triple glazing are evaluated by analyzing spectral data of various colored DSSC. As a result, Green(4) has the highest visible transmittance that is 28.8%, and Blue(3) has the lowest that is 0.3%. And, in case of optical performance of Green(4) depending on the incidence angle, SHGC and Tsol are decreased sharply from more than $60^{\circ}C$. Finally, It is judged that Red(4), Green(1), (4), Blue(4) are suitable for application in office building because visible transmittance is high and solar heat gain coefficient is low relatively in spite of composing to double and triple glazing.