• 제목/요약/키워드: direct synthesis

검색결과 592건 처리시간 0.026초

지식 표현 기법을 이용한 모델 구조의 표현과 구성 : 단편구조 유연생산 시스템 예 (Model Structuring Technique by A Knowledge Representation Scheme: A FMS Fractal Architecture Example)

  • 조대호
    • 한국시뮬레이션학회논문지
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    • 제4권1호
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    • pp.1-11
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    • 1995
  • The model of a FMS (Flexible Manufacturing System) admits to a natural hierarchical decomposition of highly decoupled units with similar structure and control. The FMS fractal architecture model represents a hierarchical structure built from elements of a single basic design. A SES (System Entity Structure) is a structural knowledge representation scheme that contains knowledge of decomposition, taxonomy, and coupling relationships of a system necessary to direct model synthesis. A substructure of a SES is extracted for use as the skeleton for a model. This substructure is called pruned SES and the extraction operation of a pruned SES from a SES is called pruning (or pruning operation). This paper presents a pruning operation called recursive pruning. It is applied to SES for generating a model structure whose sub-structure contains copies if itself as in FMS fractal architecture. Another pruning operation called delay pruning is also presented. Combined with recursive pruning the delay pruningis a useful tool for representing and constructing complex systems.

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Development of fluorination methodology for carbon-fluorine bond formation: old electrophilic fluorinating reagents

  • Bae, Dae Young;Lee, Eunsung
    • 대한방사성의약품학회지
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    • 제4권1호
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    • pp.11-15
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    • 2018
  • Electrophilic fluorinating reagents are typically efficient for carbon-fluorine (C-F) bonds formation due to their higher reactivity even under mild condition. Thus, they have been playing an important role to improve C-F bonds formation reactions via direct fluorination reaction with electrophilic fluorinating reagents or transition metal catalysis. Advances on the recent fluorination methods are mainly results of $Selectfluor^{TM}$'s capability on facile fluorination. In this mini-review, we describe synthesis and application of four old yet popular electrophilic fluorinating reagents such as N-fluorobenzenesulfonimide (NFSI), N-fluoropyridinium salts, $Selectfluor^{TM}$, and N-fluorosultam.

Living cationic polymerization of Viny Ethers in Presence of Iodomethyl Methyl Ether and Zinc Iodide

  • Kwon, Soonhong;Lee, Yunsung;Mah, Soukil
    • Fibers and Polymers
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    • 제2권1호
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    • pp.131-134
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    • 2001
  • Living cationic polymerization behaviors of isobutyl vinyl ehters (IBVE), initiated by iodomethyl methyl ether (IMME)/zinc iodide ($Znl_2$) have been investigated. The polymerization was carried out at 0, -15, and $-30^{\circ}C$ in toluene. It was found that the rate of polymerization increased as the IMME concentration increased and decreased as temperature decreased. 100% conversion was always achieved without exception. Furthermore, the number-average molecular weight ($M_{n}$) of polymers increased in direct proportion to monomer conversion. The molecular weights of polymers were in good agreement with the theoretical values, calculated on the basis that one polymer chain was formed by one IMME molecule and the values of polydispersity index are always less than 1.2, revealing the living nature. The living nature was also confirmed by synthesis of poly(IBVE-b-TBVE) by subsequent monomer addition of t-butyl vinyl ether (TBVE).

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Asymmetric Total Synthesis of the Glycosidase Inhibitor, 1,4-dideoxy-l,4-imino-D-arabinitol(DAB1)

  • Kim, In-Su;Hoon, Jung-Young
    • 한국응용약물학회:학술대회논문집
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    • 한국응용약물학회 2003년도 Annual Meeting of KSAP : International Symposium on Pharmaceutical and Biomedical Sciences on Obesity
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    • pp.115-115
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    • 2003
  • Naturally occurring sugar mimics with a nitrogen in the ring are classified into five structural classes: polyhydroxylated pyrrolidines, piperidines, indolizidines. pyrrolizidine, and nortropanes. Glycosidase are involved in a wide range of important biological processes, such as intestinal digestion, post-translational processing of glycoproteins and the lysosomal catabolism of glycoconjugate. The realization that alkaloidal sugar mimics might have enormous therapeutic potential in many diseases such as viral infection, cancer and diabetes has led to increasing interest and demand for these compounds. Most of these effects can be shown to result from the direct or indrect inhibition of glycosidases.

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블라인드 신호 감청기술 (The Listen-in Technique for Blind Signals)

  • 나선필;박철순;장원
    • 한국군사과학기술학회지
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    • 제8권4호
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    • pp.102-109
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    • 2005
  • In this paper, we propose a new listen-in technique to overcome the problems and the shortcomings which could possibly meet in the previous listen-in methods to deal with the blind signal manually according to operator's decision. In the proposed listen-in method, receiving the signals, classifying the modulation types, and demodulating the signals can be done automatically without operator's intervention. We realize the listen-in technology by developing the high speed frequency tuner, the automatic modulation recognizer, and the signal demodulator. In conclusion, we confirm and show that the developed equipment has a good performance in classifying the modulation type through the computer simulation and the field test.

Hyperbranched poly(ether sulfone) with 1,3,5-s-Triazine Moiety

  • Youngkyu Chang;Kwon, Young-Chul;Park, Kyusoon;Im, Chulhee-K
    • Macromolecular Research
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    • 제8권3호
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    • pp.142-146
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    • 2000
  • Hyperbranched poly(ether sulfone) analogs with the 1,3,5-s-triazine moiety were prepared by the direct polymerization of AB$_2$type monomer, 2,4-bis(4-hydroxyphenyl)-6-(4-(4-(4-fluorobenzenesulfonyl)phenoxy)phenyl)-1,3,5-s-triazine (3). The selective reactivity of three chlorine atoms on cyanuric chloride toward nucleophiles provides an efficient route for the systematic synthesis of AB$_2$type triazine monomers and their hyperbranched polymers. The triazine rings influenced the structural and material characteristics of these hyperbranched polymers. The hyperbranched poly(ether sulfone) analog4 showed a glass transition at 295$^{\circ}C$. and was soluble in THF, 1,4-dioxane, and DMSO. An excellent thermal stability of polymer 4 was exhibited by a TGA analysis, which showed that 5% weight loss occurred at 480$^{\circ}C$.

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하이솔리드 도료용 고 고형분인 아크릴수지의 합성에 관한 연구 (Synthesis of Acrylic Resins with High-Solids Contents for HS Coatings)

  • 양인모;우종표;박홍수;김성길
    • 한국응용과학기술학회지
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    • 제17권4호
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    • pp.233-239
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    • 2000
  • To prepare an environmental friendly high-solid coatings an acrylic resin containing 80% of solid content was synthesized by addition polymerization of caprolactone acrylate, n-butyl acrylate, ethyl methacrylate, and 2-hydroxyethyl methacrylate. The conversion was $78{\sim}93%$ and the prepared resin's physical properties are as follows: viscosity, $212{\sim}3424cps: $M_{n}$ $1740{\sim}2400$. There was a trend that viscosity and molecular weight of the resin increased with Tg, but no direct proportionality was observed.

Synthesis of N,N-Diaryl-(pyridin-3-yl)pyrimidin-2-amine Derivatives and Their Photochemical Properties

  • El-Deeb, Ibrahim Mustafa;Lee, So-Ha
    • 한국응용과학기술학회지
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    • 제25권3호
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    • pp.291-298
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    • 2008
  • Although the pyrimidine derivatives were obtained in low yields ranging from 8% to 20%, we reported the successful preparation of N,N-diaryl-pyrimidin-2-amine derivatives starting from the corresponding 2-aminopyrimidines (1a-1c), by direct palladium-catalyzed arylation using different arylbromides. The reasons of low yields are thought to be the electronic and steric effects by the neighboring aromatic systems. The absorption spectra and photoluminescent spectra of compounds (3a 3g and 4a-4c) were measured using dichloromethane on the concentration of 25 mM by UV vis spectroscopy and luminescent spectroscopy. Pyrimidine derivatives 4a, 4b, and 4c showed moderate emission maxima at 474 nm, 481 nm, and 367 nm, respectively, while other compounds showed very weak photoluminescence or no photoluminescence at all.

6자유도 진동 흡진기의 기하적 설계 이론 (Geometrical Design Theory of a 6 DOF Vibration Absorber)

  • 장선준;최용제
    • 한국정밀공학회지
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    • 제22권7호
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    • pp.191-199
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    • 2005
  • Many researchers have been investigating the design of multi-mode absorption vibration absorber for multi degree-of-freedom (DOF) system. The approach taken to this problem has been to find the optimized constants of stiffness and damping for the given set of single-DOF absorbers or single multi-DOF absorber attached to a multi degree-of-freedom system. This paper presents a novel geometrical and direct design theory of a 6 DOF vibration absorber via screw theory. Theoretical development is demonstrated by a practical example in which the diagonal stiffness matrix is synthesized using rectangular configuration of springs. The performance of this absorber is simulated by modal analysis.