• Title/Summary/Keyword: direct dye

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Preparation and Evaluation of Low Viscosity Acrylic Polymer Based Pretreatment Solution for DTP Reactive Ink (DTP 반응성 잉크용 저점도 아크릴계 고분자 전처리액 제조 및 특성 평가)

  • Kim, Hyeok-Jin;Seo, Hye-Ji;Kwak, Dong-Sup;Hong, Jin-Pyo;Yoon, Seok-Han;Shin, Kyung
    • Textile Coloration and Finishing
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    • v.29 no.3
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    • pp.122-130
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    • 2017
  • In the direct digital textile printing process, the pre-treatment process is an essential condition for products by forming a clear pattern by sticking and penetration of DTP dye without spreading on the fabric. Recently, pre-treatment agent is changing from high viscosity to low viscosity in order to reduce defects of fabric during pre-treatment process. In this study, pre-treatment agent of acrylic polymer with low viscosity(less than 50cps) was prepared according to the solid content of the polymer, pre-treated on the cotton fabric, and direct DTP printing was performed to compare the color and sharpness. As a result, it showed high color at a viscosity of 50cps or less. When the solid content of the polyacrylic acid having a high molecular weight(A1) was 2.5wt%, when the solid content of the polyacrylic acid having a low molecular weight(A2) was 1 - 1.5wt%, the color was the best. And when the solid content of A1 and A2 was 1.5wt%, the degree of spreading was small and A1 was superior to A2 at the sharpness.

STUDY OF SYNTHESIS, MATTER S PROPERTIES AND APPLICATION OF MICA/TIA$_2$/SIO$_2$PIGMENT IN COSMETICS AREA

  • Ju, Namgung;Lee, Dong-Kyu
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.24 no.3
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    • pp.51-58
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    • 1998
  • Generally pigment differs from dye stuff because it cannot be melted in water but also because it is stable physically and chemically. In this study you will discover the function, properties and effects of Micai-TiO$_2$-SiO$_2$pigment as abase material pigment. But until now used Mica of the base material is about 7-l5${\mu}{\textrm}{m}$ with an average diameters of 15${\mu}{\textrm}{m}$. A new characteristic superficial pigment was obtained from covering the TiO$_2$ and SiO$_2$ with the adsorption result of isoelectric point of a Mica flake, TiO$_2$ and SiO$_2$In the composition reaction study of adsorption was done as well as the physical characteristics of the superficial texture of the obtained material. L,a,b of color change as oil was absorbed, optical nature and change of reflection according to direct and diffused reflection. In the composition of Mica slurry the best result obtained was in a solution with pH 2.0 to 2.3. Following this result, we can come to the idea that electrical attraction was done during the change of electrical charge of the Mica and TiO$_2$ deposit. Also this pigment shows a big scale between the direct reflection and diffused reflection light. Using this characteristic in cosmetic, it was obtained a natural but a contrast between light and shadow making possible a sculptured make-up. Color change due to oil adsorption was insignificant which improved the last of make up.

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Studies on Durability and Polarization Properties of Poly(vinyl alcohol) Polarizing Films Prepared with Reactive Dichroic Dyes (반응성 이색성 염료를 사용하여 제조한 폴리(비닐 알코올) 편광필름의 내구성 및 편광특성에 관한 연구)

  • Choi, E-Joon;Choi, Seung Sock;Park, Il Hyun;Chang, Jin Ho;Back, Sang-Hyun;Park, Sang-Bong
    • Polymer(Korea)
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    • v.37 no.1
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    • pp.66-73
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    • 2013
  • Three reactive dichroic dyes with 3,5-dichloro-2,4,6-triazine moiety were synthesized by reaction between dichroic dyes (such as congo red, direct black 22 or direct black 4) and cyanuric chloride. Poly(vinyl alcohol) (PVA) films were dyed with the obtained three reactive dichroic dyes. After 400% drawing of the PVA films, their optical properties were compared with an iodine-doped PVA film prepared in the same condition. Durability test was performed at $50^{\circ}C$ in 85% of relative humidity for 120 hrs. We found that compared with the iodine-doped PVA polarizing film, the relative durability of the PVA polarizing film dyed with the reactive dichroic dyes was greatly improved.

The Usefulness of Intraoperative Myelography during Spinal Surgery (수술중 시행한 척수 조영술의 유용성)

  • Yoon, Sung-Hoon;Yi, Jin-Seok;Jang, Ha-Sung;Lee, Hung-Jin;Yang, Ji-Ho;Lee, Il-Woo;Kang, Joon-Ki
    • Journal of Korean Neurosurgical Society
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    • v.30 no.sup2
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    • pp.322-327
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    • 2001
  • Objectives : There are many kinds of method to evaluate neural decompression during operation. They are direct visual and manual inspection, intraoperative ultrasound, endoscope, intraoperative computed tomography and intraoperative myelography. We used intraoperative myelography to evaluate the proper decompression of neural elements during the decompressive surgery. Methods : We injected 10-20cc of nonionic water-soluble contrast materials through direct puncture site of exposed dura during operation or lower lumbar level or lumbar drain inserted preoperatively. 12 patients were included in this study. They were 7 patients of centrally herniated lumbar disc disease, 1 patient of multiple lumbar spinal stenosis, 2 patients of thoracic extradural tumor and 2 cervical fracture & dislocations. Results : 5 of 12 patients showed remained neural compression through intraoperative myelography, so they were operated further through other approach. Myelographic dye is heavier than CSF, so the dependent side of subarachnoid space was visualized only. In one case, CSF leakage through hemovac was detected, but it was treated only bed rest for 5 days after hemovac removal. Conclusion :Intraoperative myelography is an effective method to evaluate neural decompression during spinal surgery. This technique is easy and familiar to us, neurosurgeons.

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Colour Removal from Dyestuff Wastewater by Micro Bubbles Flotation Process (마이크로 버블 부상 공정에 의한 염료폐수의 색도 제거)

  • Kim, Myeng-Joo;Han, Sien-Ho
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.606-612
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    • 2022
  • The purpose of this study is to convert hydrophobic dyestuff to hydrophilic dyestuff by reacting cationic collector with anionic dyestuff and reaction anionic collector with cationic dyestuff. The removal of colors from aqueous solutions and/or dispersions has been studied by dispersed-air flotation in a batch column. In this studies used generated micro bubble by ceramic gas diffuser having micro pore size for air flotation process. In this study, a ceramic gas diffuser with micro pore size was used to generate micro bubbles for the air flotation process. Two colours were used for the experiments: Basic Yellow 1 (cationic dyestuff) and Direct Orange 10 (anionic dyestuff). All two were effectively removed by flotation within 8 mins. Sodium dodecyl sulfate, sodium oleate (an anionic collector), and amines (a cationic collector) were found to be effective as collectors in the removal of color, which was found to be related to the pH of the solution and the amount of collector added to it, with high collector dosages causing the process to become pH-independent.

Photodegradation Characteristics of Oxygen Vacancy-fluorinated WO3 Photocatalysts Controlled by Plasma and Direct Vapor Fluorination (플라즈마 및 직접 기상 불소화에 의해 제어된 산소결핍 불소화 WO3 광촉매의 광분해 특성)

  • Lee, Hyeryeon;Lee, Raneun;Kim, Daesup;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.33 no.2
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    • pp.159-165
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    • 2022
  • To enhance the photocatalytic activities of WO3 photocatalysts, fluorine doping was performed to induce the oxygen vacancies. Both plasma and direct vaper fluorination were carried out for fluorine doping, and photocatalytic activities were examined by using methylene blue dye. Oxygen vacancies of the plasma and direct vaper fluorinated WO3 photocatalysts were measured to be 14.65 and 18.59%, which increased to about 23 and 56% at pristine WO3 photocatalysts. The degradation efficiency of methylene blue was also determined about 1.7 and 3.4 times higher than pristine WO3 photocatalysts, respectively, depending on oxygen vacancies increased. In addition, it was confirmed that the bandgap process energy decreased from 2.95 eV to 2.64 and 2.45 eV after fluorine doping. From this result, it is considered that the direct vaper fluorination has an advantage for increasing the photocatalytic activities of WO3 compared to that of the plasma fluorination.

An Experimental Study on the Flame Structure of Partially Premixed Flame using OH PLIF (OH PLIF를 이용한 부분 예혼합 화염의 화염구조에 관한 실험적 연구)

  • Lee, Seung-Young;Lee, Jong-Ho;Jeon, Chung-Hwan;Chang, Young-June
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.54-59
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    • 2001
  • OH radical concentration have been measured in a methane-air partially premixed flames using PLIF. Excitation lines were selected $Q_{1}(6)$ branch, (1,0) band. The system is consisted of Nd:YAG laser, dye laser and frequency doubler to make pump beam for OH radical. On the direct photographs, flame height increases as fuel flow rate and equivalence ratio increase. And on the PLIF images, OH radical is distributed from premixed flame front to nonpremixed flame front through the flame structure with all equivalence ratio. OH overall concentrations increase with equivalence ratio. At the stoichiometric equivalence ratio, the peak of OH radical concentration exists strongly near the inner cone. As equivalence ratio is changed to richer, OH radical distribution goes thinly and the peak is increased as longitudinal direction. As the flow goes to the downstream, OH radical concentration decreases and broadens, because OH radical reacts with another species after OH formation at the initial oxidization. This phenomenon resembles radial distribution. At the l00cc fuel flowrate, the radial peak of OH radical exists from x/R=l.0 to 1.5.

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Physical Properties and Dyeability of Cotton Fabrics Treated with Liquid Ammonia (액체암모니아 처리 면직물의 물성 및 염색성)

  • Jeon, Sung-Ki;Lee, Chang-Soo;Im, Yong-Jin;Lee, Chung;Kim, Tae-Kyung;Lee, Hye-Jung
    • Textile Coloration and Finishing
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    • v.15 no.4
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    • pp.73-79
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    • 2003
  • It is generally known that cotton treated with liquid ammonia has better soft handle, wrinkle recoveries and stability of appearance as compared with the alkali mercerized cotton. In this study, the various cotton fabrics treated with liquid ammonia$(NH_3)$, sodium hydroxide(NaOH) and sodium hydroxide(NaOH)/liquid ammonia$(NH_3)$ and untreated cotton fabric were investigated and compared in terms of physical properties and dyeing behavior. As the result, the strength of four kinds of cotton fabrics were similar. But the elongation of cotton treated with liquid ammonia increased slightly. Liquid ammonia treatment reduced the crystallinity of cotton and the crystalline structure of cotton transformed from cellulose 1 to mixed structure of celluloseIand III. In dyeing, dyeing rate decreased but equilibrium dye uptake increased by liquid ammonia treatment of cotton fabrics.

A Study on the Morphological Changes of Actual Hair Cuticles by Different Types of Conditioner after Coloring Treatment (염색시술 후 사용한 컨디셔너의 종류에 따른 모표피층의 형태 변화 연구)

  • Choi, Jung-Myung;Na, Hyun-Joon;Park, Shin-Jung;Chang, Jee-Hye
    • Journal of the Korean Society of Fashion and Beauty
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    • v.3 no.1 s.4
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    • pp.72-77
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    • 2005
  • The present study was to investigate the effects of different types of conditioner on the morphological changes of hair cuticles after coloring treatment. The virgin hair, aged 22 years served as a subject. Coloring treatment was done with a commercial hair dye agent for 35 minutes as routine procedures at $25^{\circ}C$, 50% R.H. environmental condition. The two different types of conditioner, Essence and LPP were applied to the colored hair 10 times with 2 days interval for 20 days. The hair cuticles were observed by a scanning electron micro scopy before and after coloring and conditioner treatment. The main results were as follows. Coloring treatment damaged the hair cuticles, and both of Essence and LPP had a direct conditioning effect. Also, the damaged hair cuticles were recovered by the repeated application of hair conditioner. Moreover, LPP was more effective in hair curing compared to Essence. These results show that a hair conditioner can be helpful to keep healthy hair and to shorten an interval of coloring.

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Photo-grafting Dyeing of Wool Fabrics with ${\alpha}$-bromoacrylamide reactive dye (반응성 염료를 이용한 양모직물의 광그라프트 염색)

  • Dong, Yuanyuan;Jang, Jin-Ho
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.31-31
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    • 2011
  • Lanasol dyes containing ${\alpha}$-bromoacrylamide or ${\alpha},{\beta}$-dibromopropionylamide group are used for wool dyeing. They are normally applied to wool under pH 4.5 to 6.5 at $100^{\circ}C$. Although wool fabric can be dyed to obtain deep colour, high light and wet fastness, the dyeing processes need long dyeing time at high temperature, with salt addition, which inevitably causes environmental problems. Grafting is a modification method for textile where monomers are covalently bonded onto the polymer chain. It can be initiated by ozone, ${\gamma}$ rays, electron beams, plasma, corona discharge and UV irradiation. Coloration by UV-induced photografting exhibits several advantages such as fast reaction rate, energy saving, simple equipment, easy exploitation and environmentally friendliness. Also it requires much lower energy compared to the conventional dyeing and less damage to the substrate. In this study, a direct sequential UV-induced photografting onto wool fabrics was discussed. To understand the graft polymerization mechanism further, several characterization methods were used. Moreover, the effects of several principal factors on the graft photopolymerization were investigated. Furthermore, the colorfastness results were compared with conventional dyeing methods.

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