• 제목/요약/키워드: dipole moment

검색결과 177건 처리시간 0.032초

유도성 시스템으로부터 무선기기 보호를 위한 이격 거리에 관한 연구 (Study on Separation Distance to Protect Radio Service from Inductive System)

  • 이일규;심용섭;민경일;차재상;이경근
    • 한국위성정보통신학회논문지
    • /
    • 제6권1호
    • /
    • pp.103-108
    • /
    • 2011
  • 본 논문은 산업현장 뿐만 아니라 가정의 일생생활에서 그 사용이 점차 증가하고 있는 유도성 시스템과 기존의 무선기기에 대한 간섭에 관한 것이다. 자계강도 간섭 신호를 방사하는 유도성 시스템의 간섭을 분석하기 위한 모델을 제시하였고 이 모델을 바탕으로, 측정을 통해 구해진 유도성 시스템의 자계강도는 마그네틱 다이폴 모멘트로 변환되고 무선기기의 허용 가능한 간섭 레벨을 고려하여 유도성 시스템으로부터 무선기기를 보호하기 위해 요구되는 이격 거리를 산출하는 방법을 제시하였다. 또한, 실제 적용 가능한 시나리오를 설정하고 본 논문에서 제시한 방법을 이용하여 유도성 시스템으로부터 무선기기를 보호하기 위한 이격거리를 산출하였다. 본 논문에서 제시한 이격 거리 산출 방법은 유도성 시스템과 무선기기의 양립성 확보에 기여할 것이다.

메로시아닌 색소 LB막의 상호혼합효과에 의한 J-aggregates 편광특성 (Polarization Properties of J-aggregates by Mutual Mixing Effect in the LB Films of Merocyanine Dyes)

  • 양창헌;김경철;권영수;신훈규
    • 전기학회논문지
    • /
    • 제59권12호
    • /
    • pp.2245-2249
    • /
    • 2010
  • The physical properties of the LB films with merocyanine dyes have been published and attract attention due to the possibility of molecular structure control. The evaluation of the thin films was focused for the purpose of molecular structure control. The molecular structure in the case of the thin films with dyes can be examine by optical absorption spectra measurements. In the result measured by optical absorption spectra, the $[DX]_{1-x}[DO]_x$ LB films shows a large in-plane anisotropy and the transition dipole moment of red-shifted band is preferentially oriented perpendicular to the dipping direction of the film, while that of the blue-shifted band prefers the dipping direction. The spectrum for $0_{\circ}$, $90_{\circ}$-polarized light coincides with the spectrum for non-polarized light and also with the spectrum was observed in the LB film deposited using a fresh solution. These results show that the aging process does not cause a structural change in chromophore but a change in the degree of molecular orientation. In the results, study of the merocyanine dyes LB films using optical absorption spectra would an interesting problem of absorbance peak shifts and mixed components.

Comparison of Three Modeling Methods for Identifying Unknown Magnetization of Ferromagnetic Thin Plate

  • Choi, Nak-Sun;Kim, Dong-Wook;Yang, Chang-Seob;Chung, Hyun-Ju;Kim, Hong-Joon;Kim, Dong-Hun
    • Journal of Electrical Engineering and Technology
    • /
    • 제6권6호
    • /
    • pp.799-805
    • /
    • 2011
  • This study presents three different magnetization models for identifying unknown magnetization of the ferromagnetic thin plate of a ship. First, the forward problem should be solved to accurately predict outboard magnetic fields due to the magnetization distribution estimated at a certain time. To achieve this, three different modeling methods for representing remanent magnetization (i.e., magnetic charge method, magnetic dipole array method, and magnetic moment method) were utilized. Material sensitivity formulas containing the first-order gradient information of an objective function were then adopted for an efficient search of an optimum magnetization distribution on the hull. The validity of the proposed methods was tested with a scale model ship, and field signals predicted from the three different models were thoroughly investigated with reference to the experimental data.

Improved Electron Injection on Organic Light-emitting Diodes with an Organic Electron Injection Layer

  • Kim, Jun-Ho;Suh, Chung-Ha;Kwak, Mi-Young;Kim, Bong-Ok;Kim, Young-Kwan
    • Transactions on Electrical and Electronic Materials
    • /
    • 제6권5호
    • /
    • pp.221-224
    • /
    • 2005
  • To overcome of poor electron injection in organic light-emitting diodes (OLEDs) with Al cathode, a thin layer of inorganic insulating materials, like as LiF, is inserted between an Al cathode and an organic electron transport layer. Though the device, mentioned above, improves both turn on voltage and luminescent properties, it has some problems like as thickness restriction, less than 2 nm, and difficulty of deposition control. On the other hand, Li organic complex, Liq, is less thickness restrictive and easy to deposit and it also enhances the performance of devices. This paper reports the improved electron injection on OLEDs with another I A group metal complex, Potassium quinolate (Kq), as an electron injection material. OLEDs with organic complexes showed improved turn-on voltage and luminous efficiency which are remarkably improved compared to OLEDs with Al cathode. Especially, OLEDs with Kq have longer life time than OLEDs with Liq.

Regulation Mechanism of Redox Reaction in Rubredoxin

  • Tongpil Min;Marly K. Eidsness;Toshiko Ichiye;Kang, Chul-Hee
    • Journal of Microbiology
    • /
    • 제39권3호
    • /
    • pp.149-153
    • /
    • 2001
  • The electron transfer reaction is one of the most essential processes of life. Not only does it provide the means of transforming solar and chemical energy into a utilizable form for all living organisms, it also extends into a range of metabolic processes that support the life of a cell. Thus, it is of great interest to understand the physical basis of the rates and reduction potentials of these reactions. To identify the major determinants of reduction potentials in redox proteins, we have chosen the simplest electron transfer protein, rubredoxin, a small (52-54 residue) iron-sulfur protein family, widely distributed in bacteria and archaea. Rubredoxins can be grouped into two classes based on the correlation of their reduction potentials with the identity of residue 44; those with Ala44 (ex: Pyrococcus furiosus) have reduction potentials that are ∼50 mV higher than those with Va144 (ex: Clostridium pasteurianum). Based on the crystal structures of rubredoxins from C. pasteurianum and P. furiosus, we propose the identity of residue 44 alone determines the reduction potential by the orientation of the electric dipole moment of the peptide bond between 43 and 44. Based on 1.5 $\AA$ resolution crystal structures and molecular dynamics simulations of oxidized and reduced rubredoxins from C. pasteurianum, the structural rearrangements upon reduction suggest specific mechanisms by which electron transfer reactions of rubredoxin should be facilitated.

  • PDF

Analysis of Nonclassical Fullerene C24 Regioisomers Encapsulating H2O using Hybrid Density Functional Methods B3LYP and M06-2X

  • Lee, Seol;Lee, Ji Young;Lee, Kee Hag
    • Bulletin of the Korean Chemical Society
    • /
    • 제35권3호
    • /
    • pp.899-904
    • /
    • 2014
  • The atomic structures and electronic properties of six classical and nonclassical $H_2O$@$C_{24}$ fullerene regioisomers are systematically studied using the hybrid density functional B3LYP method and M06-2X method with empirical dispersion in conjunction with the 6-31G(d,p) basis sets. The charge transfer, frontier orbitals, dipole moment, energy gap between the HOMO and LUMO, and volume change of the $C_{24}$ cage are analyzed upon encapsulation of a $H_2O$ molecule in each $C_{24}$ regioisomer. All encapsulation processes are endothermic and the relative stabilities of six $C_{24}$ fullerene regioisomers change upon encapsulation of $H_2O$.

VDCN/VPr 공중합체(共重合體)의 비선형(非線形) 유전특성(誘電特性) (Nonlinear Dielectric Relaxation in VDCN/VPr Copolymer)

  • 이덕출;강대하
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1989년도 하계종합학술대회 논문집
    • /
    • pp.356-358
    • /
    • 1989
  • Linear and nonlinear complex permittivities have been measured for an alternating copolymer of vinylidene cyanide(VSCN) with vinyl propionale(VPr). It is found that the third order permittivity ${\varepsilon}_3$ depends upon frequency according to a function V ${\varepsilon}_3$/ ${1+(j{\omega}{\tau}_3)^{\beta}}^3$ while the linear permittivity ${\varepsilon}_1$obeys a Debye type function ${\nabla}{\varepsilon}_1$/ {1+$(j{\omega}{\tau}_1)^{\beta}$}. Experimental results are well fitled by predicted functions except at low frequency where dc conduction dominates. The relaxation times ${\tau}_1$ and ${\tau}_3$ at same teperature are nealy equal and depend upon temperature according to WLF form. The relaxation strengths ${\nabla}{\varepsilon}_1$ and ${\nabla}{\varepsilon}_3$ have a peak at the vicinity of glass transition temperature (Tg). The strength ${\nabla}{\varepsilon}_1$ has a value of -9 order and ${\nabla}{\varepsilon}_3$ has a negative value of -25 order. The analysis of mechanism by combined knowledge about linear and nonlinear permittivities and dipole moment gives us an imformation of the electrical and thermal dipolar motions in this copolymer.

  • PDF

아조벤젠이 기능화된 덴드리머 유기단분자막의 광학적 거동 (Optical Behavior of Azobenzene Functionalized Dendrimer in Organic Monolayers)

  • 신훈규;손정호;김병상;권영수
    • 한국전기전자재료학회논문지
    • /
    • 제15권7호
    • /
    • pp.627-633
    • /
    • 2002
  • Many isolated featureless domains were explicitly observed even at the air-water interface. We measured the surface pressure shift originating from the photo-isomerization of azobenzene units on the periphery of dendrimers. The maximum surface pressure was gradual1y increased and saturated by cyclic compression and decompression. By irradiation of 365 [nm] light, the surface pressure was increased, which was originated by the photo-isomerization process of the azobenzene group on the periphery from trans to cia form. The increase of the dipole moment ($\mu$), which may increase the interaction among Azo dendrimer molecules, made an important role on surface pressure shift. From the absorbance spectrum by UV irradiation and heat treatment, we can see that the absorbance in the UV region decreases with the increase of the UV irradiation time, but the peak at 350 m, characteristic of dendrimers in the LB monolayers, was not shifted until four irradiation cycles. This suggests that optical behavior and morphological change are affected by the functional group and the symmetric chain.

인지질 유기단분자막의 알킬체인에 의한 유전완화시간 (Dielectric Relaxation Time for Alkyl Chain of Phospolipid Organic Monolayers Film)

  • 송진원;조수영;김영근;이경섭
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2004년도 춘계학술대회 논문집 반도체 재료 센서 박막재료 전자세라믹스
    • /
    • pp.111-115
    • /
    • 2004
  • In this paper, evaluation of physical properties about dielectric relaxation phenomena by the detection of the surface pressures and displacements current on the monolayer films of phospolipid monomolecular DLPC, DMPC using pressure stimulus. As a result, the changed surface pressure, displacement current and the transition forms of dipole moment of phospolipid monomolecular in area per molecular by pressure stimulus were conformed well. It was known that the monolayers by linear relationship for decision of dielectric relaxation time between compressure speed $\alpha$ and molecule area $A_m$ By according to the linear relationship relation get that frictional constant $\xi$, DLPC was $1.89{\times}10^{-19}$[Js] and DMPC was $0.722{\times}10^{-19}$[Js]. It is found that the phospolipid monolayer of dielectric relaxation takes a little time and depend on the molecular area.

  • PDF

Molecular-scale Structure of Pentacene at Functionalized Electronic Interfaces

  • Seo, Soon-Joo;Peng, Guowen;Mavrikakis, Manos;Ruther, Rose;Hamers, Robert J.;Evans, Paul G.;Kang, Hee-Jae
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
    • /
    • pp.299-299
    • /
    • 2011
  • A dipolar interlayer can cause dramatic changes in the device characteristics of organic field-effect transistors (OFETs) or photovoltaics. A shift in the threshold voltage, for example, has been observed in an OFET where the organic semiconductor active layer is deposited on SiO2 modified with a dipolar monolayer. Dipolar molecules can similarly be used to change the current-voltage characteristics of organic-inorganic heterojunctions. We have conducted a series of experiments in which different molecular linkages are placed between a pentacene thin film and a silicon substrate. Interface modifications with different linkages allow us to predict and examine the nature of tunneling through pentacene on modified Si surfaces with different dipole moment. The molecular-scale structure and the tunneling properties of pentacene thin films on modified Si (001) with nitrobenzene and styrene were examined using scanning tunneling spectroscopy. Electronic interfaces using organic surface dipoles can be used to control the band lineups of a semiconductor at organic/inorganic interfaces. Our results can provide insights into the charge transport characteristics of organic thin films at electronic interfaces.

  • PDF