• Title/Summary/Keyword: diffusion treatment

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Evaluation of Pressurized Water Diffusion in Water Treatment Process Using CFD (전산유체역학(CFD)를 활용한 정수공정에서 압력수 확산공정 진단)

  • Cho, Young-Man;Yoo, Soo-Jeon;Roh, Jae-Soon;Bin, Jae-Hoon;Choe, Kwang-Ju;Lee, Kwang-Ug;Lee, Gi-Bong;Lee, Jeong-Gyu
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.5
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    • pp.359-367
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    • 2011
  • The Process of Pressurized water diffusion is mixing process by pressurized water injection with coagulate and chlorine water in the water treatment system. The objectives of this research were to evaluate the mixing length and diameter of diffusion plate and distance from injection pipe for complete mixing by using computational fluid dynamics. From the results of CFD simulation, when diameter of injection pipe is 50 mm, 100 mm and injection pressure is $5kg/cm^2$ and the diameter of inlet pipe is 2,200 mm, the complete mixing length is 4D (D: Length as diameter of inlet pipe). When diameter of injection pipe is 50 mm, the diameter of the diffusion plate in o.1D and distance from injection pipe is 0.2D, the complete mixing length is 3D that is the most short mixing length. But when diameter of injection pipe is 100 mm and mutually related the diameter, distance of diffusion plate, the complete mixing length is 4D over. Therefore, as the diameter of inlet pipe is 2,200 mm, the injection pipe 50 mm is more efficient than 100 mm.

The Diffusion of Boron from Borate Rod through Pinus densiflora and Pinus koraiensis (소나무와 잣나무에서 붕산염 막대로부터 붕소의 확산)

  • Oh, Choong-Sup;Kim, Jae-Jin;Kim, Gyu-Hyeok
    • Journal of Conservation Science
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    • v.7 no.2
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    • pp.60-67
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    • 1998
  • The effects of moisture content (MC) and diffusion period on the diffusion of boron from borate rod through Pinus densiflora and P. koraiensis were investigated as a preliminary research of integrated remedial treatment for heritage wooden structures using borate rod. After equilibrating MCs of samples (15, 25, and 40%), borate rod (1,000 mg) was inserted into the sample, and stored for diffusion of boron at room temperatures ($23^{\circ}C$) for 2, 4, 8, and 12 weeks. Wafers were serially cut at constant intervals from rod treatment point and the boron penetration through longitudinal and transverse direction was measured by staining with boron indicator. For boron diffusion, MC above fiber saturation point was needed, and the diffusion rates increased with time. The fastest rates of diffusion were observed in longitudinal direction, followed by the radial and then the tangential direction. The rates of diffusion in all directions were the fastest in P. koraiensis. In P. densiflora, the diffusion rates through heartwood was faster than that in sapwood in longitudinal direction and vice versa in transverse direction. Based on the best result of this study, optimal space between rod insertion points could be recommended as follows; approximately 120 mm for P. koraiensis and heartwood of P. densiflora, 60 mm for sapwood of P. densiflora in longitudinal direction, and approximately 30 mm for all species tested in transverse direction. However, the effect of rod size and long-term exposure for diffusion on boron movement should be fully investigated for the accurate evaluation of optimal space between rod holes.

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Effect of Heat Treatment on the Microstructural Evolution of Pt-aluminide Coated Ni-based Superalloy (Pt-Aluminide로 코팅된 초내열합금의 열처리에 따른 미세조직변화)

  • Joo, D.;Park, S.H.;Jung, Y.G.;Lee, K.H.;Kim, C.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.19 no.2
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    • pp.103-108
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    • 2006
  • Microstructural evolution of Pt-aluminide coated Ni-based superalloy has been investigated with ductilization heat treatment. The Pt coat was prepared on the superalloy and then aluminide coating was conducted using a pack cementation process. Samples were heat-treated at $1050^{\circ}C$ for 2 hrs and the microstructure and element analysis were preformed. A various precipitated compounds were observed within the coating layer and the diffusion region in the Pt-aluminide coating and heat treatment, indicating that the bi-phase compounds of $PtAl_2$ and NiAl were performed during the Pt-aluminide coating, whereas $M_{23}C_6$, MC, $Ni_3Al$ and ${\sigma}$ phases were precipitated in the inter-diffusion region. The bi-phase compounds of $PtAl_2$ and NiAl were transformed into the single phase compound of $PtAl_2$ with the heat treatment, increasing the amount of carbide and ${\sigma}$ phase.

Strength Change in Ultra Low Carbon Steel due to Carburizing Heat Treatment for Hot Press Forming (HPF 적용을 위한 극저탄소강의 강도에 미치는 침탄 열처리의 영향)

  • Kang, Soo Young
    • Korean Journal of Metals and Materials
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    • v.50 no.6
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    • pp.433-438
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    • 2012
  • Strength change in ultra low carbon steel carburized at $880^{\circ}C$ and $930^{\circ}C$ for 10, 30, 60 and 120 minutes was investigated. The results were analyzed by a tensile test, chemical composition analysis, optical microscopy and scanning electron microscopy. Stress in the 0.5% strain specimen in the tensile test increased as the time treated at $880^{\circ}C$ and $930^{\circ}C$ increased, because the carbon diffusion layer and the martensite of the specimen increased with increasing treatment time. Martensite was found in the ferrite region in the specimen treated at $880^{\circ}C$, which is attributed to grain boundary diffusion.

Evaluation of Diffusion on Cement Mortar and Durability of Concrete Specimen Using Inorganic Coating Material and Surface Treatment System (무기질 도료 및 표면처리 시스템을 적용한 시멘트 모르타르와 콘크리트의 내구성 평가)

  • Kim, In-Seob;Lee, Jong-Kyu;Chu, Yong-Sik;Kim, Tae-Hyun;Shim, Kwang-Bo
    • Journal of the Korea Concrete Institute
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    • v.15 no.4
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    • pp.522-528
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    • 2003
  • Concrete has been considered as a semi-permanent structural material, because its excellent durability. However, such high durable structure is often attacked by some environmental condition such as chloride diffusion, carbonation and so on. In order to prevent the deterioration behaviors of concrete structures. We estimated durability of concrete when used surface treatment system and coatings by new type inorganic coating materials. Base on the results of chloride ion's diffusion test, the coated cement mortar had smaller transmitted quantity.

A study on the grain growth mechanism in dual-phase high Cr-steel (고크롬 (α+γ) 2상강의 결정립 성장기구)

  • Wey, Myeong-Yong
    • Journal of the Korean Society for Heat Treatment
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    • v.11 no.4
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    • pp.324-332
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    • 1998
  • The grain growth characteristics of dual-phase (${\alpha}+{\gamma}$) containing high Cr-steel have investigate using ${\alpha}$-, ${\gamma}$-single phases and (${\alpha}+{\gamma}$)dual-phase of 12%Cr Steel. The heat treatment has performed at $1000-1200^{\circ}C$ for 1-100hr. The results are as follows : 1) The grain growth rate in (${\alpha}+{\gamma}$) dual phase was substantially slower than that of single grain. 2) The relation between mean grain radius $\bar{{\gamma}}$ and annealing time t is, in general, described as following equation : $$(\bar{{\gamma}})^n-(\bar{{\gamma}_o})^n=K_n{\cdot}t{\cdots}{\cdots}(1)$$ i) In the case of single phase of high Cr steel, Eq.(1) is described as $(\bar{{\gamma}})^2-(\bar{{\gamma}_o})^2=K_2{\cdot}t$ and the grain growth is controlled by boundary migration. ii) In dual phase, the grain growth needs diffusion of alloying elements because the chemical composition of ${\alpha}$- and ${\gamma}$- phases differs from each other. When the volume fraction of ${\alpha}$-, ${\gamma}$-phase was almost equal and ${\gamma}$-phase in the case of 80 and $90%{\gamma}$. Eq.(1) is described as $(\bar{{\gamma}})^3-(\bar{{\gamma}_o})^3=K_3{\cdot}t$ because the grain growth is controlled by volume diffusion iii) In the case of ${\gamma}$-rich phase (80 and $90%{\gamma}$), the grain growth of minor phase (10 and $20%{\alpha}$) is described as $(\bar{{\gamma}})^4-(\bar{{\gamma}_o})^4=K_4{\cdot}t$ because the boundary diffusion is predominent rather than volume diffusion.

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Effect of Heat Treatment of the Diffusion Barrier for Bus Electrode of Plasma Display by Electroless Ni-B Deposition (무전해 Ni-B 도금을 이용한 플라즈마 디스플레이 버스 전극용 확산방지막의 열처리 영향)

  • Choi Jae Woong;Hwang Gil Ho;Hong Seok Jun;Kang Sung Goon
    • Korean Journal of Materials Research
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    • v.14 no.8
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    • pp.552-557
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    • 2004
  • Thin Ni-B films, 1 ${\mu}m$ thick, were electrolessly deposited on Cu bus electrode fabricated by electro deposition. The purpose of these films is to encapsulate Cu electrodes for preventing Cu oxidation and to serve as a diffusion barrier against copper contamination of dielectric layer in AC-plasma display panel. The layers were heat treated at $580^{\circ}C$(baking temperature of dielectric layer) with and without pre-annealing at $300^{\circ}C$($Ni_{3}B$ formation temperature) for 30 minutes. In the layer with pre-annealing, amount of Cu diffusion was lower about 5 times than that in the layer without pre-annealing. The difference of Cu concentration could be attributed to Cu diffusion before $Ni_{3}B$ formation at grain boundaries. However, the diffusion behavior of the layer with pre-annealing was similar to that of the layer without pre-annealing after $Ni_{3}B$ formation. With increasing annealing time, Cu concentration of both layers increased due to grain growth.

Treatment of Melamine by GAC Adsorption According to Adsorbent Size: Kinetics and Dispersion-Diffusion (흡착제 크기에 따른 GAC의 멜라민 흡착 처리 : 반응속도와 분산-확산)

  • Lee, Jai-Yeop;Lee, Sangjung;Han, Ihnsup
    • Journal of Soil and Groundwater Environment
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    • v.18 no.3
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    • pp.65-72
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    • 2013
  • Adsorption of melamine was examined using columns packed with granular activated carbon (GAC). Raw GAC was sieved with 20, 40, 60 and 80 mesh to determine the influence of adsorbent particle size on reaction and diffusion. The mass ratio of the adsorption capacity of GAC for melamine ranged from 9.19 to 11.06%, and adsorption rates increased with decreasing particle size within this range. Rate constants between 3.295 ~ 4.799 $min^{-1}$ were obtained using a pseudofirst-order equation that was used to determine adsorption kinetics. A surface diffusion model was adapted to take into account the unsteady-state equation of a spherical adsorbent by converting the surface concentration from a constant to a variable governed by a dispersion equation. The calculated values were fit with the experimental results by using the diffusion coefficients as regression parameters. The modified equation exhibited a more precise agreement with respect to the sum of the absolute error (SAE).

Evaluation of Coagulants Dispersion in Pump Diffusion Mixer for Water Treatment (CFD모사 기법을 이용한 Pump Diffusion Mixer내의 응집체 확산분포에 대한 평가)

  • Park, Young-Oh;Park, No-Suk;Kim, Seong-Su;Kim, Ki-Don;Lim, Kyung-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.1
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    • pp.49-63
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    • 2008
  • The objectives of this research were to evaluate the pressurized/the main inlet water flowrate ratio which have been used as the most important parameter for operating the pump diffusion mixer until now, to suggest the alternative operating parameter and the relating criteria if the flowrate ratio was not inadequate. For the objectives of this research, computational fluid dynamics (CFD) simulation was conducted for 21 cases of flowrate ratio in full-scaled pump diffusion mixer. From the results of CFD simulation, the local velocity gradient values were calculated in each case in order to analyze the simulation results in more detail. For verifying CFD simulation, wet test was conducted. The wet test was to measure the factual coagulant dispersion distribution at a distance of 5.4m from deflector. From both results of CFD simulation and wet test, flowrate ratio was inadequate as operating parameter or criteria, on the other hand the pressurized/the main inlet velocity ratio(dimensionless) was useful in predicting the performance of pump diffusion mixer. Also, the injected coagulant could be dispersed evenly in overall cross section on the condition that pressurized/the main inlet velocity ratio(dimensionless) is over at least 20.

Low-temperature Sintering Behavior of TiO2 Activated with CuO

  • Paek, Yeong-Kyeun;Shin, Chang-Keun;Oh, Kyung-Sik;Chung, Tai-Joo;Cho, Hyoung Jin
    • Journal of the Korean Ceramic Society
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    • v.53 no.6
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    • pp.682-688
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    • 2016
  • In $TiO_2$-CuO systems, low-temperature sinterability was investigated by a conventional sintering method. Sintering temperatures were set at under $950^{\circ}C$, at which the volume diffusion is inactive. The temperatures are less than the melting point of Ag ($961^{\circ}C$), which is often used as an internal conductor in low-temperature co-fired ceramic technology. To optimize the amount of CuO dopant, various dopant contents were added. The optimum level for enhanced densification was 2 wt% CuO. Excess dopants were segregated to the grain boundaries. The segregated dopants supplied a high diffusion path, by which grain boundary diffusion improved. At lower temperatures in the solid state region, grain boundary diffusion was the principal mass transport mechanism for densification. The enhanced grain boundary diffusion, therefore, improved densification. In this regard, the results of this study prove that the sintering mechanism was the same as that of activated sintering.