• Title/Summary/Keyword: diffusion method

Search Result 2,967, Processing Time 0.028 seconds

Development of Oxygen Diffusion Test Method for Crack Width Evaluation of Self-Healing Concrete (자기치유 콘크리트의 균열치유 성능평가를 위한 개선된 산소확산 시험방법 제안)

  • Lee, Do-Keun;Shin, Kyung-Joon
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.9 no.3
    • /
    • pp.375-382
    • /
    • 2021
  • Self-healing concrete is in the spotlight in that it can effectively extend the lifespan of concrete structures by healing cracks in the structure by themselves without additional repairing or retrofiting actions. Currently, self-healing concrete is a field that is being actively studied around the world, but since most studies focus on the improvement of healing performance, there is a lack of methods to rationally evaluate the self-healing performance of concrete. Although the gas diffusion test method has been developed for the use in the performance evaluation of self-healing concrete, it has revealed that for gas diffusion through the matrix affect the crack diffusion coefficients depending on the environmental conditions such as the saturation of the specimen, the temperature, and humidity during the experiment. Therefore, in this study, the method has been proposed to eliminate the influence of the matrix diffusion when calculating the crack diffusion coefficient. In addition, a pre-conditioning process was introduced to shorten the experimental time. As a result, the crack width could be estimated with an error level of less than 3% in the test time of about 20 minutes.

Uniformly Convergent Numerical Method for Singularly Perturbed Convection-Diffusion Problems

  • Turuna, Derartu Ayansa;Woldaregay, Mesfin Mekuria;Duressa, Gemechis File
    • Kyungpook Mathematical Journal
    • /
    • v.60 no.3
    • /
    • pp.629-645
    • /
    • 2020
  • A uniformly convergent numerical method is developed for solving singularly perturbed 1-D parabolic convection-diffusion problems. The developed method applies a non-standard finite difference method for the spatial derivative discretization and uses the implicit Runge-Kutta method for the semi-discrete scheme. The convergence of the method is analyzed, and it is shown to be first order convergent. To validate the applicability of the proposed method two model examples are considered and solved for different perturbation parameters and mesh sizes. The numerical and experimental results agree well with the theoretical findings.

Determination of Vitamin $B_12$ by Agar Diffusion Method (원통평판법을 이용한 비타민 $B_12$의 정량)

  • Lee, Sung-Ho;Cho, Chin-Sung;Song, Young-Joon
    • Journal of Pharmaceutical Investigation
    • /
    • v.21 no.2
    • /
    • pp.79-84
    • /
    • 1991
  • The agar diffustion method using Escherichia coli was investigated for determination of Vitamin $B_{l2}$ instead of turbidimetric method using Lactobacillus leichannii (USP XXII method). The turbidimetric method is difficult to control the test organism and it has complicated procedure. From this study, it was found that the agar diffusion method on the determination of Vitamin $B_{12}$ in pharamaceutical preparation is simple and convenient as compared with turbidimetric method. Also we found that the coefficient of variation in reproducibility and the standard error in recovery were 2.18% and 1.83%, respectively.

  • PDF

Development of an Automated Diffusion Scrubber-Conductometry System for Measuring Atmospheric Ammonia

  • Lee, Bo-Kyoung;Lee, Chong-Keun;Lee, Dong-Soo
    • Bulletin of the Korean Chemical Society
    • /
    • v.32 no.6
    • /
    • pp.2039-2044
    • /
    • 2011
  • A semi-continuous and automated method for quantifying atmospheric ammonia at the parts per billion level has been developed. The instrument consists of a high efficiency diffusion scrubber, an electrolytic on-line anion exchange device, and a conductivity detector. Water soluble gases in sampled air diffuse through the porous membrane and are absorbed in an absorbing solution. Interferences are eliminated by using an anion exchange devises. The electrical conductivity of the solution is measured without chromatographic separation. The collection efficiency was over 99%. Over the 0-200 ppbv concentration range, the calibration was linear with $r^2$ = 0.99. The lower limit of detection was 0.09 ppbv. A parallel analysis of Seoul air over several days using this method and a diffusion scrubber coupled to an ion chromatography system showed acceptable agreement, $r^2$ = 0.940 (n = 686). This method can be applied for ambient air monitoring of ammonia.

A MODEL STUDY ON MULTISTEP RECOVERY OF ACTINIDES BASED ON THE DIFFERENCE IN DIFFUSION COEFFICIENTS WITHIN LIQUID METAL

  • CHUN, YOUNG-MIN;SHIN, HEON-CHEOL
    • Nuclear Engineering and Technology
    • /
    • v.47 no.5
    • /
    • pp.588-595
    • /
    • 2015
  • This study presents an effective method for additional recovery of residual actinides in liquid electrodes after the electrowinning process of pyroprocessing. The major distinctive feature of this method is a reactor with multiple reaction cells separated by partition walls in order to improve the recovery yield, thereby using the interelement difference in diffusion coefficients within the liquid electrode and controlling the selectivity and purity of element recovery. Through an example of numerical simulation of the diffusion scenarios of individual elements, we verified that the proposed method could effectively separate the actinides (U and Pu) and rare-earth elements contained in liquid cadmium. We performed a five-step consecutive recovery process using a simplified conceptual reaction cell and recovered 58% of the initial amount of actinides (U + Pu) in high purity (${\geq}99%$).

Automated Determination of SOx in Air by Diffusion Scrubber-lon Chromatography (확산포집-이온크로마토그래프법을 이용한 대기중 SOx의 자동정량)

  • 이용근;이동수;백선영
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.11 no.4
    • /
    • pp.307-313
    • /
    • 1995
  • An automatic method is developed for the determination of SOx in atmosphere. The method involves SOx sampling in diffusion scrubber followed by ion chromatographic analysis. Filtered air is withdrawn at 1.8.ell./min through a diffusion scrubber of which inner tube is made of PTFE(Gore-tex) membrane tubing. 1mM $H_{2}$ $O_{2}$ is used as absorbing solution so that SOx is oxidized to S $O_{4}$$^{2-}$. The scrubbered solution is automatically injected into ion chromatograhpy eith conductivity detection for sulphate determination. Replacement of commonly used polyproplene membrane with PTFE gives several merits such as easy preparation of diffusion scrubber, better collection efficiency. No measurable memory effect is experienced, and this isin contrast to previous work for ammonia. Detection limit of this method defined by three times standard deviation is 0.56ppbv. The precision is 0.4% RSD at SOx concentration of 7.3ppbv Results for Seoulatmosphere ate presented.

  • PDF

Calculation of the Viscosity and Diffusion Coefficients for Some Binary Gaseous Mixtures Using the Semi-empirical Inversion Method (반실험적 반전 방법을 이용한 이성분계 기체 혼합물의 점도와 확산계수 계산)

  • Rafiee, H.R.;Heidari, N.
    • Journal of the Korean Chemical Society
    • /
    • v.55 no.4
    • /
    • pp.581-589
    • /
    • 2011
  • Viscosity and diffusion coefficients for the gaseous binary mixtures of benzene- toluene, benzene-phenol and benzene-p-xylene over a wide range of temperature and composition have been predicted using the semi-empirical inversion method. The accuracies are within 3% and 4% for viscosities and diffusion coefficients, respectively.

Improved Generalized Method of Moment Estimators to Estimate Diffusion Models (확산모형에 대한 일반화적률추정법의 개선)

  • Choi, Youngsoo;Lee, Yoon-Dong
    • The Korean Journal of Applied Statistics
    • /
    • v.26 no.5
    • /
    • pp.767-783
    • /
    • 2013
  • Generalized Method of Moment(GMM) is a popular estimation method to estimate model parameters in empirical financial studies. GMM is frequently applied to estimate diffusion models that are basic techniques of modern financial engineering. However, recent research showed that GMM had poor properties to estimate the parameters that pertain to the diffusion coefficient in diffusion models. This research corrects the weakness of GMM and suggests alternatives to improve the statistical properties of GMM estimators. In this study, a simulation method is adopted to compare estimation methods. Out of compared alternatives, NGMM-Y, a version of improved GMM that adopts the NLL idea of Shoji and Ozaki (1998), showed the best properties. Especially NGMM-Y estimator is superior to other versions of GMM estimators for the estimation of diffusion coefficient parameters.

A study on the diffusion bonding of the $Al_2$O$_3$ ceramics to metal (A$_2$O$_3$세라믹과 Ni-Cr-Mo鋼과의 인서트 合金을 이용한 擴散接合에 關한 硏究)

  • 김영식;박훈종;김정일
    • Journal of Welding and Joining
    • /
    • v.10 no.3
    • /
    • pp.63-72
    • /
    • 1992
  • The joining methods of ceramics to metals which can be expected to obtain high temperature strength are mainly classified into the solid-state diffusion bonding method and the active brazing method. Between these two, the solid-state diffusion bonding method is given attentions as substituting method for active brazing method due to being capable of obtaining higher bonding strength at high temperature and accurate bonding. In this paper, the solid-state diffusion bonding of $Al_{2}$O$_{3}$ ceramics to Ni-Cr-Mo alloy steel (SNCM21) using insert metal was carried out. The insert metal employed in this study was experimentally home-made, Ag-Cu-Ti alloy. Influence of several bonding parameters of $Al_{2}$O$_{3}$SNCM21 joint was quantitatively evaluated by bonding strength test, and microstructural analyses at the interlayer were performed by SEM/EDX. From above experiments, the optimum bonding condition of the solid-state diffusion bonding of $Al_{2}$O$_{3}$/SNCM21 using Ag-Cu-Ti insert metal was determined. Futhermore, high temperature strength and thermal-shock properties of $Al_{2}$O$_{3}$/SNCM21 joint were also examined. The results obtained are as follows. 1. The maximum bonding strength was obtained at the temperature of 95% melting point of insert metal. 2. The high temperature strength of $Al_{2}$O$_{3}$/SNCM21 joint appeared to bemaximum value at test temperature 500.deg.C and the bonding strength with increasingtemperature showed parabolic curve. 3. The strength of thermal-shocked specimens was far deteriorated than those of as-bonded specimens. Especially, water-quenched specimen after heated up to 600.deg. C was directly fractured in quenching.

  • PDF

Research of the Performance Improvement of a Light Shelf Depending on the Diffusion Film Installation Position (확산필름 부착 위치에 따른 광선반 성능개선 연구)

  • Park, Eunsu;Lee, Heangwoo;Song, Seonkjae;Kim, Yongseong
    • KIEAE Journal
    • /
    • v.17 no.3
    • /
    • pp.91-97
    • /
    • 2017
  • Purpose: Various studies on a light shelf are in progress, but it has the problem of glare occurrence. The present study suggested a diffusion film as the method for resolving the glare problem, and aimed to establish light shelf-related basic data by conducting the performance evaluation of a light shelf depending on the installation position of the diffusion film. Method: To carry out the light shelf performance evaluation depending on the diffusion film installation position, three cases were established: no diffusion film installation (Case 1), diffusion film installation on the reflector (Case 2), and diffusion film installation on the upper glass surface of the window for light shelf installation (Case 3); and the energy reduction performance, luminance, and luminance contrast were analyzed based on a testbed. Result: The conclusions of this study are as follows. 1) When the diffusion film was applied, the amount of light introduced through the light shelf decreased, and the average indoor illumination decreased accordingly. 2) For Case 3, the lighting energy reduction performance was identical to the lighting energy reduction efficiency of the existing light shelf; and for Case 2, it was found to be inappropriate as the lighting energy consumption increased compared to that of the existing light shelf. 3) The analysis of the glare for the cases established in this study showed that the luminance contrast was low for Case 3, and thus the glare problem could be minimized. 4) The specific angle of the light shelf could induce the glare problem by increasing the luminance depending on the external condition. 5) Based on the aforementioned contents, the installation position of the diffusion film for improving the lighting performance and glare problem of the light shelf was found to be the upper glass surface of the window for light shelf installation.