• Title/Summary/Keyword: diffusion law

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A Study on the Characteristics of High Temperature and Mechanisms for Creep Deformation of AZ31 Mg Alloy (AZ31마그네슘 합금의 고온특성 및 크리이프 변형기구에 관한연구)

  • Kang, D.M.;An, J.O.
    • Journal of Power System Engineering
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    • v.9 no.4
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    • pp.96-101
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    • 2005
  • Magnesium alloys have been widely used for many structural components of automobiles and aircraft because of high specific strength and good cast ability in spite of hexagonal closed-packed crystal structure of pure magnesium. In this study, uniaxial tension tests at high temperature and creep tests are done in order to investigate the characteristics of high temperature and mechanisms for creep deformation of AZ31 Mg alloy. Yield stress and ultimate tensile stress decreased with increasing temperature, but elongation increased from results of uniaxial tension test at high temperature. The apparent activation energy Qc, the applied stress exponent n and rupture life have been determined during creep of AZ31 Mg alloy over the temperature range of 473K to 573K and stress range of 23.42 MPa to 93.59 MPa, respectively, in order to investigate the creep behavior. Constant load creep tests were carried out in the equipment including automatic temperature controller, whose data are sent to computer. At around the temperature of $473K{\sim}493K$ and under the stress level of $62.43{\sim}93.59%MPa$, and again at around the temperature of $553K{\sim}573K$ and under the stress level of $23.42{\sim}39.00MPa$, the creep behavior obeyed a simple power-law relating steady state creep rate to applied stress and the activation energy for the creep deformation was nearly equal, respectively, and a little low to that of the self diffusion of Mg alloy including aluminum. Also rupture surfaces at high temperature have had bigger dimples than those at lower temperature by SEM.

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Creep characteristic of Mg alloy at high temperature (고온에서 마그네슘 합금의 크리이프 특성)

  • An, Jung-O;Park, Kyong-Do;Kwak, Jae-Seob;Kang, Dae-Min
    • 한국금형공학회:학술대회논문집
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    • 2008.06a
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    • pp.39-44
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    • 2008
  • Magnesium alloys have given high attention to the industry of light-weigh as automobile and electronics with aluminium, titanium and composite alloys due to their high strength, low specific density and good damping characteristics. But the magnesium contained structures under high temperature have the problems related to creep deformation and rupture life, which is a reason of developing the new material against creep deformation to use them safely. The purpose of this study is to predict the creep deformation mechanism and rupture time of AZ31 magnesium alloy. For this, creep tests of AZ31 magnesium alloy were done under constant creep load and temperature with the equipment including automatic temperature controller with acquisition computer. The apparent activation energy Qc and the applied stress exponent n, rupture life have been determined during creep of AZ31 Mg alloy over the temperature range of $150^{\circ}C$ to $300^{\circ}C$. In order to investigate the creep behavior. Constant load creep tests were carried out in the equipment including automatic temperature controller, whose data are sent to computer. At around the temperature of $150^{\circ}C{\sim}300^{\circ}C$ the creep behavior obeyed a simple power-law relating steady state creep rate to applied stress and the activation energy for the creep deformation was nearly equal and a little low, respectively, to that of the self diffusion of Mg alloy.

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The Sulfidation and Oxidation Behavior of Sputter-Deposited Nb-Al-Cr Alloys at High Temperatures

  • Habazaki, Hiroki;Yokoyama, Kazuki;Konno, Hidetaka
    • Corrosion Science and Technology
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    • v.2 no.3
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    • pp.141-147
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    • 2003
  • Sputter-deposited Nb-Al-Cr alloys. $3-5{\mu}m$ thick, have been prepared on quartz substrates as oxidation-and sulfidation-resistant materials at high temperatures. The oxidation or the alloys in the $Ar-O_2$ atmosphere of an oxygen partial pressure of 20 kPa follows approximately the parabolic rate law, thus being diffusion controlled. Their oxidation rates are almost the same as or even lower than those ofthc typical chromia-forming alloys. The multi-lavered oxide scales are formed on the ternary alloys. The outermost layer is composed of $Cr_2O_3$, which is"mainly responsible for the high oxidation'resistance of these alloys. In contrast to sputter-deposited Cr-Nb binary alloys reported previously, the inner layer is not porous. TEM observation as well as EDX analysis indicates that the innermost layer is a mixture of $Al_2O_3$ and niobium oxide. The dispersion of $Al_2O_3$ in niobium oxide may be attributable to the prevention of the formation of the porous oxide layer. The sulfidation rates of the present ternary alloys arc higher than those of the sputter-deposited Nb-AI binary alloys, but still several orders of magnitude lower than those of conventional high temperature alloys. Two-layered sulfide scales are formed, consisting of an outer $Al_2S_3$ layer containing chromium and an inner layer composed of $NbS_2$ and a small amount of $Cr_2S_3$. The presence of $Cr_2S_3$ in the inner protective $NbS_2$ layer may be attributed to the increase in the sulfidation rates.

Prediction Model of Absorbed Quantity and Diffusivity of Salf in Radish during Salting (무우의 염절임시 소금의 침투량과 확산도 예측모델)

  • 최용희;권태연
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.20 no.6
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    • pp.572-581
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    • 1991
  • For the development of a model to predict absorbed salt quantity in radish during salting, absorbed salt quantity and water content change in radish by the hour were measured at 5%, 10%, 15% brine concentration and $10^{\circ}C,\;20^{\circ}C,\;30^{\circ}C$ respectively. Absorbed salt quantity in radish by the time showed logarithmic function, absorbed salt quantity by brine concentration and temperature showed linear relation. A model to predict absorbed salt quantity in radish at each time, brine concentration and temperature was calculated by the regression program of SPSS. Apparent diffusivity of salt in radish was calculated from appropriated diffusion equation solution of Fick's second law using computer simulation. Salt diffusivity in radish increased as brine concentration increased and the effect of temperature could by expressed by Arrhenius equation. A model equation which could predict salt diffusivity was developed by regression analysis. To specify relation between salt quantity which absorbed into radish and water content which removed out of it, Flux ratio(${\Delta}W/{\Delta}S$) was calcuated. The values showed that the removed water content was greater than the absorbed salt quantity.

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Oxidation Behavior of Ag-Cu-Tio Brazing Alloys (Ag-Cu-Ti 브레이징 합금의 산화거동)

  • 우지호;이동복;장희석;박상환
    • Journal of the Korean Ceramic Society
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    • v.35 no.1
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    • pp.55-65
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    • 1998
  • The oxidation behavior of Ag-36.8a%Cu-7.4at%Ti alloy brazed on Si3N4 substrate was investigated at 400, 500 and 600$^{\circ}C$ in air. Under this experimental condition Si3N4 and Ag were not oxidized whereas Cu and Ti among the brazing alloy components were oxidizied obeying the parabolic oxidation rate law. The activation energy of oxidation was found to be 80kj/ mol which was smaller than that of pure Cu owing to the presence of oxygen active element of Ti. The outer oxide scale formed from the initial oxidation state was always composed of Cu oxides which were known to be growing by the outward diffusion of Cu ions. As the oxidation progressed the concentration gradient occurred due to the continuous consumption of Cu as Cu oxides and consequently build-up of an Ag-enriched layer below the Cu oxides resulted in the formation of multiple oxide scales composed of Cu oxide (CuO) /Ag-enriched layer/Cu oxide (Cu2O) /Ag-enriched layer. Also the inward diffusing of oxygen through Cu oxide and Ag-enriched layers led to the formation of internal oxides of TiO2.

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Diffusion Policy for the Gendered Innovations in Science and Technology Research (과학기술 연구개발에서의 젠더혁신 확산방안 - 성별특성분석 토대의 젠더혁신 지원정책을 중심으로 -)

  • Paik, Hee Young;Woo, Soo-jung;Lee, Heisook
    • Journal of Korea Technology Innovation Society
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    • v.20 no.4
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    • pp.989-1014
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    • 2017
  • Major advanced countries pursuing accountability for research and development are carrying out gendered innovations by recognizing the importance of sex and gender analysis in science research and technology development. Korea needs to actively promote gendered innovations as a strategy moving from Fast Follower to First Mover. In order to promote gendered innovations in the science, technology and ICT fields, policies of integrating the gender dimension in the process of research from research design to the analysis of research outcomes should be declared and research support measures should be introduced from the proposal evaluation for the gendered innovations. In particular, in order to support the new gendered innovations research systematically in Korea's R & D system, a legal basis must precede. In this study, we propose an amendment to the law related to gender innovation by analyzing the cases in foreign countries.

A Linkage Analysis of ISMS-P and GDPR; Focused on Personal Information Protection (ISMS-P와 GDPR의 개인정보보호 부문 연계 분석)

  • Park, Minjung;Yu, Jieun;Chai, Sangmi
    • Journal of Information Technology Services
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    • v.18 no.2
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    • pp.55-73
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    • 2019
  • The importance of the personal information has been increased, there have been a lot of efforts to establish a new policy, certification or law for administrating personal information more effectively and safely. Korean government has operated ISMS and PIMS certification system to assess whether an organization has established and managed appropriate information security system or not. However, it has been addressed the needs for revising and modifying of PIMS and ISMS. It is evaluated there are a few overlapped criteria to assess information management system in both ISMS and PIMS. ISMS-P certification, combining with ISMS and PIMS, is, finally, suggested, in the recent. GDPR is established having an aim of primarily to give control to individuals over their personal data and to simplify the regulatory environment for international business by unifying the regulation within the EU. This study compares GDPR and ISMS-P, focusing on "personal information". It can be expected to contribute as followings. This study can be a criterion for self-evaluation of possibility to violate of GDPR of a firm in preparation for ISMS-P. Second, this study also aims to increase the understanding of the role of ISMS-P and GDPR, among various certifications with the purpose of assessment of the information security management system, by reducing the costs required to obtain the unnecessary certification and alleviating the burden. Third, it contributes to diffusion of ISMS-P newly implemented in Korea.

Review of ESG Challenges in Supply Chain Management Using Text Analysis (ESG 경영시대의 공급망 관리 분야 과제: 텍스트 분석을 활용하여)

  • Rha, Jin Sung
    • Journal of Korea Society of Industrial Information Systems
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    • v.27 no.5
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    • pp.145-156
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    • 2022
  • In recent years, as there is growing concern with ESG (Environmental, Social, and Governance), the strategic direction of business management is changing from maximizing shareholders wealth to maximizing stakeholders value. ESG is reshaping a corporation's supply chain management strategies. The purpose of this study is to explore the ESG challenges in supply chain management. As a result of network text analysis and topic modeling analysis on 3226 news articles, 'Suppliers', 'Sustainability', 'Shared Growth' 'Carbon Neutral', 'Safety and Health', 'Responsible Business Alliance', 'Supply Chain Due Diligence Law' were identified as the main issue. Since ESG initiatives in the supply chain are not limited to the efforts of individual firms, future research should focus on figuring out what difficulties and challenges exist in the diffusion of ESG practices along multi-tiered supply chains, and how to overcome them.

Reliability Analysis of Chloride Ion Penetration based on Level II Method for Marine Concrete Structure (해양 콘크리트 구조물에 대한 Level II 수준에서의 염소이온침투 신뢰성 해석)

  • Han, Sang-Hun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.12 no.6
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    • pp.129-139
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    • 2008
  • Due to uncertainty of numerous variables in durability model, a probalistic approach is increasing. Monte Carlo simulation (Level III method) is an easily accessible method, but requires a lot of repeated operations. This paper evaluated the effectiveness of First Order Second Moment method (Level II method), which is more convenient and time saving method than MCS, to predict the corrosion initiation in harbor concrete structure. Mean Value First Order Second Moment method (MV FOSM) and Advanced First Order Second Moment method (AFOSM) are applied to the error function solution of Fick's second law modeling chloride diffusion. Reliability index and failure probability based on MV FOSM and AFOSM are compared with the results by MCS. The comparison showed that AFOSM and MCS predict the similar reliability index and MV FOSM underestimates the probability of corrosion initiation by chloride attack. Also, the sensitivity of variables in durability model to corrosion initiation probability was evaluated on the basis of AFOSM. The results showed that AFOSM is a simple and efficient method to estimate the probability of corrosion initiation in harbor structures.

Ship's Hull Fouling Management and In-Water Cleaning Techniques (선체부착생물관리와 수중제거기술)

  • Hyun, Bonggil;Jang, Pung-Guk;Shin, Kyoungsoon;Kang, Jung-Hoon;Jang, Min-Chul
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.24 no.6
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    • pp.785-795
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    • 2018
  • The International Maritime Organization (IMO) has recognized the risk of hull fouling and announced '2011 Guidelines for the control and management of ship's biofouling to minimize the transfer of invasive aquatic species'and is planning international regulations to enforce them in the future. In this study, to effectively respond to future international regulation, we introduce the case of leading countries related to management of hull fouling and also investigate environmental risk assessment techniques for in-water cleaning. Australia and New Zealand, the leading countries in hull fouling management, have established hull fouling regulations through biological and chemical risk assessment based on in-water cleaning scenarios. Most European countries without their government regulation have been found to perform in-water cleaning in accordance with the IMO's hull fouling regulations. In the Republic of Korea, there is no domestic law for hull fouling organisms, and only approximately 17 species of marine ecological disturbance organisms, are designated and managed under the Marine Ecosystem Law. Since in-water cleaning is accompanied by diffusion of alien species and release of chemical substances into aquatic environments, results from biological as well as chemical risk assessment are performed separately, and then evaluation of in-water cleaning permission is judged by combining these two results. Biological risk assessment created 40 codes of in-water cleaning scenarios, and calculated Risk Priority Number (RPN) scores based on key factors that affect intrusion of alien species during in-water cleaning. Chemical risk assessment was performed using the MAMPEC (Marine Antifoulant Model to Predict Environmental Concentrations), to determine PEC and PNEC values based on copper concentration released during in-water cleaning. Finally, if the PEC/PNEC ratio is >1, it means that chemical risk is high. Based on the assumption that the R/V EARDO ship performs in-water cleaning at Busan's Gamcheon Port, biological risk was estimated to be low due to the RPN value was <10,000, but the PEC/PNEC ratio was higher than 1, it was evaluated as impossible for in-water cleaning. Therefore, it will be necessary for the Republic of Korea to develop the in-water cleaning technology by referring to the case of leading countries and to establish domestic law of ship's hull fouling management, suitable for domestic harbors.