• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.280-280
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• 2012

We examined ammonia diffusion on the surface of amorphous ice film through the measurement of decreasing residual quantity of $NH_3$ molecules compared to $H_2O$. The populations of $NH_3$ molecules on the surface of amorphous ice were monitored by using the techniques of temperature programmed reactive ion scattering (TPRIS) method. The ratio of intensity between ammonia and water was examined as a function of time at controlled temperature. When ammonia molecules were externally added onto an ice film at a temperature of 80 K, ammonia coverage with regard to ice was 0.12-0.16 ML. The intensity of ammonia molecules on the surface of ice decreased as time increased and the extent of decreased intensity of ammonia increased as controlled temperature increased. Moreover, energy barrier was estimated to be $51kJmol^{-1}$ on amorphous ice film. The results of the experiment indicate that ammonia molecules have a property of vertical diffusion into amorphous ice and the energy barrier of ammonia diffusion into bulk of ice is higher than that of hydrogen bonding.

• 한국컴퓨터산업교육학회:학술대회논문집
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• 한국컴퓨터산업교육학회 2003년도 제4회 종합학술대회 논문집
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• pp.87-94
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• 2003

Anisotropic diffusion is a selective smoothing technique that promotes smoothing within a region instead of smoothing across boundaries. In anisotropic diffusion, the rate of smoothing is controlled by the local value of the diffusion coefficient chosen to be a function of the local image gradient magnitude. El-Fallah and Gary E. Ford represented the image as a surface and proved that setting the inhomogeneous diffusion coefficient equal to the inverse of the magnitude of the surface normal results in surface evolving speed that is proportional to the mean curvature of the image surface. This model has the advantage of having the mean curvature diffusion (MCD) render invariant magnitude, thereby preserving structure and locality. In this paper, the proposed MCD model efficiently reduces diffusion coefficient at the thin edges using the smoothness of the surface.

• Journal of Photoscience
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• 제12권1호
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• pp.41-46
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• 2005

We synthesized chiral choleseric liquid crystalline monomer p-phenylene bis-(p-3-acryloxy-2(S)-methylpropoxy)benzoate (1) and achiral nematic liquid crystalline monomer, p-phenylene p-acryloxy-6-hexyloxy-p-octyloxybenzoate (2) for the construction of cholesteric polymer network with a pitch gradient. In this research we attempted to synthesize cholesteric polymer film which have a wide reflection bandwidth in the region of visible wavelength with the synthesized chiral cholesteric monomer 1 and nematic monomer 2 under various photopoly merization conditions. We succeeded to construct cholesteric polymer film network with a pitch gradient covering more than 200 nm bandwidth in the visible wavelength by diffusion controlled photostructuring method.

• Macromolecular Research
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• 제17권3호
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• pp.168-173
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• 2009

This study reports the preparation and characterization of nanohydrogels by using sodium alginate as a model material. Alginate nanohydrogels (ANH) were prepared by emulsification-diffusion method in a w/o system with 1,2-diacyl-sn-glycero- 3-phosphocholin as the lipophilic surfactant. The effects of the alginate to surfactant ratio and the remaining water contents on the mean particle size and swellability of ANHs were investigated in terms of the concentration, agitation speed, and agitation time. The feasibility of using nanohydrogels and their controllability were proved by the water the absorbency of ANHs during a 7-day evaluation by dynamic light scattering. In this work, the mean particle sizes of ANHs could be controlled from 49.2 nm (measured in ethanol phase) to $1.9{\mu}m$ (measured in water phase, after 7 days of water absorption).

• Computers and Concrete
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• 제3권2_3호
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• pp.103-122
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• 2006

Drying shrinkage of concrete occurs due to the loss of moisture and thus, it is controlled by moisture diffusion process. On the other hand, the shrinkage causes cracking of concrete and affects its moisture diffusion properties. Therefore, moisture diffusion and drying shrinkage are two coupled processes and their interactive effect is important for the durability of concrete structures. In this paper, the two material parameters in the moisture diffusion equation, i.e., the moisture capacity and humidity diffusivity, are modified by two different methods to include the effect of drying shrinkage on the moisture diffusion. The effect of drying shrinkage on the humidity diffusivity is introduced by the scalar damage parameter. The effect of drying shrinkage on the moisture capacity is evaluated by an analytical model based on non-equilibrium thermodynamics and minimum potential energy principle for a two-phase composite. The mechanical part of drying shrinkage is modeled as an elastoplastic damage problem. The coupled problem of moisture diffusion and drying shrinkage is solved using a finite element method. The present model can predict that the drying shrinkage accelerates the moisture diffusion in concrete, and in turn, the accelerated drying process increases the shrinkage strain. The coupling effects are demonstrated by a numerical example.

• 대한기계학회논문집B
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• 제34권7호
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• pp.679-688
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• 2010

본 연구에서는 기존의 역열전달 문제(inverse heat transfer problem)와 같이 역해석(inverse analysis)을 통해 미지의 파라미터를 추정(estimation)하는 개념을 복잡한 연소문제에 도입하였다. 기존의 연구에서는 역해석 기법을 연소문제 자체에 보다는 대부분 연소현상을 동반한 복사열전달과 같은 역열전달 문제에 국한해서 적용하고 있기 때문에, 열전달 문제에 한정되어 사용되고 있는 기존의 역해석을 새로운 공학문제에 확장하여 적용함과 동시에 효율적인 연소기 설계 및 최적화 개념을 제시하는데 본 연구의 의의가 있다고 할 수 있다. 이를 위해 실제적으로 많이 사용하고 있는 축대칭 원통형 연소기 내부로 주입되는 메탄($CH_4$)과 산소($O_2$) 성분의 초기 질량분율 값을 연소기 입구 근방에서 측정한 개스의 온도 데이터를 이용하여 역추정하였다. 이때, 복잡한 확산지배 연소 현상을 효율적으로 역해석하기 위해 최적화 방법 중의 하나인 반발 입자 군집 최적화 방법을 역해석 기법으로 적용하였다.

• 대한금속재료학회지
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• 제46권7호
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• pp.412-419
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• 2008

Creep behavior of the squeeze infiltrated AS52 Mg matrix composites reinforced with 15 vol% of aluminum borate whiskers($Al_{18}B_4O_{33}w$) fabricated squeeze infiltration method was investigated. Microstructure of the composites was observed as uniformly distributed reinforcement in the matrix without any particular defects of casting pores etc.. Creep test was carried out at the temperature of 150 and $200^{\circ}C$ under the applied stress range of 60~120 MPa. The creep resistance of the composite was significantly improved comparing with the unreinforced AS52 Mg alloy. The creep behavior of composites might be interpreted with the substructure invariant model successfully for the composite. Threshold stress of the composite exist for the creep deformation of the composite. The analysis of the creep behavior of the composite with threshold stress indicated that creep deformation was controlled by the lattice diffusion process of AS52 Mg matrix at given effective stresses and temperatures. Activation energy was also calculated to check lattice diffusion controlled creep behavior of the composite.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.252.1-252.1
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• 2013

Hexagonal boron nitride (h-BN) is a two dimensional material which has high band-gap, flatness and inert properties. This properties are used various applications such as dielectric for electronic device, protective coating and ultra violet emitter so on. 1) In this report, we were growing h-BN sheet directly on sapphire 2"wafer. Ammonia borane (H3BNH3) and nickel were deposited on sapphire wafer by evaporate method. We used nickel film as a sub catalyst to make h-BN sheet growth. 2) During annealing process, ammonia borane moved to sapphire surface through the nickel grain boundary. 3) Synthesized h-BN sheet was confirmed by raman spectroscopy (FWHM: ~30cm-1) and layered structure was defined by cross TEM (~10 layer). Also we controlled number of layer by using of different nickel and ammonia borane thickness. This nickel film supported h-BN growth method may propose fully and directly growing on sapphire. And using deposited ammonia borane and nickel films is scalable and controllable the thickness for h-BN layer number controlling.

• Archives of Pharmacal Research
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• 제14권4호
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• pp.298-304
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• 1991

Isoprinosine, an antiviral agent with a bitter taste, has been clinically used up to a maximum of 4 g daily in 4-8 doses. In this investigation, isoprinosine was microencapsulated with ethylcellulose 22 cps, 50 cps and 100 cps by means of polymer deposition from cyclohexane through temperature change. Complete removal of cyclohexane from the microcapsules was necessary, since ethylcellulose-coated microcapsules obtained from cyclohexane medium were heavily solvated with cyclohexane and formed lumps even after drying. The displacement of cyclohexane by n-hexane during isolation of microcapsules (Method III) or the freezing of the anal-washed microcapsules before drying (Mothod II) provided the dried products which were more discrete microcapsules than those which were simply dried in the air overnight (Method I). Method III was especially the most effective procedure in preparing finer and more discrete microcapsules. The drug-release from microcapsules was influenced by the ratio of core to wall, the viscosity grade of ethylcellulose and the overall microcapsule size. The release rate was adequately fitted to both the first-order and the diffusion-controlled processes. It is therefore possible to design the release-controlled microcapsules with ethylcellulose of different viscosity along with various core to wall ratio.

• 한국전기전자재료학회논문지
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• 제20권3호
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• pp.207-212
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• 2007

The concentration profiles of deep energy levels($E_c$ -0.23e V, $E_v$+0.36e V and $E_c$ -0.23e V) in platinum-diffused silicon have generally a sharp gradient in the vicinity of the surface of the silicon wafer. In this work two efficient methods are proposed to obtain the uniform concentration profiles throughout the silicon wafer. One is that the platinum diffusion is carried out at $1000^{\circ}C$ for 1h in oxygen atmosphere. In this case the values of obtained uniform concentration, $1{\times}10^{15}cm^{-3}$ for the $E_c$ -0.23e V level, and 1{\times}10^{14}cm^{-3}$ for the $E_c$ -0.52e V level, are very restricted, respectively. The other is two-step annealing process. The platinum diffusion is carried out at $850{\sim}1100^{\circ}C$ in a nitrogen ambient for 1h and then the annealing is performed at $1000^{\circ}C$ in oxygen ambient after removing platinum-source from the platinum diffused samples. The advantage of this method is that the uniform concentration of these levels required power devices can be controlled by setting the desired temperatures when the platinum diffusion is carried out in nitrogen ambient.