• Title/Summary/Keyword: diffusion coefficient(D)

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Measurement of Diffusion Coefficient in Cell-Laden Agarose Gel with Different Cell Concentrations (아가로스 겔에 포함된 세포의 농도가 확산 계수에 미치는 영향 측정)

  • Lee, Byung Ryong;Jin, Songwan
    • Journal of the Korean Society of Visualization
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    • v.11 no.1
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    • pp.16-21
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    • 2013
  • In this study, diffusion coefficients of 20 kDa FITC-dextran in 2% agarose gel with different cell concentrations were measured using fiberoptic-based fluorescence recovery after photobleaching technique. As increasing cell concentration suspended in agarose gel, the diffusion coefficients were decreased. The diffusion coefficient of agarose gel which contains $10{\times}10^6$ cells/ml was decreased to 11% that of in agarose gel without cells. The distribution of fluorescence dye in 3D scaffold was also simulated. The simulation result shows that the diffusion coefficient is more significant factor than the scaffold structure.

3D Sound Diffusion Control Using Wavelets (웨이블릿을 이용한 입체음향의 확산감 제어)

  • 김익형;정의필
    • Journal of the Institute of Convergence Signal Processing
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    • v.4 no.4
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    • pp.23-29
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    • 2003
  • In this paper, we propose an idea for the improved 3-D sound system using conventional stereo headphones to obtain a better sound diffusion from the mono-sound recorded at an anechoic chamber. We use the HRTF(Head Related Transfer Function) for the sound localization and the wavelet filter bank with time delay for the sound diffusion. And we test the modified HRTF with the various sampling rate. We investigate the effects of the 3-D sound depending on the length of time delay at lowest frequency band. Also the correlation coefficient of the signals between the left channel and the right channel is measured to identify the sound diffusion. At last we obtain the diffusion sound using Cool Edit for reverberation.

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Design of diffusers in consideration of scattering and diffusion characteristics (확산 지향성을 고려한 확산체의 설계)

  • Kim, Yong-Hee;Kim, Jae-Ho;Kim, Jeong-Jun;Jeon, Jin-Yong
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2008.04a
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    • pp.21-24
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    • 2008
  • This study proposes a optimized shape of diffuser profile through investigating the scattering and diffusion characteristics of diffusers. The scattering coefficient according to ISO 17497-1 evaluates uniformity of reverberant sound field of late reflections, while the diffusion coefficient according to AES-4id-2001 evaluates polar response of early reflections. Thus both scattering and diffusion characteristics should contribute to design shape of diffusers to maximize physical performance. To find out design method, the previous results on hemisphere diffusers are reviewed. The frequency characteristics of scattering coefficients depended on the structural height of the diffusers, while amount of scattering coefficients depended on the surface coverage density of the diffusers. However absorptive properties also increased with augment of surface coverage density, thus optimum coverage density should be considered. For the directional diffuser, three types of 2D-diffusers are proposed; semicylinder of h=5mm, semi-truncated cone of h=5-25mm and semicylinder of h=25mm. As results, diffusers with the maximum height of 25mm show the highest scattering coefficients, while diffuser of h=5mm shows high scattering coefficients only at the high-frequency bands. Diffusion coefficient will be investigated for diffusive properties of the early reflection.

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Absorption of d-Limonene in Orange Juice into a Laminated Food Package Studied with a Solid Phase Micro-extraction Method

  • Lee, Hahn-Bit;Yang, Hee-Jae;Min, Sea-C.
    • Food Engineering Progress
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    • v.14 no.4
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    • pp.354-358
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    • 2010
  • The methods for determining the diffusion parameters for the diffusion of d-limonene, a major volatile compound of orange juice, through a multi-layered food packaging material and predicting its absorption into the packaging material have been investigated. The packaging material used was the 1.5-mm thick multi-layered packaging material composed of high impact polystyrene (HIPS), polyvinylidene chloride (PVDC), and low density polyethylene (LDPE). Orange juice was placed in a cell where volatiles were absorbed in the sample package and kept at $23{\pm}2^{\circ}C$ for 72 hr. The d-limonene absorbed in a 1.5-mm thick multi-layered food packaging material was analyzed by a solid phase micro-extraction (SPME). The absorption parameters for the absorption of d-limonene in the packaging material were determined and absorption of d-limonene into the packaging material was predicted using absorption storage data. The SPME desorption at $60^{\circ}C$ for 1 hr resulted in the most sensitive and reproducible results. The diffusion coefficients of d-limonene in the packaging material and the partition coefficient at $23{\pm}2^{\circ}C$ were approximately $1-2{\times}10^{12}m^2$/s and 0.03, respectively. The absorption profile no earlier than 30 hr was fit well by a model derived from the Fick's law.

A study on the stress dependence of diffusion coefficient at the elevated tenperature and the structural characterictics of 12% Cr rotor steel. (12% Cr강의 고온 확산계수의 응력의존성과 조직의 특성에 관한 연구)

  • 장윤석;김태형
    • Journal of Ocean Engineering and Technology
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    • v.11 no.2
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    • pp.39-47
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    • 1997
  • Creep rate the elevated temperature is known to be controller by the softening process of microstructure especially in the solid solution alloys such as 125 Cr rotor steel. The change of structure is a decreasing process of the free energy of the state including stress, diffusivity of the material, and tmeperature. This study shows that diffusion coefficient, D of 12% Cr rotor steel at 953K with 74.8 MPa is 1.084~3.140*$10^{15}mm^2sec^1$ compared to $1.658*10^{24}mm^2sec^1$at 963K without stress. During creep, the growth of martensite laths accelerates the diffusion coefficient under stress due to incoherency of interface between carbides and matrix.

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The Determination of Diffusion and Partition Coefficients of Indoor Bottom Finishing Materials (바닥재의 확산계수 및 분배계수 산정)

  • Park, Jin-Soo;Little, John C.;Kim, Shin-Do;Yun, Joong-Seop
    • Journal of Environmental Health Sciences
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    • v.34 no.3
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    • pp.219-225
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    • 2008
  • Many building materials may contain high concentrations of volatile organic compounds (VOCs) and other hazardous pollutants(HAPs). Specifically, VOCs discharged by indoor building material may cause "new house" syndrome, atopic dermatitis etc. The diffusion coefficient and initially contained total VOC quantity were determined using microbalance experiments and small chamber tests. Interactions between volatile organic compounds (VOCs) and vinyl flooring (VF), a relatively homogenous, diffusion-controlled building material, were characterized. Rapid determination of the material/air partition coefficient (K) and the material-phase diffusion coefficient (D) for each VOC was achieved by placing thin VF slabs in a dynamic microbalance and subjecting them to controlled sorption/desorption cycles. K and D are shown to be independent of concentration for all of the VOCs and water vapor. This approach can be applied to other diffusion-controlled materials and should facilitate the prediction of their source/sink behavior using physically-based models.

Comparison study of turbulent diffusion coefficient using Smagorinsky method and 2-level method (Smagorinsky method와 2-level method를 이용한 난류 확산계수의 비교 연구)

  • 이화운;오은주;정우식;최현정;임주연
    • Journal of Environmental Science International
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    • v.11 no.7
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    • pp.679-686
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    • 2002
  • Turbulence greatly influence on atmospheric flow field. In the atmosphere, turbulence is represented as turbulent diffusion coefficients. To estimate turbulent diffusion coefficients in previous studies, it has been used constants or 2-level method which divides surface layer and Ekman layer. In this study, it was introduced Smagorinsky method which estimates turbulent diffusion coefficient not to divide the layer but to continue in vertical direction. We simulated 3-D flow model and TKE equation applied turbulent diffusion coefficients using two methods, respectively. Then we showed the values of TKE and the condition of each term to TKE. The results of Smagorinsky method were reasonable. But the results of 2-level method were not reasonable. Therefor, it had better use Smagorinsky method to estimate turbulent diffusion coefficients. We are expected that if it is developed better TKE equation and model with study of computational method in several turbulent diffusion coefficients for reasonably turbulent diffusion, we will able to predict precise wind field and movements of air pollutants.

Modeling on Chloride Diffusivity in Concrete with Isotropic and Anisotropic Crack (등방성 및 이방성 균열을 가진 콘크리트의 염화물 확산계수 모델링)

  • Lee, Hack-Soo;Bae, Sang-Woon;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.6
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    • pp.104-111
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    • 2013
  • Deterioration is accelerated due to additional intrusion of chloride ion in crack width in cracked concrete. In this paper, modeling on equivalent diffusion coefficient in cracked concrete is performed for 1-D (Anisotropic) and 2-D (Isotropic) diffusion based on steady state condition. In the previous research, rectangular shape of crack was considered but the shape was modified to wedge shape with torturity. For verification of the proposed model, crack is induced in concrete sample and migration test in steady state is performed for 1-D diffusion. For 2-D diffusion, previous test results are adopted for verification. Through considering wedge shape of crack with torturity, diffusion coefficients in 1-D and 2-D diffusion are reduced, and the more reasonable prediction is obtained. The results from the proposed model with torturity of 0.10~0.15 are shown to be in the best agreement with the test results.

Determination of Oxygen Diffusion Coefficient from Vaporization Rate of MgO.$nAl_2O_3$ Spinel (MgO.$nAl_2O_3$ 스피넬에 대한 증발속도의 측정으로부터 산소의 확산계수의 결정)

  • 이홍림;배철훈
    • Journal of the Korean Ceramic Society
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    • v.20 no.2
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    • pp.129-134
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    • 1983
  • MgO.$Al_2O_3$ polycrstalline spinel powder was subjected to vaporization over the temperature range of 1150-130$0^{\circ}C$ under H2 atmosphere. Diffusion coefficient of oxygen ion through the spinel were calculated using the measure vaporization rates as follows : D=28.4 exp(-901500/RT) Reference data of the vaporization rates of MgO.$8Al_2O_3$ single crystal spinel were applied to the vaporiza-tion model proposed in this study and were calculated to give the oxygen ion diffusion coefficients over the tempera-ture 1700-195$0^{\circ}C$. The obtained diffusion coefficients are as follows: $D=3.20{\times}106$ exp(-155600/RT)

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FLUORESCENCE QUENCHING OF BBOT BY ANILINE IN DIFFERENT ORGANIC SOLVENTS

  • Kadadevarmath, J.S.;Giraddi, T.P.;Chikkur, G.C.
    • Journal of Photoscience
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    • v.4 no.3
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    • pp.105-112
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    • 1997
  • The fluorescence quenching of 2, 5-di-(5-tert-butyl-2-benzoxazolyl)-thiophene (BBOT) by aniline in five different solvents namely heptane, hexane, cyclohexane, dioxane and acetonitrile has been carried out at room temperature with a view to understand the quenching mechanisms. The experimental results show positive deviation in the Stern-Volmer plots in all the solvents. In order to interpret these results we have invoked the Ground state complex and sphere of action static quenching models. Using these models various rate parameters have been determined. The magnitudes of these parameters suggest that sphere of action static quenching model agrees well with the experimental results. Hence this positive deviation is attributed to the static and dynamic quenching. Further, with the use of Finite Sink approximation model, it was possible to check these bimolecular reactions as diffusion-limited and to estimate independently distance parameter R$^1$ and mutual diffusion coefficient D. Finally an attempt has been made to correlate the values of R$^1$ and D with the values of the encounter distance R and the mutual diffusion coefficient D determined using the Edward's empirical relation and Stokes-Einstein relation.

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