• Title/Summary/Keyword: differential conductivity

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INFLUENCE OF THERMAL CONDUCTIVITY AND VARIABLE VISCOSITY ON THE FLOW OF A MICROPOLAR FLUID PAST A CONTINUOUSLY MOVING PLATE WITH SUCTION OR INJECTION

  • Salem, A.M.;Odda, S.N.
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.9 no.2
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    • pp.45-53
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    • 2005
  • This paper investigates the influence of thermal conductivity and variable viscosity on the problem of micropolar fluid in the presence of suction or injection. The fluid viscosity is assumed to vary as an exponential function of temperature and the thermal conductivity is assumed to vary as a linear function of temperature. The governing fundamental equations are approximated by a system of nonlinear ordinary differential equations and are solved numerically by using shooting method. Numerical results are presented for the distribution of velocity, microrotation and temperature profiles within the boundary layer. Results for the details of the velocity, angular velocity and temperature fields as well as the friction coefficient, couple stress and heat transfer rate have been presented.

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Synthesis and Properties of New Proton-Conducting Polyacrylate (새로운 양성자 전도성 폴리아크릴막의 합성 및 특성 분석)

  • Yun Jong Bok;Kim Hye Kyong;Jo Ju Hui;Wegner Gerhard;Jang Hyeok
    • 한국전기화학회:학술대회논문집
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    • 2001.06a
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    • pp.189-192
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    • 2001
  • In order to prepare the proton-conducting membrane with lower cost and higher ionic conductivity than commercialized one, the concept of incorporating the nitrogen acid to polymer backbone, is proposed. The synthesis, thermal, and temperature-variable impedance/electrical conductivity studies of poly (p-tolunesulfonylamido acrylate) are reported. This polymer can be prepared by reacting poly (acryloyl chloride) with ptolunesulfonamide and cast into homogeneous membranes. Thermogravimetric analysis (TGA) shows that the polymer is thermally stable up to about $200^{\circ}C$ and Differential scanning calorimetry (DSC) illustrates that the glass transition occur at around $67^{\circ}C$. The ionic conductivity measured by dielectric spectroscopy is in the range of $10^{-5}\;S/cm$ in dry atmosphere that it can be a candidate for the membrane of PEMFC or DMFC.

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Effects of Thermal-Carrier Heat Conduction upon the Carrier Transport and the Drain Current Characteristics of Submicron GaAs MESFETs

  • Jyegal, Jang
    • Proceedings of the Korea Society for Industrial Systems Conference
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    • 1997.11a
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    • pp.451-462
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    • 1997
  • A 2-dimensional numerical analysis is presented for thermal-electron heat conduction effects upon the electron transport and the drain current-voltage characteristics of submicron GaAs MESFETs, based on the use of a nonstationary hydrodynamic transport model. It is shown that for submicron GaAs MESFETs, electron heat conduction effects are significant on their internal electronic properties and also drain current-voltage characteristics. Due to electron heat conduction effects, the electron energy is greatly one-djmensionalized over the entire device region. Also, the drain current decreases continuously with increasing thermal conductivity in the saturation region of large drain voltages above 1 V. However, the opposite trend is observed in the linear region of small drain voltages below 1 V. Accordingly, for a large thermal conductivity, negative differential resistance drain current characteristics are observed with a pronounced peak of current at the drain voltage of 1 V. On the contrary, for zero thermal conductivity, a Gunn oscillation characteristic is observed at drain voltages above 2 V under a zero gate bias condition.

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Dielectric Changes During the Curing of Epoxy Resin Based on the Diglcidyl Ether of Bisphenol A (DGEBA) with Diamine

  • 김홍경;차국헌
    • Bulletin of the Korean Chemical Society
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    • v.20 no.11
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    • pp.1329-1334
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    • 1999
  • The curing characteristics of diglycidyl ether of bisphenol A (DGEBA) with diaminodiphenylmethane (DDM) as a curing agent were studied using differential scanning calorimetry (DSC), rheometrics mechanical spectrometry (RMS), and dielectric analysis (DEA). The isothermal curing kinetics measured by DSC were well represented with the generalized auto-catalytic reaction model. With the temperature sweep, the inverse relationship between complex viscosity measured by RMS and ionic conductivity obtained from DEA was established indicating that the mobility of free ions represented by the ionic conductivity in DEA measurement and the chain segment motion as revealed by the complex viscosity measured from RMS are equivalent. From isothermal curing measurements at several different temperatures, the ionic conductivity contribution was shown to be dominant in the dielectric loss factor at the early stage of cure. The contribution of the dipole relaxation in dielectric loss factor became larger as the curing further proceeded. The critical degrees of cure, at which the dipolar contribution in the dielectric loss factor starts to appear, increases as isothermal curing temperature is increased. The dielectric relaxation time at the same degree of cure was shorter for a sample cured at higher curing temperature.

Modification of Strain-dependent Hydraulic Conductivity with RMR (RMR에 따른 변형률 의존 수리전도도 변화 해석)

  • 윤용균
    • Tunnel and Underground Space
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    • v.13 no.1
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    • pp.44-51
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    • 2003
  • Changes of the hydraulic conductivity resulting from the redistribution of stresses by underground excavation are examined using the strain-dependent hydraulic conductivity modification relation, where the modulus reduction ratio and induced strain are the major parameters. The modulus reduction ratio is defined in terms of RMR(Rock Mass Rating) to represent the full gamut of rock mass condition. Though shear dilation has the effect on the modification of hydraulic conductivity, the extent of it depends on RMR When the extensional strain is applied to a fracture, the hydraulic conductivity increases with the decrease of RMR Loading configuration has the effect on the modification of hydraulic conductivity, where the differential stress mode with a magnitude of the minimum principal stress $($\sigma$_x)$ fixed and a magnitude of the maximum principal stress $($\sigma$_y)$ varied is found to exert the greatest effect on the change of hydraulic conductivity.

Specific Heat and Thermal Conductivity of XLPE Insulator and Semiconductive Materials for 154kV Power Cable (154kV 전력케이블용 XLPE 절연체와 반도전 재료의 비열 및 열전도)

  • Lee, Kyoung-Yong;Yang, Jong-Seok;Choi, Yong-Sung;Park, Dae-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.05b
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    • pp.19-24
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    • 2005
  • To improve mean-life and reliability of power cable, we have investigated specific heat (Cp) and thermal conductivity of XLPE insulator and semiconductive materials in 154kV underground power transmission cable. Specimens were respectively made of sheet form with EVA, EEA and EBA added 30wt%, carbon black, and the other was made of sheet form by cutting XLPE insulator in 154kV power cable. Specific heat (Cp) and thermal conductivity were· measured by DSC (Differential Scanning Calorimetry) and Nano Flash Diffusivity. Specific-heat measurement temperature ranges of XLPE insulator were from 20[$^{\circ}C$] to 90[$^{\circ}C$], and the heating rate was 1[$^{\circ}C$/min]. And the measurement temperatures of thermal conductivity were 25[$^{\circ}C$}], 55[$^{\circ}C$] and 90[$^{\circ}C$]. In case of semiconductive materials, the measurement temperature ranges of specific heat were from 20[$^{\circ}C$] to 60[$^{\circ}C$], and the heating rate was 1[$^{\circ}C$/min]. And the measurement temperatures of thermal conductivity were 25[$^{\circ}C$] and 55[$^{\circ}C$]. From these experimental results, both specific heat and thermal conductivity were increased by heating rate because volume of materials was expanded according to rise in temperature.

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Specific Heat and Thermal Conductivity Measurement of XLPE Insulator and Semiconducting Materials (XLPE 절연층과 반도전층 재료의 비열 및 열전도 측정)

  • Lee Kyoung-Yong;Yang Jong-Seok;Choi Yong-Sung;Park Dae-Hee
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.1
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    • pp.6-10
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    • 2006
  • To improve mean-life and reliability of power cable, we have investigated specific heat (Cp) and thermal conductivity of XLPE insulator and semiconducting materials in 154(kV) underground power transmission cable. Specimens were respectively made of sheet form with EVA, EEA and EBA added $30[wt\%],$ carbon black, and the other was made of sheet form by cutting XLPE insulator in 154(kV) power cable. Specific heat (Cp) and thermal conductivity were measured by DSC (Differential Scanning Calorimetry) and Nano Flash Diffusivity. Specific-heat measurement temperature ranges of XLPE insulator were from $20[^{\circ}C]\;to\;90[^{\circ}C],$ and the heating rate was $1[^{\circ}C/mon].$ And the measurement temperatures of thermal conductivity were $25[^{\circ}C],\;55[^{\circ}C]\;and\;90[^{\circ}C].$ In case of semiconducting materials, the measurement temperature ranges of specific heat were from $20[^{\circ}C]\;to\;60[^{\circ}C],$ and the heating rate was $1[^{\circ}C/mon].$ And the measurement temperatures of thermal conductivity were $25[^{\circ}C],\;55[^{\circ}C].$ In addition we measured matrix of semiconducting materials to show formation and growth of carbon black in base resins through the SEM. From these experimental results, both specific heat and thermal conductivity were increased by heating rate because volume of materials was expanded according to rise in temperature.

Lithium Ion Concentration Dependant Ionic Conductivity and Thermal Properties in Solid Poly(PEGMA-co-acrylonitrile) Electrolytes

  • Kim, Kyung-Chan;Roh, Sae-Weon;Ryu, Sang-Woog
    • Journal of Electrochemical Science and Technology
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    • v.1 no.1
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    • pp.57-62
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    • 2010
  • The lithium ion concentration dependant ionic conductivity and thermal properties of poly(ethylene glycol) methyl ether methacrylate (PEGMA)/acrylonitrile-based copolymer electrolytes with $LiClO_4$ have been studied by differential scanning calorimetry (DSC), linear sweep voltammetry (LSV) and AC complex impedance measurements. In systems with 11 wt% of acrylonitrile all liquid electrolytes were obtained regardless of lithium ion concentration. Complex impedance measurements with stainless steel electrodes give ambient ionic conductivities $8.1\times10^{-6}\sim1.4\times10^{-4}S cm^{-1}$. On the other hand, a hard and soft films at ambient temperature were obtained in copolymer electrolyte system consists of 15 wt% acrylonitrile with 6 : 1 and 3 : 1 of [EO] : [Li] ratio, respectively. DSC measurements indicate the crystalline melting temperature of poly(PEGMA) disappeared completely after addition of $LiClO_4$ in this system due to the complex formation between ethylene oxide (EO) unit and lithium salt. As a result, free standing film with room temperature ionic conductivity of $1.7\times10^{-4}S cm^{-1}$ and high electrochemical stability up to 5.5V was obtained by controlling of acrylonitrile and lithium salt concentration.

Volume Resistivity, Specific Heat and Thermal Conductive Properties of the Semiconductive Shield in Power Cables

  • Lee Kyoung-Yong;Choi Yong-Sung;Park Dae-Hee
    • KIEE International Transactions on Electrophysics and Applications
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    • v.5C no.3
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    • pp.89-96
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    • 2005
  • To improve the mean-life and reliability of power cables, we have investigated the volume resistivity and thermal properties demonstrated by changing the content of carbon black, an additive of the semiconductive shield for underground power transmission. Nine specimens were made of sheet form for measurement. Volume resistivity of the specimens was measured by a volume resistivity meter after 10 minutes in a preheated oven at temperatures of both 25$\pm$1[$^{\circ}C$] and 90$\pm$ 1[$^{\circ}C$]. As well, specific heat (Cp) and thermal conductivity were measured by Nano Flash Diffusivity and DSC (Differential Scanning Calorimetry). The ranges of measurement temperature were from 0[$^{\circ}C$] to 200[$^{\circ}C$], and heating temperature was 4[$^{\circ}C$/min]. From these experimental results, volume resistivity was high according to an increase of the content of carbon black. Specific heat was decreased, while thermal conductivity was increased according to a rise in the content of carbon black. Furthermore, both specific heat and thermal conductivity were increased by heating temperature because the volume of materials was expanded according to a rise in temperature.

Development of Highly Thermal Conductive Liquid Crystalline Epoxy Resins Bearing Phenylcyclohexyl Mesogenic Moieties (Phenylcyclohexyl mesogenic moieties를 함유한 고 열전도성 액정성 에폭시 수지의 개발)

  • Jeong, Iseul;Kim, Youngsu;Goh, Munju
    • Composites Research
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    • v.30 no.6
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    • pp.350-355
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    • 2017
  • The new liquid crystalline (LC) epoxy was designed by substituting the phenylcyclohexyl (PCH) mesogen moiety with an alkyl chain at the 2,5 position of the diglycidyl terephthalate. The mesomorphic properties were evaluated by differential scanning calorimetry (DSC) and polarized optical microscopy (POM). All LC epoxy derivatives exhibited an enantiotropic smectic phase upon heating and cooling process. The LC phase temperature range was widened by mixing the eutectic mixture of LC epoxies. Interestingly, the cured LC epoxy exhibited the highest thermal conductivity of $0.4W{\cdot}m^{-1}{\cdot}K^{-1}$. The novel LC epoxy with high thermal conductivity might be used as a composite material for electronic and display devices.