• Title/Summary/Keyword: diester

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Dyeing Properties of Polyurethane Fiber by Novel Phthalimidyl Azo Disperse Dyes (Phthalimide계 신규 Azo dye의 Polyurethane계 섬유 염색 특성)

  • Choi, Jong-Yun;Choi, Jae-Hong
    • Textile Coloration and Finishing
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    • v.21 no.6
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    • pp.46-55
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    • 2009
  • Some phthalimidyl azo dyes containing N,N-diethyl or N,N-di($\beta$-methoxycarbonylethyl) group have been attempted to apply onto two kinds of polyurethane based materials and rationalize their dyeability and fastness comparing with those of some commercial disperse dyes. Phthalimidyl azo dye showed 66~98% of exhaustion yield at $120^{\circ}C$ by a conventional exhaust dyeing method. The dyeings were found to have a higher wash fastness with both fabrics in comparison with those of commercial dyes which indicates lower thermomigration and efficient alkali clearable properties of phthalimidyl ring and/or diester group during post-dyeing process.

카로티노이드 $^1O_2$ 퀜칭효과

  • 박수남;이태영
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.10 no.1
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    • pp.75-89
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    • 1984
  • $^1O_2$ quenching abilities of several carotenoids which contain hydroxy, carbonyl and ester groups were compared quantitatively with $\beta$-carotene, and the capacity of the quenching was interpreted in the light of electronic effects. The rate constans of $^1O_2$ quenching of lutein diester and astaxanthin diester in MeOH solution were shown to be $1.9\times10^{10}M^{-1}Sec^{-1}$, $2.3\times10^{10}M^{-1}Sec^{-1}$ respectively. Under the experimental conditions, and within the carotenoid tested results, the larger the resonance energy is, the larger becomes the rate constant and consequently the lower the transition energy is, the better becomes the quencher.

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Metabolism of Dietary Carotenoids and Effects to Intensify the Body Color of Cultured Sea bass (양식 농어의 Carotenoids 대사와 체색선명화에 미치는 영향)

  • KANG Dong-Soo;HA Bong-Seuk
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.27 no.3
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    • pp.272-281
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    • 1994
  • To investigate the effects on pigmentation and carotenoids metabolism of sea bass, Lateolablax japonicus, by supplemented carotenoids, fish were fed the diets each containing ${\beta}$-carotene, lutein ester, astaxanthin, astaxanthin monoester and astaxanthin diester for 8 weeks. Carotenoids in the integuments were analyzed. The important carotenoids in the integuments of sea bass were tunaxanthin and lutein. ${\beta}$-carotene, ${\beta}$-cryptoxanthin, zeaxanthin and ${\beta}$-carotene triol were minor contributors. Differences in the content of ${\beta}$-carotene, tunaxanthin fraction and lutein were observed between the natural and cultured sea bass. The wild sea bass contained higher amounts of tunaxanthin fraction and lutein, but contained lower amounts of ${\beta}$-carotene than cultured sea bass. In cultured sea bass with supplemented carotenoids, carotenoid deposition was higher in order of astaxanthin monoester group, astaxanthin group and astaxanthin diester group. Based on the contents and composition of carotenoids in each group after the feeding the experimental diet, The metabolism of carotenoid in sea bass was presumed to be the reductive metabolic pathways: astaxanthin to tunaxanthin via ${\beta}$-carotene triol, zeaxanthin and lutein.

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Synlube 제조에 관한 연구(II)

  • 김종호
    • Tribology and Lubricants
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    • v.6 no.1
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    • pp.7-16
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    • 1990
  • 본 보에서는 지난호(윤활학회지 Vol.5, No.2 1989. 10)에 이어 synlube 중 ester oil의 제조 및 합성유와 광유와의 물성 비교 결과를 요약하여 기술하였다. 천연 ester oil인 동,식물유가 윤활유로 사용된 역사는 기원전 1600년경 부터이다. 그러나 ester계 합성유는 저온성상 및 윤활성을 향상시킬 목적으로 2차대전 중 독일과 미국에서 연구를 시작하여 1947년 영국에서 diester oil을 turbo-prop 엔진으로 사용하기 시작하였다.

테레프탈산을 이용한 diester기 함유 분산염료의 합성

  • 서연경;박종호;박은진;김성동
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.10a
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    • pp.191-194
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    • 1998
  • Diester형 분산염료란 염료 분자 구조 중에 diester기를 함유하고 있어 염색은 일반 분산염료와 동일하게 수행하고, 염색 후 묽은 알칼리 용액으로 처리하면 섬유 표면에 존재하는 미고착 염료들의 ester기가 가수분해되어 sodium carboxylate가 생성되면서 염료가 수용성으로 변하여 쉽게 제거되는 성질을 가진 염료를 말한다. (중략)

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Critical Micelle Concentration of Sucrose Monostearate (모노스테아르산설탕의 Critical Micelle Concentration)

  • Noh Jang Sook;Lee Kwang Soon;Chang Sae Hee;Ahn Woon-Sun
    • Journal of the Korean Chemical Society
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    • v.18 no.5
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    • pp.354-357
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    • 1974
  • The critical micelle concentration(CMC) of sucrose monostearate is determined between 20 and $40^{\circ}C$, and the effect caused by the addition of sucrose distearate on the CMC is also studied. It is found that, when both of monoester and diester are dissolved, the curve of surface tension of the solution versus the concentration shows a discontinuity at about 40 dyne $cm^{-1}$ of the surface tension. The discontinuity is interpreted as the associate formed between monoester and diester changes its surface orientation at this region.

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Synthesis of Biodegradable Aliphatic Polyester with Amino Group in the Side Chain (곁사슬에 아미노기를 도입한 생분해성 지방족 폴리에스테르의 합성)

  • Lee, Chan-Woo
    • Polymer(Korea)
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    • v.34 no.4
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    • pp.381-385
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    • 2010
  • Aiphatic diester monomer, 3-[(benzyloxycarbonylamino)butyl]-1,4-dioxane-2,5-dione (BABD), was synthesized with the N-$\varepsilon$-benzyloxy-carbonyl-L-lysine as starting material. This monomer was synthesized to add the functionality to poly(lactic acid)s. BABD unit was successfully incorporated into the PLLA chain which was confirmed by $^1H$ NMR. The copolymer composition could be controlled by the feed ratios of monomer. The $M_n$ of this resultant polymer is expected to reach high molecular weight after the purification of monomer and optimization of polymerization time, though the polymer showed relatively low degree of polymerization ($M_n$=3300). The copolymer is expected to possess the enhanced hydrophilicity and the possibility of chemical modification on amino group.

Structural Elucidation of Carotenoids in Penaeus orientalis Shells (Penaeus orientalis 껍질로부터 분리 정제한 Carotenoids의 구조 결정)

  • 김재웅;김동희;이서구
    • The Korean Journal of Food And Nutrition
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    • v.13 no.3
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    • pp.269-272
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    • 2000
  • Penaeus orientalis 껍질에서 6종류의 carotenoids가 분리정제되었다. $\beta$-carotene(3.1%), doradexanhinester(6.1%), astaxanthin diester(54.8%), zeaxan-thin monoester(7.9%), astaxanthin monoester(12.4%) 그리고 astaxanthin(5.7%)의 함량과 구조들은 UV/VIS.IR $^1$H0NMR. MS 스펙트라와 검화반응, 아세탈화반응, 알릴릭그룹,에폭시 반응 그리고 환원반응을이용하여 결정되었다. Carotenoids와 에스테르 결합된 지방산들은 주로 $C_{18:1}$, $C_{16:0}$, $C_{16:1}$ 이고 나머지 지방산들도 소량 함유되었다.되었다.

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Investigation of Phosphorus Species in Marine Sediment (해저 퇴적물에 함유된 인의 존재 형태에 대한 연구)

  • 김영규
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.2
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    • pp.151-159
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    • 2003
  • $^{31}$ /P NMR and XRD have been used to study the mineralogical compositions and the phosphorus species in marine sediments near Wolsung nuclear power plant. The core samples with 30cm depth were investigated and no mineralogical changes have been found. The studied marine sediments were composed of quartz, albite, microcline, calcite, and some clay minerals such as illite, smectite, chlorite, and kaolinite. Only orthophosphate-monoester and very small amount of ortho-phosphate-diester were identified as phosphorus species in the studied sample, different from the species reported in other countries. These phosphorus species are mainly from organisms and was exposed to the oxic conditions. The consistent mineralogical compositions as well as the same phosphorus species throughout the entire core samples indicate that the constant oxic condition was kept without any changes in sedimentary conditions or the sediments were deposited with different sedimentary conditions, but later they were disturbed by other activities and exposed to the surface oxic conditions continuously.