• Journal of Microbiology and Biotechnology
• /
• v.8 no.6
• /
• pp.656-662
• /
• 1998

To make a distinction between the influence of the dielectric constant and of methanol concentration on trypsin-catalyzed hydrolysis and methanolysis at $0^{\circ}C$, a model reaction of $N^u$-benzyloxycarbonyl-L-lysine p-nitrophenyl ester with water-methanol mixtures was chosen and a kinetic study done. The $k_{cat}$ values increased with methanol concentration, in a linear manner whereas $K_{M}$ values increased in a log-linear fashion. However, the $k_{cat},$_{M}$ ratio increased at lower methanol concentrations than 30% and then began to decrease at higher concentrations. The decrease in $k_{catK_M}$observed at higher than 30% methanol concentrations is attributed to the hydrophobic partitioning effect on substrate binding. On the other hand, the increase in $k_{catK_M}$ in the 0~30% methanol concentration range seems to be due to the effect of nucleophilic cosolvent on $k_{cat}$ and of the dielectric constant on $k_m$. This explanation was verified by measuring the effect of varying the dielectric constant of the medium on kinetic constants with isopropyl alcohol chemically unrelated to the enzyme reaction as the methanol concentration is maintained at a constant level. Therefore, we conclude that the effect of increasing the methanol concentration in the model reaction on the kinetic parameters $k_{cat \;and\;{K_M}}$ is caused by changes in both the nucleophilicity and the dielectric constant of the medium. Based on product analysis, the increase in $k_4, k_3$by decreasing the temperature can be accounted for by the suppression of hydrolytic reactions. This observation indicates that the nucleophile is favored by low temperatures. There was no loss of trypsin activity over a 10 h period in 60% methanol concentration at $pH^＊\; 5.5,\; 0^{\circ}C$.EX>.

• Journal of the Korean Institute of Telematics and Electronics
• /
• v.19 no.3
• /
• pp.13-18
• /
• 1982

This Paper is an experimental study on the effective dielectric constant of microstrip line. To quantify the dispersive effects on a microstrip line, the effective dielectric constant, which is the ratio of free space wavelength to guide wavelength, is calculated for teflon substrates. The calculation is based on the Fourier transform of the current distribution on microstrip line. Measurements of effective dielectric constant using a microstrip elliptic resonator and ring resonator are also described. As a result, the computed values of effective dielectric constant agree almost all with measured values, using ring and elliptic resonator, in case of w/h or the ratio of microstrip width to substrate thickness equal unity over frequency range of 8 to 12GHz.

• Smart Structures and Systems
• /
• v.16 no.6
• /
• pp.1091-1105
• /
• 2015

Piezoelectric coefficient and dielectric constant of PZT-5H vary with electric field. In this work, variations of these coefficients with electric field are included in finite element modelling of a cantilevered plate instrumented with piezoelectric patches. Finite element model is reduced using modal truncation and then converted into state-space. First three modal displacements and velocities are estimated using Kalman observer. Negative first modal velocity feedback is used to control the vibrations of the smart plate. Three cases are considered v.i.z case 1: in which variation of piezoelectric coefficient and dielectric constant with electric field is not considered in finite element model and not considered in Kalman observer, case 2: in which variation of piezoelectric coefficient and dielectric constant with electric field is considered in finite element model and not considered in Kalman observer and case 3: in which variation of piezoelectric coefficient and dielectric constant with electric field is considered in finite element model as well as in Kalman observer. Simulation results show that appreciable amount of change would appear if variation of piezoelectric coefficient and dielectric constant with r.m.s. value of electric field is considered.

• Journal of the Korean Society of Safety
• /
• v.23 no.3
• /
• pp.51-57
• /
• 2008

NDT(Non-Destructive Testing Evaluation) using electromagnetic(EM) properties can be used for evaluation of physical performance in cement-based materials. In this study, a technique for strength evaluation in cement mortar is proposed through the measured EM properties(conductivity and dielectric constant). For this research, cement mortar specimens with 5 W/C ratios are made for evaluation of compressive strength and they are also utilized for tests of EM properties in the range of $0.2{\sim}20GHz$ frequency considering exposure condition and curing period. The averaged conductivity and dielectric constant in $5{\sim}20GHz$ frequency are reduced to $83{\sim}93%$ and $81{\sim}87%$, respectively with increasing water to cement ratios. Through the linear regression analysis, relationships between EM properties and results from the compressive strength are obtained, which shows higher correlated factor($0.93{\sim}0.94$) in the specimens exposed to room condition. The gradients in dielectric constant for strength results is measured to be higher than those in conductivity by $3.9{\sim}5.1$ times. The results from dielectric constant in room condition shows the most efficient relation for evaluation of strength.

• Tribology and Lubricants
• /
• v.27 no.3
• /
• pp.125-133
• /
• 2011

The purpose of this study is to develop an engine oil quality monitoring system to warn the abnormal condition of engine oil. To do this, first of all, it is needed a personal controller development to measure the capacitance of a pre-developed engine oil deterioration detection sensor integrated with an oil filter. To measure the capacitance of engine oil in the sensor, it is used the way measuring the electric charging time in a capacitor by impressing DC volt. This method has merits on cost and signal stability. The measured capacitance is compensated by comparing with the one measured by an impedance analyzer. Also, using the dielectric constant gained by an impedance analyzer, the calculating equation of the dielectric constant of engine oil related with the currently developed sensor is decided. Then, the deterioration degree of engine oil is estimated according to the change rate of dielectric constant between green oil and used oil. Finally, using this dielectric constant information together with engine oil temperature and pressure, the currently developed engine oil quality monitoring system is to tell the abnormal state of engine oil.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.22 no.3
• /
• pp.205-209
• /
• 2009

In this study, in order to develop the composition ceramics for lead-free ultrasonic motor, (1-x-0.09)$NaNbO_{3-x}BaTiO_3-0,09LiNbO_3$ ceramics were fabricated using a conventional mixed oxide process and their piezoelectric and dielectric characteristics were investigated according to the $BaTiO_3$ substitution. All the specimens showed orthorhombic phase structure without secondary phase, $BaTiO_3$ substitution enhanced density, dielectric constant(${\epsilon}_r$) and electromechanical coupling factor($k_p$), However, mechanical quality factor was deteriorated. Curie temperature of specimens was observed as about $380^{\circ}C$. At the $BaTiO_3$ substitution of 4 mol%, density, electromechanical coupling factor($k_p$), dielectric constant(${\epsilon}_r$) and piezoelectric constant($d_{33}$) of specimen showed the optimum value of $4.493g/cm^3$, 0.236, 175, 70 pC/N, respectively.

• Advances in materials Research
• /
• v.2 no.3
• /
• pp.141-153
• /
• 2013

Nanocrystalline Barium niobate ($BaNbO_3$) has been synthesized by a novel auto-igniting combustion technique. The X-Ray diffraction studies reveals that $BaNbO_3$ posses a cubic structure with lattice constant $a=4.071{\AA}$. Phase purity and structure of the nano powder are further examined using Fourier-Transform Infrared and Raman spectroscopy. The average particle size of the as prepared nano particles from the Transmission Electron Microscopy is 20 nm. The UV-Vis absorption spectra of the samples are recorded and the calculated average optical band gap is 3.74eV. The sample is sintered at an optimized temperature of $1425^{\circ}C$ for 2h and attained nearly 98% of the theoretical density. The morphology of the sintered pellet is studied with Scanning Electron Microscopy. The dielectric constant and loss factor of a well-sintered $BaNbO_3$ at 5MHz sample is found to be 32.92 and $8.09{\times}10^{-4}$ respectively, at room temperature. The temperature coefficient of dielectric constant was $-179pp/^{\circ}C$. The high dielectric constant, low loss and negative temperature coefficient of dielectric constant makes it a potential candidate for temperature sensitive dielectric applications.

• Proceedings of the IEEK Conference
• /
• 2008.06a
• /
• pp.343-344
• /
• 2008

A measurement method of the dielectric constant of materials whose standard sample is not prepared easily is proposed. The unprepared sample of the material is placed in a cavity, and the resonant frequency is measured. A commercial software simulates the same sample and the cavity leading to find the correct dielectric constant. The measured samples include a ceramic, a forced glass, and a powdered enamel.

• Macromolecular Research
• /
• v.8 no.2
• /
• pp.53-58
• /
• 2000

Stabilities and structures of resorcinol formaldehyde resins (RF resins) and their dependence on solvent were studied by molecular mechanics and molecular dynamics. Dimers to decamers of the RF resins in the conditions of dielectric constant = 1.00, 21.01, 36.64, and 80.10 were calculated. The average distance between oxygen atoms in 1-hydroxyl groups of adjacent resorcinols of the resins became longer with increased dielectric constant of the environment. The number of intramolecular hydrogen bonds of the resins decreased by increasing the dielectric constant of the environment. The RF resin structure on the surface of fabric or steel cord was explained based on the present calculation.

• Bulletin of the Korean Chemical Society
• /
• v.23 no.5
• /
• pp.741-744
• /
• 2002

Single phase of multicomponent oxide ZrTiO4 film could be prepared through surface sol-gel route simply by coating the mixture of 100 mM zirconium butoxide and titanium butoxide on $Pt/Ti/SiO_2Si(100)$ substrate, following pyro lysis at $450^{\circ}C$, and annealing it at 770 $^{\circ}C.$ The dielectric constant of the film was reduced as the film thickness decreased due to of the interfacial effects caused by layer/electrode and a few voids inside the multilayer. However, the dielectric property was independent of applied dc bias sweeps voltage (-2 to +2 V).The dielectric constant of bulk film, 31.9, estimated using series-connected capacitor model was independent of film thickness and frequency in the measurement range, but theoretical interfacial thickness, ti, was dependent on the frequency. It reached a saturated ti value, $6.9{\AA}$, at high frequency by extraction of some capacitance component formed at low frequency range. The dielectric constant of bulk ZrTiO4 pellet-shaped material was 33.7 and very stable with frequency promising as good applicable devices.