• Bulletin of the Korean Chemical Society
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• v.18 no.8
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• pp.811-814
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• 1997

An oxidative thermal regeneration process was developed and evaluated for its potential applicability in several environmental areas. The feasibility of the process is affected strongly by the gradual carbon loss, energy consumption, physical changes of carbon, and effective destruction efficiency of adsorbed materials during the regeneration. The aim of the study is to determine the optimum conditions to maintain acceptable destruction efficiency for adsorbed organics, controlling oxidant flow rate. Prior to its applications, various preliminary tests were carried out to determine the effects of experimental parameters on the process. The tests performed were reaction temperature, carbon loss, surface area, surface structure, and adsorptive property. The results of these tests show that the parameters are dependent on oxidant flow rate, and suggest that the process is comparable and, in some ways, possibly superior to conventional regeneration techniques because the oxidative process is a single step and less energy intensive.

• Bulletin of the Korean Chemical Society
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• v.18 no.8
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• pp.814-818
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• 1997

The chemical waste treatment, APEG (alkali/polyethylene glycol) process has been shown to be effective for the dechlorination of PCBs in transformer oil. Considerable amount of PCBs, however, still remains in the waste exceeding the 25-50 ppm limit set by regulatory agency. A new thermal regeneration technology has been developed in our laboratory for disposal of hazardous organic wastes. Due to the limited oxidation of carbon surface through the reverse movement of flame front to oxidant flow, this technology was termed counterflow oxidative system (COS). Specially, the oxidant flow in the COS process is a principal parameter which determines the optimum conditions regarding acceptable removal and destruction efficiency of adsorbed organic wastes at minimal carbon loss. The COS process, under optimum conditions, was found to be very effective and the removal and destruction efficiency of 99.99% or better was obtained for residual PCBs in the waste while bulk (≥90%) of carbon was recovered. Any toxic formation of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzo furans (PCDFs) were not detected in the regenerated carbon and impinger traps. The results of surface area measurement showed that the adsorptive property of regenerated carbon is mostly reclaimed during the COS process.

• Proceedings of the KSME Conference
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• 2001.06d
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• pp.751-758
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• 2001

Exergy concept is applied to the analysis of part-load performance of gas turbine engine. Exergy is a useful tool to find the source of irreversibility in thermal system. In this study, details of the performance characteristics of a heavy-duty gas turbine, l50MW-class GE 7FA model, are described by theoretical investigations with exergy analysis. Result shows that exergy destruction rate of gas turbine increases with decreased load, which means increase of irreversibility. Also, it is found that variations of IGV angle and amount of cooling air for turbine blades are closely related to the inefficiencies of compressor and turbine, respectively.

• Analytical Science and Technology
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• v.13 no.6
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• pp.699-704
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• 2000

A study has been made for the electrochemical destruction of cyanide ions and removal of zinc ions from a simulated electroplating wastewater by the use of a platinum platized-titanium anode and a stainless steel cathode. Several experimental parameters, including electrolysis time, cell current, additives, and chloride concentration, have been investigated and used for efficient destruction of cyanide waste and removal of zinc ions from aqueous solutions. It was found that cell current and type of additives gave great effects on the destruction of cyanide ions and removal of zinc ions. The optimized conditions (electrolysis time: 1hr, current: 12A, additive: 0.5 M NaCl) have been defined to destroy cyanide ions and remove zinc ions with high efficiency and low operation cost. The proper reaction mechanism leading to the destruction of cyanide on the anode has also been discussed.

• Journal of the Korean Institute of Gas
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• v.21 no.6
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• pp.88-95
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• 2017

The usage of toxic gas in Korea is increasing in the development of high-tech industries such as semiconductors, displays and solar panels. The recent survey of domestic toxic gas consumption indicates an increase in annual average of 12.4 percent, but it is still focused on usage, and it is negligent in safety and treating the post. In September 2012, an accident occurred in Gu-mi involving hydrofluoric acid leak demonstrates the absence of safety management. Due to the incident, the government, industry and academia have been interested in chemical substances(toxic gas), and the government-led safety management has been established and implemented, but there are still a lot of safety blind spots. The purpose of this study is to develop effective measurement methods for the destruction or removal efficiency of gaseous materials emitted from the Scrubber used in the semiconductor and display industries. Also, this study demonstrated how toxic gas facilities can be applied without error by verification test for the measurement method guideline of the destruction or removal efficiency of the green-house gas reduction facility in the semiconductor and display industries used by the National Institute of Environmental Research and the UNFCCC, and suggested the differentiated measurement methods for toxic gas reduction facilities, and the third party certification for safety facilities is needed to prevent toxic gas accidents.

• Journal of Environmental Science International
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• v.14 no.8
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• pp.785-792
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• 2005

In order to reduce roadside and indoor air pollution for volatile organic compounds VOC), it may be necessary to apply photocatalyst-coated construction materials. This study evaluated the technical feasibility of the application of $TiO_2$ photocatalysis for the removal of VOC present in roadside or indoor air. The photocatalytic removal of five target VOC was investigated: benzene, toluene, ethyl benzene and o,m,p-xylenes. Variables tested for the current study included ultraviolet(UV) light intensity coating materials, relative humidity (RH), and input concentrations. Prior to performing the parameter tests, adsorption of VOC onto the current experiment was surveyed, and no adsorption was observed. Stronger UV intensity provided higher photocatalytic destruction(PCD) efficiency of the target compounds. For higher humidity, higher PCD efficiency was observed. The PCD efficiency depended on coating material. Contrary to certain previous findings, lower PCD efficiencies were observed for the experimental condition of higher input concentrations. The current findings suggested that the four parameters tested in the present study should be considered for the application of photocatalyst-coated construction materials in cleaning VOC of roadside or indoor air.

• Journal of the Korean Chemical Society
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• v.50 no.6
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• pp.454-463
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• 2006

refractory organic compounds in aqueous solution are not readily removed by the existing conventional wastewater treatment process. In recent years, the sonolysis and electrochemical oxidation process had been shown to be promising for wastewater treatment due to the effectiveness and easiness in operation. This study was performed to investigate the characteristics of sonolytic and electrolytic decomposition as the basic data for development of the wastewater treatment process. Trichloroethylene(TCE) and 2,4- dichlorophenol(2,4-DCP) were used as the samples, and their destruction efficiency were measured with various operating parameters, such as initial solution concentration, initial solution pH, reaction temperature, sonic power and current density. Also, the decomposition mechanism conformed indirectly with the effect of NaHCO3 as a radical scavenger on the decomposition reaction. Thermal decompositon reaction is predominant for TCE but thermal and radical decompositon reactions were dominant for 2,4-DCP. Results showed that the destruction efficiencies of all samples were above 65% within 120 minutes by sonolysis and electrolysis at the same time, and were increased with increasing initial concentration, sonic power and current density. Destruction efficiency of TCE was high in the acidic solution, but 2,4-DCP showed high destruction efficiency in basic solution.

• Journal of the Korean Electrochemical Society
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• v.2 no.4
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• pp.183-189
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• 1999

A study on the destruction of organic cation and anion exchange resins by electro-generated Ag(II) as a mediator was carried out to develop the ambient-temperature aqueous process, known as Ag(II)-mediated electro-chemical oxidation (MEO) process, for the treatment of a large quantity of spent organic ion exchange resins as the low and Intermediated-level radioactive wastes arising from the operation, maintenance and repairs of nuclear facilities. The effects of controllable process parameters such as applied current density, temperature, and nitric acid concentration on the MEO of organic ion exchange resins were investigated. The cation exchange resin was completely decomposed to $CO_2$. The current efficiency increased with a decrease in applied current density while nitric acid concentration and temperature on the MEO of cation exchange resin did not affect the MEO. On the other hand, anion exchange resins were decomposed to CO and $CO_2$. The ultimate conversion to CO was about $10\%$ regardless of temperature. The destruction efficiencies to $CO_2$ were dependent upon temperature and the effective destruction of anion exchange resin could be obtained above $60^{\circ}C$.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2007.10a
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• pp.249-250
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• 2007

• Proceedings of the Korean Society of Computer Information Conference
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• 2012.07a
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• pp.243-246
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• 2012

A new multi inner stage(MIS) cyclone was designed to remove the acidic gas and minute particles of harmful materials produced from electronic industry. To characterize gas flow in MIS cyclone, pressure and velocity distribution were calculated by means of computational fluid dynamics(CFD) commercial program. Also, the flow locus of particles and particle removal efficiency were analyzed by Lagrangian method. When outlet pressure condition was -1,000 Pa, the efficiency was the best in this study. Based on the CFD simulation result, the pressure loss and destruction removal efficiency was measured through MIS cyclone experiment.