• Journal of Environmental Health Sciences
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• v.30 no.2
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• pp.133-139
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• 2004

The objective of this study was to investigate the destruction efficiency and to determine the fundamental parameters of oxidation kinetics under the supercritical water(SCW) condition. Target material was cephradine, toxic and antibiotic material, in the pharmaceutical wastewater. For this purpose, the effect of reaction temperature and oxidant were investigated on the destruction efficiency of cephradine. And the oxidation kinetics of cephradine was derived by using a empirical power-law model. The experiment was carried out in a cylindrical batch reactor made of Hastelloy C-276 which was endurable high temperature and pressure. The destruction efficiency of cephradine increased with increment of the temperature and reaction time. Also the type of oxidants was effected and oxidants(Air and $H_2O$$_2$) were enhanced the destruction efficiency. The global oxidation kinetics for cephradine has led to two rate expressions according to type of oxidant. - In the presence of air oxidant: Rate=k. $e^{-Ea}$RT/(Ceph.)$^{1.0}$ ( $O_2$)$^{0.51}$$\pm$0.05(k=3.27${\times}$$10^{5}$ sec. Ea=63.25 kJ/mole) - In the presence of $H_2O$$_2$ oxidant : Rate=kㆍ $e^{-Ea}$RT/(Ceph.)$^{1.0}$ ($H_2O$$_2$)$^{0.62}$$\pm$0.02(k=2.76${\times}$$10^4$/sec. Ea=47.65 kJ/mole)ole))

• Journal of Environmental Science International
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• v.15 no.7
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• pp.635-642
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• 2006

Present study evaluated the low-temperature destruction of n-hexane and benzene using mesh-type transition-metal platinum(Pt)/stainless steel(SS) catalyst. The parameters tested for the evaluation of catalytic destruction efficiencies of the two volatile organic compounds(VOC) included input concentration, reaction time, reaction temperature, and surface area of catalyst. It was found that the input concentration affected the destruction efficiencies of n-hexane and benzene, but that this input-concentration effect depended upon VOC type. The destruction efficiencies increased as the reaction time increased, but they were similar between two reaction times for benzene(50 and 60 sec), thereby suggesting that high temperatures are not always proper for thermal destruction of VOCs, when considering the destruction efficiency and operation costs of thermal catalytic system together. Similar to the effects of the input concentration on destruction efficiency of VOCs, the reaction temperature influenced the destruction efficiencies of n-hexane and benzene, but this temperature effect depended upon VOC type. As expected, the destruction efficiencies of n-hexane increased as the surface area of catalyst, but for benzene, the increase rate was not significant, thereby suggesting that similar to the effects of the re- action temperature on destruction efficiency of VOCs, high catalyst surface areas are not always proper for economical thermal destruction of VOCs. Depending upon the inlet concentrations and reaction temperatures, almost 100% of both n-hexane and benzene could be destructed, The current results also suggested that when applying the mesh type transition Metal Pt/SS catalyst for the better catalytic pyrolysis of VOC, VOC type should be considered, along with reaction temperature, surface area of catalyst, reaction time and input concentration.

• Fashion & Textile Research Journal
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• v.7 no.4
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• pp.433-438
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• 2005

Seven commercial lining fabrics normally used in a market were selected: plain-weave fabrics with polyester, nylon, rayon and acetate fiber, and polyester textured yarn, in addition, polyester fabrics with plain, twill and satin weave. Then seam strength, seam efficiency, resistance to slippage of yarns and type of seam destruction were examined related to endurance by textiles in sewing capability of the lining fabrics. In results, as tensile strength was greater, seam strength got greater, which shows tensile strength and seam strength have close relationship. Tensile and seam strength of acetate fabric were the least, but seam efficiency was the greatest. It presents that strong tensile and seam strengths do not show high seam efficiency at the same time. Various types of seam destruction have been shown. When tensile strength of the sewing thread was greater than tensile strength of fabric, fabric destruction was occurred before the sewing thread destruction. When tensile strength of the fabric was greater than seam strength, the sewing thread destruction was occurred. Resistance to slippage of yarns got greater as tensile strength of the fabric got greater. The plain-weave fabric, which tensile strength of fabric was smaller, showed the greater resistance to slippage of yarns than twill and satin weave fabrics. The stretch fabric revealed the optimal lining fabric with the greatest resistance to slippage of yarns.

• Bulletin of the Korean Chemical Society
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• v.28 no.8
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• pp.1383-1388
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• 2007

Recently, the semiconductor and display industries have tried to reduce the emissions of perfluorocompounds (PFCs) from the globally environmental regulation. Total amount of PFC emission can be calculated from the flow rate and the partial pressures of PFCs. For the precise measurement of PFC emission amount, the mass flow controlled helium gas was continuously injected into the equipment of which scrubber efficiency is being measured. The partial pressures of PFCs and helium were accurately measured using a mass spectrometer in each sample extracted from inlet and outlet of the scrubber system. The flow rates are calculated from the partial pressures of helium and also, PFC destruction and removal efficiency (DRE) of the scrubber is calculated from the partial pressure of PFC and the flow rate. Under this method, the relative expanded uncertainties of the flow rate and the partial pressures of PFCs are ± 2% (k = 2) in case the concentrations of NF3 and SF6 are as low as 100 μmol/mol.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.26 no.11
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• pp.497-503
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• 2014

The performances of refrigeration truck systems using R404A and R134a were investigated by experimental testing, and compared. The optimal COPs of the R404A and R134a systems were 2.96 and 3.42, when the refrigerant charge amount was 1.3 kg and 1.4 kg, respectively. When the indoor side air temperature increased from $5^{\circ}C$ to $9^{\circ}C$, the total exergy destruction rate of the R404A system was on average 39.1% higher than that of the R134a system. In addition, the exergy efficiency of the R404A system was 12.9% higher than that of R134a system, for various indoor air temperatures. When the outdoor side air temperature increased from $25^{\circ}C$ to $35^{\circ}C$, the total exergy destruction rate of the R404A and R134a systems decreased by 18.9% and 19.5%, respectively. In addition, the exergy efficiency of the R404A and R134a systems increased by 25.2% and 30.7%, respectively. As the compressor rotating speed increased, the COP of the R404A and R134a systems decreased by 23.6% and 18.4%. The total exergy destruction rate and exergy efficiency of the R404A system were 27.2% and 15.7% higher than those of R134a system, respectively. Compared to the R404A system, the R134a system showed a higher COP and a lower exergy destruction rate; thus it can be concluded that the R134a system has the better performance.

• Journal of Korean Society for Atmospheric Environment
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• v.16 no.6
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• pp.665-674
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• 2000

A major source of the hazardous waste generated is from chemical industries producing plastics, herbicides, pesticides and chlorinated solvents. All of these processes produce a class if hazardous waste termed the chlorinated hydrocarbons(CHCs), either directly or from undesirable side reactions. In this study, we investigated the destruction characteristics of hazardous waste through incineration. A nonequilibrium combustion model was used to describe the effect of the chemical kinetics due to the flame inhibition characteristics of $CCl_4$ which was used as the surrogate of hazardous waste. A parametric screening studies was made in a dump incinerator proposed in this study. The dump incinerator showed high $CCl_4$ DRE(Destruction and Removal Efficiency) as 5 nines. $CCl_4$/CH$_4$ ratio appeared to be most important in the destruction of $CCl_4$ through incineration.

• Resources Recycling
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• v.21 no.4
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• pp.69-75
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• 2012

Destruction of HFC-134a from ELV (End of Life Vehicle) were determined in a gasification-melting demonstration system of municipal solid waste (100ton/day). The injection system has been developed for the uniform injection of HFC-134a to the gasification-melting system. The destruction characteristics of HFC-134a and analysis of exhaust gases have been performed. The destruction efficiency was 99.995% for HFC-134a feeding of 3 kg/hr and the exhaust gases such as CO, SOx, NOx, HCl and HF satisfied the environmental standards.

• Journal of Korean Society for Atmospheric Environment
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• v.28 no.4
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• pp.446-453
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• 2012

Destruction and removal efficiency (DRE) of $SF_6$ was tested with varying degrees of ionization and initial concentrations of $SF_6$. The applied dose of ionization energy varied from 0 to 400 kGy. The initial concentration of $SF_6$ gas also varied from 1,000 ppm to 2,500 ppm. In order to assess the effect of a residence time on DRE (Destruction and Removal Efficiency, %), experiments were also conducted at different irradiation times of 3, 5, 10, 15, and 20 sec, respectively. The DRE of $SF_6$ increased with an increasing amount of dose and current. Regardless of initial concentration of $SF_6$, 90% level of DRE was achieved by applying over 10 mA of electrical current.

• Journal of Environmental Science International
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• v.13 no.9
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• pp.767-777
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• 2004

This study evaluated the technical feasibility of the application of $TiO_2$ photocatalysis for the removal of volatile hydrocarbons(VHC) at low ppb concentrations commonly associated with non-occupational indoor air quality issues. A series of experiments was conducted to evaluate five parameters (relative humidity (RH), hydraulic diameter (HD), feeding type (FT) of VHC, photocatalytic oxidation (PCO) reactor material (RM), and inlet port size (IPS) of PCO reactor) for the PCO destruction efficiencies of the selected target VHC. None of the target VHC presented significant dependence on the RH, which are inconsistent with a certain previous study that reported that under conditions of low humidity and a ppm toluene inlet level, there was a drop in the PCO efficiency with decreasing humidity. However, it is noted that the four parameters (HD, RM, FT and IPS) should be considered for better VHC removal efficiencies for the application of $TiO_2$ photocatalytic technology for cleansing non-occupational indoor air. The PCO destruction of VHC at concentrations associated with non-occupational indoor air quality issues can be up to nearly 100%. The amount of CO generated during PCO were a negligible addition to the indoor CO levels. These abilities can make the PCO reactor an important tool in the effort to improve non-occupational indoor air quality.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.5
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• pp.577-583
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• 2007

To overcome certain disadvantages of past typical control techniques for toxic contaminants emitted from various industrial processes, the current study was conducted to establish a thermal catalytic system using mesh-type transition-metal platinum(Pt)/stainless steel(SS) catalyst and to evaluate catalytic thermal destruction of five chlorinated hydrocarbons[chlorobenzene(CHB), chloroform(CHF), perchloroethylene (PCE), 1,1,1-trichloroethane(TCEthane), trichloroethylene(TCE)]. In addition, this study evaluated the catalyst poison effect on the catalytic thermal destruction. Three operating parameters tested for the thermal catalyst system included the inlet concentrations, the incineration temperature, and the residence time in the catalyst system. The thermal decomposition efficiency decreased from the highest value of 100% to the lowest value of almost 0%(CHB) as the input concentration increased, depending upon the type of chlorinated compounds. The destruction efficiencies of the four target compounds, except for TCEthane, increased upto almost 100% as the reaction temperature increased, whereas the destruction efficiency for TCEthane did not significantly vary. For the target compounds except for TCEthane, the catalytic destruction efficiencies increased up to 30% to 97% as the residence time increased from 10 sec to 60 sec, but the increase of destruction efficiency for TCEthane stopped at the residence time of 30 sec, suggesting that long residence times are not always proper for thermal destruction of VOCs, when considering the destruction efficiency and operation costs of thermal catalytic system together. Conclusively, the current findings suggest that when applying the transition-metal catalyst for the better destruction of chlorinated hydrocarbons, VOC type should be considered, along with their inlet concentrations, and reaction temperature and residence time in catalytic system. Meanwhile, the addition of high methyl sulfide(1.8 ppm) caused a drop of 0 to 50% in the removal efficiencies of the target compounds, whereas the addition of low methyl sulfide (0.1 ppm), which is lower than the concentrations of sulfur compounds measured in typical industrial emissions, did not cause.