• Title/Summary/Keyword: depth of diffusion

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Development of Novel Techniques for Determining the Oxygen Tracer Diffusion Coefficients in Oxides II - Measurements of the Depth Profiles of $^{18}O$ Concentration in the solid Samples by Raman Spectroscopy (산화물에서의 산소추적자확산계수를 결정하는 새로운 방법의 개발 II - 라만분광법에 의한 고체시료 중의 시간에 따른 $^{18}O$ 농도변화 측정 -)

  • 김병국;마하구찌히로오;박순자
    • Journal of the Korean Ceramic Society
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    • v.31 no.12
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    • pp.1459-1466
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    • 1994
  • A novel technique for determining the oxygen tracer diffusion coefficients in oxides was developed. After the 16O-18O solid-gas exchange reactions between 16O in the oxides and 18O in the ambient gas, Raman spectra of the cross sections of oxide samples were measured in a spatial resolution of 5 ${\mu}{\textrm}{m}$. From thus obtained Raman spectra, depth profiles of 18O concentration in the oxide samples were calculated. The oxygen tracer diffusion coefficients and the surface exchange coefficients were determined under the assumptions that samples are semi-infinite slab and that the surface exchange reactionsare not negligible. The oxygen tracer diffusion coefficient of 2.8 mol% Y2O3-containing tetragonal ZrO2 polycrystals, 8 mol% Y2O3-containing ZrO2 polycrystals, and 10 mol% Y2O3-containing cubic ZrO2 single crystals (along the a axis) are as follows.

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Diffusivity of Carbon Dioxide in Concrete (콘크리트 내 이산화탄소 확산계수 예측에 관한 연구)

  • 오병환;정상화;이명규
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.669-674
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    • 2003
  • The purpose of this study is to identify the diffusion coefficients of carbon dioxide for various concrete mixtures. The test results indicate that the diffusion coefficient increases with the increase of water-cement ratio. The diffusion coefficient decreases with the increase of relative humidity at the same water-cement ratio. The diffusion of carbon dioxide reached the steady-state within about five hours after exposure. It was found that the diffusion coefficient of cement paste is larger then that of concrete or mortar. The quantitative values of diffusivity of carbon dioxide in this study will allow more realistic assessment of carbonation depth in concrete structures.

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Analysis of Transient Magnetic Diffusion in a High-Temperature Superconductor Tube (고온 초전도체 관에서의 과도 자기확산 해석)

  • 설승윤;정성기
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.11
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    • pp.991-996
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    • 2002
  • Transient magnetic diffusion process in a melt-cast BSCCO-2212 tube is analyzed by an analytical method. The transient diffusion partial differential equation is transformed into an ordinary differential equation by integral method. The penetration depth of magnetic field into a superconducting tube is obtained by solving the differential equation numerically. The results show that the penetration depth as a function of time which is somewhat different from the results by Bean's critical state model. The reason of the difference between the present results and that of Bean's model is discussed and compared in this paper.

Analysis of Transient Magnetic Diffusion in a High-Temperature Superconductor Tube (고온 초전도체 관에서의 과도 자기확산 해석)

  • Seol, S.Y.;Jung, S.K.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.04a
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    • pp.41-45
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    • 2002
  • Transient magnetic diffusion process in a melt-cast BSCCO-2212 tube is analyzed by an analytical method. The transient diffusion equation is transformed into an ordinary differential equation by integral method. The penetration depth of magnetic field into a superconducting tube is obtained by solving the differential equation numerically. The results show that the penetration depth as a function of time which is somewhat different from the results by Bean's critical current model. The reason of the difference between the present results and that of Bean's model is discussed and compared in this paper.

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The Characteristics of Thermal Diffusion With the Vertical-Closed Loop Type Geothermal Heat Exchanger (수직밀폐형 지중열교환기의 온도분포 특성)

  • Sun, Jong-Cheol;Kim, Byung-Chul;Koh, Young-Ha
    • Journal of the Korean Solar Energy Society
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    • v.33 no.1
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    • pp.57-65
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    • 2013
  • The temperatures with the ground depth, the positions of circulation water in ground heat exchanger were measured and thermal diffusion characteristics with the distances of the direction normal to the borehole was analysed. The deeper the depth of ground, the less the influences of outdoor temperature, but below 10m of ground, there was no influences of ground temperature. When the depth of trench pipe was below the depth of 2m, there was no influence. In the ground of 10m when the distances between the pipe and the other places were above 0.5m, the variations of temperature were less than $1.6^{\circ}C$ and above 2.5m they were less than $0.1^{\circ}C$. When the distances of bore hole were above 5m, there were no. influences of the nearest ground heat exchanger.

A study on the fire smoke diffusion delay strategy in a great depth underground double deck tunnel junction (대심도 복층터널 교차로 화재연기 확산지연 방안 연구)

  • Shin, Tae-Gyun;Moon, Jung-Joo;Yang, Yong-Won;Lee, Yun-Taek;Han, Jae-Hee
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.21 no.1
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    • pp.115-126
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    • 2019
  • Recently, in order to solve the traffic congestion in urban areas and to improve the peripheral environment, research on the design and construction technology development of great depth underground double-deck tunnel is under way by using the underground space in the urban area. The network type double-deck tunnel is in the form of an intersection with a small cross section and a steep slope as per construction at the base of a flatland, so that the fire smoke spreads rapidly in case of fire, which is expected to cause damage of human life. Therefore, this study is analyzed the delay effect of fire smoke diffusion according to the installation and non - installation of delay system for fire smoke diffusion at the intersection. Fire fumes were delayed up to 270 seconds when the delay system for fire smoke diffusion was installed at the intersection and it is analyzed that the greater the operating area of the delay system for fire smoke diffusion, the more preventable the damage of human life of the intersection.

The Expectation of Effective Diffusion Coefficient of $CO_2$ on Carbonated Concrete (중성화된 콘크리트의 $CO_2$ 유효확산계수 예측)

  • 이창수;윤인석;이규동;권재근
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.555-558
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    • 2001
  • Carbonation of concrete decreases durability of RC structures due to failure of passive film of rebar. Therefore, expecting carbonation depth is a governing parameter of service life prediction for RC structures. This study attempt to estimate carbonation depth quantitatively by using equivalent effective diffusion coefficient of $CO_2$.

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Characterization of Zn diffusion in TnP Cy $Zn_3P_2$ thin film and rapid thermal annealing (RHP에서의 $Zn_3P_2$ 박막 및 RTA법에 의한 Zn 확산의 특성)

  • 우용득
    • Journal of the Korean Vacuum Society
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    • v.13 no.3
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    • pp.109-113
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    • 2004
  • Zn diffusions in InP have been studied by electrochemical capacitance voltage. The InP layer was grown by metal organic chemical vapor deposition, and $Zn_3P_2$ thin film was deposited on the epitaxial substrates. The samples annealed in a rapid thermal annealing. It is demonstrated that surface hole concentration as high as $1\times10^{19}\textrm{cm}^{-3}$ can be achieved. When the Zn diffusion was carried at $550^{\circ}C$ and 5-20 min., the diffusion depth of hole concentration moves from 1.51$\mu\textrm{m}$ to 3.23 $\mu\textrm{m}$, and the diffusion coeffcient of Zn is $5.4\times10^{-11}\textrm{cm}^2$/sec. After activation, the concentration is two orders higher than that of untreated sample at 0.30 $\mu\textrm{m}$ depth. As the annealing time is increase, the hole concentration remains almost constant, except deep depth. It means that excess Zn interstitials exist in the doped region is rapidly diffusion into the undoped region and convert into substitutional When the thickness of $SiO_2$ thin film is above 1,000$\AA$, the hole concentration becomes stable distribution.

Determination of Required Cover Depth of Concrete Exposed to Simultaneous Attack of Carbonation and Chloride Ion (중성화와 염소이온의 동시 복합환경에 노출된 콘크리트의 적정 피복두께의 결정)

  • 이창수;윤인석;이규동
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.90-93
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    • 2003
  • The most common deteriorating processes of concrete structures in the world-wide are carbonation and chloride ion. In this paper, chloride profiles of carbonated concrete is predicted to considering two layer composite model, which is based on Fick's 2nd law. From the experimental result on combined deterioration of chloride and carbonation, it was examined that high chloride concentration was built up to 3-5㎜ over depth from carbonation depth. The analytical modeling of chloride diffusion, which was based on the Fick's 2nd law of diffusion, was suggested to depict the relative influence of the carbonation depth.

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Characteristic of Chloride Ion Diffusion in Concrete Containing GGBF (고로슬래그미분말 혼합 콘크리트의 염소이온 확산특성)

  • 문한영;김홍삼;김진철;최두선
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.793-796
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    • 2001
  • Physical properties of concrete, Such as, compressive strength, permeable pore and penetration depth of chloride ion were investigated. And to investigate the effect of containing GGBF in concrete, the diffusion coefficient of chloride was measured through an electro- migration test. The diffusion coefficient of chloride was decreased with increase of replacement ratios of GGBF when compared to OPC. Relation coefficients between physical properties of concrete and diffusion coefficient of chloride were more than 0.9.

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