• Analytical Science and Technology
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• v.27 no.5
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• pp.234-242
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• 2014

Imicyafos which is a nematicide for controlling root-knot nematodes has been registered in the Republic of Korea in 2012, and the maximum residue limits of imicyafos are set to watermelon and korean melon as each 0.05 mg/kg. Extremely reliable and sensitive analytical method is required for ensuring food safety on imicyafos residues in agricultural commodities. Imicyafos residues in samples were extracted with acetone, partitioned with hexane and dichloromethane, and then purified with florisil. The purified samples were analyzed by HPLC-UVD and confirmed with LC-MS. Linear range was between 0.1~5 mg/kg with the correlation coefficient ($r^2$) 0.99997. Average recoveries of imicyafos ranged from 77.0 to 115.4% at the spiked levels of 0.02 and 0.05 mg/kg with the relative standard deviations of 2.2~9.6%. Limit of detection and quantification were 0.005 and 0.02 mg/kg, respectively. An inter-laboratory study was conducted to validate the determination method in depth, and the results were satisfactory. All of the validation results revealed that the developed analytical method in this study is relevant for imicyafos determination in agricultural commodities and will be used as an official analytical method.

• Korean Journal of Soil Science and Fertilizer
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• v.43 no.1
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• pp.1-7
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• 2010

This study was carried out to investigate plow pan characteristics and to grasp the relationship between its particle size distribution fractal dimension ($D_m$) and water transport in paddy plow pan. Twenty four soil sampling sites with different management groups, ordinary and sandy-textured, were selected and investigated for physical properties of soils such as Yamanaka hardness in April, non-submerged condition, before rice seedling transplanting. The plow pan appearing depth and thickness was determined by penetration resistance profile. Undisturbed core samples with five replicates were sampled at plow pan layerwith 2 inch cores for measuring soil bulk density and saturated hydraulic conductivity. The particle size distribution fractal dimension ($D_m$) was calculated by the method following the procedure Tylerand Wheacraft (1992), using the USDA-based particle size analysis datawith fractions of 0-0.002, 0.002-0.053, 0.053-0.1, 0.1-0.25, 0.25-0.5, 0.5-1.0, and 1.0-2.0 mm. The plow pan of investigated fields appeared at a range from 5 to 30 cm depth, showing minimum value in sandy-textured management group and maximum value in ordinary management group. The thickness of plow pan were distributed from 5 to 17 cm, showing both minimum and maximum values in sandy-textured management group. Averagely, the plow appearing depth were deeper in ordinary management group than in sandy-textured management group, whereas the reverse in the thickness of plow pan. The particle size distribution fractal dimension ($D_m$) had higher value with finer textures, with higher fractality in coarser texture. Saturated hydraulic conductivities, $K_s$, of plow pan soils distributed from 0.5 to 1420 mm $day^{-1}$, having the highest value in sandy skeletal soils. The $K_s$ decreased with decreasing clay content and $D_m$, showing power function relationships. The coefficient of determination, $R^2$, of the fitted power functions were higher in $D_m$ as x-axis than in clay content. This means that $D_m$ could give us more effective estimation than clay content. Especially, sandy-textured paddy soils had higher $R^2$, compared to ordinary paddy soils. $K_s$ of relatively coarse-textured soils with less than 18%of clay content, therefore, was more dependent on particle size distribution than that of relatively fine-textured soils. From these results, it could be concluded that the fractal scaling gives us a unique quantity describing particle size distribution and then can be applied to estimate saturated hydraulic conductivity, especially more effective in coarse-textured soils.

• Journal of the Korean Institute of Landscape Architecture
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• v.51 no.2
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• pp.94-102
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• 2023

The Florence Charter, established in 1981 by the ICOMOS-IFLA International Commission on Historic Gardens, considered the historic garden as a plant-dominated architectural composition, a perpetual balance between the artist and the artisan's desire to remain unaltered in perpetuity. Trees, the main component of the garden, require continuous management as they repeat their creation and calling according to the cycle of the seasons and accordingly, it is suggested that management to maintain the appearance of trees in Korean palaces was an indispensable element. Although it is an important matter to historically verify the tree management techniques of the palaces of the past, research has been difficult due to the absence of historical records and the disconnection of life due to the Japanese colonial period. In addition, according to the view that trees were not generally managed in the palace, research on palace tree management techniques has not been conducted so far. Therefore, this study aimed to examine whether or not the tree management of the palaces was performed in the past through expert interviews based on photographs taken in modern times. With the identification of tree species and pruning through in-depth interviews with experts using photographs taken in the modern period, the results are as follows. First, it was found that the shapes of trees and leaves could be identified through photographs and by observing the phenomena caused by planting and pruning, it was possible to estimate whether or not the tree management was implemented in the modern palace. Second, as a result of in-depth interviews with 8 experts in 4 fields, it was possible to determine the tree species and pruning status, purpose, and method. There was no significant difference in opinions between groups, and the evidence was clearly presented. Third, the type of management of trees in the palace was mainly found to be determination of the types of tree, removal of hazardous factors of trees, and management of lower vegetation and through the photographs of Jondeokjeong and Gwanwanjeong, it was confirmed that the trees were managed even before the Japanese colonial era, considering the time of filming. Based on the photographs taken, it was possible to estimate whether the trees were managed before the Japanese colonial period through expert interviews. However, it could not be clarified due to lack of historical materials as to whether it was carried out on its own according to the circumstances of the times or by the Japanese Empire. Still, in this study, evidence was obtained to refute the view that trees of the palace were not managed in the past through the collected data. Expert opinions supporting this view were collected to make the conclusion. In addition, based on the general theory of pruning, an empirical review of expert opinions was conducted to secure the reliability of the research results.

• Journal of the Korean Society for Marine Environment & Energy
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• v.18 no.1
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• pp.1-8
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• 2015

To evaluate accuracy and precision of determination of total alkalinity ($Alk_T$) and carbon dioxide ($TCO_2$) derived from present study, experiment was applied with $CO_2$ CRM (Batch 132, Scripps Institution of Oceanography; $Alk_T=2229.24{\pm}0.39{\mu}mol/kg$, $TCO_2=2032.65{\pm}0.45{\mu}mol/kg$). As the result, average concentration of $Alk_T$ and $TCO_2$ was $2354.09{\mu}mol/kg$ (~5.6% difference with $CO_2$ CRM) and $2089.60{\mu}mol/kg$ (~2.3% difference with $CO_2$ CRM), respectively. For previous method (Gran Titration) by addition $NaHCO_3$ to deionized water($Alk_T$ $2023.33{\mu}mol/kg$), average concentration was $2193.39{\mu}mol/kg$ (sd=57.15, n=7). Whereas, average concentration was $2017.02{\mu}mol/kg$ (sd=10.98, n=7) for the present study. Recovery yield experiments of total alkalinity in deionized water and seawater were implemented by addition of $NaHCO_3$. The recovery yield of deionized water in the range 0 to $4952.39{\mu}mol/kg$ was 100.8% ($R^2$=0.999), and seawater in the range 0 to $2041.32{\mu}mol/kg$ was 102.3% ($R^2$=0.999). Comparison of $pCO_2$ sensor (PSI $CO_2-Pro^{TM}$) with present method showed very meaningful correlation coefficient ($R^2$=0.977) in the range of 427 to $705{\mu}atm$ and 9.16 to $15.24{\mu}mol/kg$ throught elapsed time for two weeks. Field experiment of diurnal variation of total carbon dioxide was accomplished at Sachon harbor in the coastal waters of East Sea of Korea. Concentration of $Alk_T$ and $TCO_2$ was increased during night, and decreased during daylight hours. The results showed mirror type between $TCO_2$ and dissolved oxygen, which was attributable to photosynthesis and respiration of phytoplankton. Also, open ocean field study was performed to obtain vertical profile of $Alk_T$ and $TCO_2$ in C-C zone (Clarion-Clipperton Fracture Zone), Northeastern Pacific. Average concentrations of $Alk_T$ in the surface mixed layer (0~60 m) and deeper layer below 200 m were $2422.38{\mu}mol/kg$ (sd=78.73, n=20) and $2465.87{\mu}mol/kg$ (sd=57.68, n=103), respectively. And average concentrations of $TCO_2$ were $2134.47{\mu}mol/kg$ (sd=65.4, n=20) and $2431.87{\mu}mol/kg$ (sd=65.02, n=103) in the same depth ranges such as $Alk_T$. Vertical distributions of $Alk_T$ and $TCO_2$ concentrations tended to increase with depth, and analyzed concentrations showed slightly higher than those of previous studies in this area.

• Journal of the Earthquake Engineering Society of Korea
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• v.7 no.5
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• pp.19-24
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• 2003

We analysed seismic phases recorded by the 10 December 2002 Cheolwon, Korea, earthquake of $M_{L}$ 3.6 and obtained source parameters such as hypocenter, origin time, earthquake magnitude. Velocity and acceleration records used in this study are from the KMA and KIGAM seismic networks. Due to the location of the epicenter in the north of the DMZ(Demilitarized Zone), direct Pg phases were recorded only at five stations in the area south of DMZ. Identification of refracted Pn phase as the first arrival is difficult in most stations. Therefore, the hypocenter determined by existing routine methods could be affected by a large error. In order to avoid the possibility of the problem, we employed a method of seismic phase analysis developed by Kim et al.. The direct, refracted, and reflected P and S phases were successfully identified using the method together with the travel time curve data. In order to improve the accuracy in determination of the hypocenter and origin time, we included PmP and SmS phases in the analysis in addition to the phases such as Pg, Pn, Sg and Sn. The epicenter, depth, and origin time of the Cheolwon earthquake determined based on data of 11 stations within 200km from the epicenter are $38.81^{\circ}$N, $127.22^{\circ}$E, 12.0km, and 7:42:51.4(local time), respectively. The average value of the local magnitude based on the Richter's definition from all the stations is 3.6 in $M_{L}$. This magnitude is smaller by 0.2 and 0.5 compared with magnitudes determined by KMA and KIGAM, respectively.

• The Journal of the Acoustical Society of Korea
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• v.23 no.1
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• pp.8-16
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• 2004

An inversion method is presented for the determination of the compressional wave speed, compressional wave attenuation, thickness of the sediment layer and density as a function of depth for a horizontally stratified ocean bottom. An experiment for estimating those properties was conducted in the shallow water of South Sea in Korea. In the experiment, a light bulb implosion and the propagating sound were measured using a VLA (vertical line array). As a method for estimating the geoacoustic properties, a coherent broadband matched field processing combined with Genetic Algorithm was employed. When a time-dependent signal is very short, the Fourier transform results are not accurate, since the frequency components are not locatable in time and the windowed Fourier transform is limited by the length of the window. However, it is possible to do this using the wavelet transform a transform that yields a time-frequency representation of a signal. In this study, this transform is used to identify and extract the acoustic components from multipath time series. The inversion is formulated as an optimization problem which maximizes the cost function defined as a normalized correlation between the measured and modeled signals in the wavelet transform coefficient vector. The experiments and procedures for deploying the light bulbs and the coherent broadband inversion method are described, and the estimated geoacoustic profile in the vicinity of the VLA site is presented.

• Journal of Wetlands Research
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• v.18 no.4
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• pp.424-431
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• 2016

LID facilities like bio-retention cells is applied to manage stormwater. LID concept becomes an important part in stormwater management, and the clear understanding of hydrologic performance and hydrologic impact on the corresponding catchment has been needed. In this study, the application of flow duration curves as design strategy is investigated. Bio-retention cells like many LID facilities are installed to reproduce natural hydrologic processes. In this study, the attempt to determine the size of a bio-retention cell is carried out to satisfy the flow duration criteria. From the results, it is shown that "5 mm * the area of a target catchment" which is the current facility design capacity is valid for the drainage area with 20-30% impervious rate. In the 100% impervious catchment where LID facilities are typically installed, the design capacity to intercept stormwater of approximately 47 mm depth is required to reproduce natural flow duration curves. This means that about 11% of the target catchment area should be allocated as a bio-retention cell. However, the criteria of the design capacity and facility surface area should be set at the possible implementation conditions in reality, and site-specific hydrologic characteristics of a target catchment should be considered.

• The Journal of Engineering Geology
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• v.7 no.2
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• pp.151-159
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• 1997

Since healed microcracks in quartz grain of grantic rocks within the same mass have identical preferred orientations, the oreintations of granitic cores may be determined if the distinctive feature of healed microcracks can be used.In this study, the possibility of determining orientations of granitic cores using healed microcrack orientations were examined using samples from the borehole drilled to 200 m in depth at the Hongcheon. Eight sections whose core recoveries are 100% were selected. Two to six samples were collected in each section and orientations of healed microcracks in each sample were measured. Healed microcracks in samples from each section show almost identical orientations. The error range for sections with only one preferred orientations is within $\pm$5$^{\circ}$, indicating that correct orientations of core can be determined. However, orientations of cores in sections which have 2 or more healed microcrack orientations should be determined using orientations as well as distribution of peaks of orientations. The error range for this case is lager than former one and is within $\pm$15$^{\circ}$. The orientations of joint which is very impontant factor for designing tunnel and slope stability can be determined using healed microcrack orientation in cores.

• Journal of Korean Society on Water Environment
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• v.24 no.2
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• pp.185-194
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• 2008

There is increased soil erosion potential at highland agricultural crop fields because of its topographic characteristics and site-specific agricultural management practices performed at these areas. The agricultural upland fields are usually located at the sloping areas, resulting in higher soil loss, pesticides, and nutrients in case of torrential rainfall events or typhoon, such as 2002 Rusa and 2003 MaeMi. At the highland agricultural fields, the soil reconditioning have been performed every year to decrease damage by continuous cropping and pests. Also it has been done to increase crop productivity and soil fertility. The increased amounts of soil used for soil reconditioning are increasing over the years, causing significant impacts on water quality at the receiving water bodies. In this study, the field investigation was done to check soil reconditioning status for potato, carrot, and cabbage at the Doam-dam watershed. With these data obtained from the field investigation, the Soil and Water Assesment Tool (SWAT) model was used to simulate the soil loss reduction with environment-friendly and agronomically enough soil reconditioning. The average soil reconditioning depth for potato was 34.3 cm, 48.3 cm for carrot, and 31.2 cm for cabbage at the Doam-dam watershed. These data were used for SWAT model runs. Before the SWAT simulation, the SWAT ArcView GIS Patch, developed by the Kangwon National University, was applied because of proper simulation of soil erosion and sediment yield at the sloping watershed, such as the Doam-dam watershed. With this patch applied, the Coefficient of Determination ($R^2$) value was 0.85 and the Nash-Sutcliffe Model Efficiency (EI) was 0.75 for flow calibration. The $R^2$ value was 0.87 and the EI was 0.85 for flow validation. For sediment simulation, the $R^2$ value was 0.91 and the EI was 0.70, indicating the SWAT model predicts the soil erosion processes and sediment yield at the Doam-dam watershed. With the calibrated and validated SWAT for the Doam-dam watershed, the soil erosion reduction was investigated for potato, carrot, and cabbage. For potato, around 19.3 cm of soil were over applied to the agricultural field, causing 146% of more soil erosion rate, approximately 33.3 cm, causing 146% of more soil erosion for carrot, and approximately 16.2 cm, causing 44% of more soil erosion. The results obtained in this study showed that excessive soil reconditioning are performed at the highland agricultural fields, causing severe muddy water issues and water quality degradation at the Doam-water watershed. The results can be used to develop soil reconditioning standard policy for various crops at the highland agricultural fields, without causing problems agronomically and environmentally.

• Journal of the Korean Vacuum Society
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• v.22 no.6
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• pp.341-347
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• 2013

The n-type and p-type silicon samples were exposed by 40.0, 3.98 MeV proton beams ranging between 0 to $20.0{\times}10^{13}protons/cm^2$. Coincidence Doppler Broadening Positron Annihilation Spectroscopy (CDBPAS) were applied to study of defect characteristics of p type and n type silicon samples. In this investigation the numerical analysis of the spectra was employed to the determination of the shape parameter, S, defined as the ratio between the amount of counts in a central portion of the gamma spectrum and the total counts of whole gamma spectrum. The S-parameter values strongly depend on the irradiated proton beam that indicated the defects generate more, rather than the energy intensity. 40 MeV irradiated proton beam in the n-type silicon at $20.0{\times}10^{13}protons/cm^2$ was larger defects than 3.98 MeV irradiated proton beam. It was analysis between the proton irradiation beams and the proton intensities of the irradiation. Because of the Bragg peak, SRIM results shows mainly in a certain depth of the sample to form the defect by the proton irradiation, rather than the defects to appear for the entire sample.