• Title/Summary/Keyword: deposition pattern

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The various bonding structure of SiOC thin films attributed to the carbon density (탄소밀도의 변화가 SiOC 박막의 결합구조에 미치는 영향)

  • Oh Teresa
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.43 no.5 s.347
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    • pp.11-16
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    • 2006
  • This paper reports the correlation between dielectric constant and degree of amorphism of the hybrid type SiOC thin films. SiOC thin films were deposited by high density plasma chemical vapor deposition using bistrimethyl- silylmethane(BTMSM,$H_{9}C_{3}-Si-CH_{2}-Si-C_{3}H_{9}$) and oxygen precursors with various flow rate ratio. As-deposited film and annealed films at $400^{\circ}C$ were analyzed by XRD. The SiOC thin films were amorphous from XRD patterns. For quantitative analysis, the diffraction pattern of the samples was transformed to radial distribution function by Fourier analysis, and then compared with each other. The degree of amorphism of annealed films was higher than that of as-deposited ones. The dielectric constant varied in accordance with flow rate ratio of precursors. The lowest dielectric constant was obtained from the as-deposited film which has the highest degree of amorphism after annealing.

Uniformity Analysis of Unmanned Aerial Application with Variable Rate Spray System (무인항공 변량방제 시스템의 살포 균일도 분석)

  • Koo, Young Mo;Bae, Yeonghwan
    • Journal of agriculture & life science
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    • v.52 no.6
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    • pp.111-125
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    • 2018
  • In this study, we evaluated the uniformity of deposition rate and particle size distributions of the variable rate application technique using the unmanned rotorcraft by measuring the spray pattern according to path location in the range of spraying flight. The coefficient of variation (CV) of the lateral coverage rate for the overlapped distribution with the spray swath of 3.6 m in both guidance and auto-pilot flight modes maintaining constant flight speed was about 30% and the CV of the coverage rate by the flight path location was extremely small. Therefore, it was assessed that the variable rate application technology compensating for the variation of ground speed was superior in terms of spray uniformity. In addition, the droplet size distributions in both volume median diameter(VMD) and number median diameter(NMD) were adequate for aerial application and uniform in terms of lateral distribution. Thereafter, we intend to contribute to a precise application on small-scaled fields using the unmanned agricultural rotorcraft by the variable rate application.

Levels and Patterns of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans in Sediments from Korean Coast

  • Moon Hyo-Bang;Choi Hee-Gu;Kim Sang-Soo;Jeong Seung-Ryul;Lee Pil-Yong
    • Fisheries and Aquatic Sciences
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    • v.4 no.2
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    • pp.51-57
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    • 2001
  • Polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) were measured in sediment samples from 19 stations in the coastal areas of Korea from February to July 2000. PCDDs and PCDFs were detected in all sediment samples. The concentrations of these con­taminants ranged from 18.2 to 804.0 pg/g dry weight and I-TEQ concentrations varied from 0.1 to 5.5 pg/g dry weight. Examination of homologue groups showed that octachlorinated dibenzo-p-dioxin (OCDD) was predominant congener in Korean coast. This pattern was similar to homologue profiles of marine sediments in which the main source of PCDDs/DFs was derived from the atmospheric deposition of particulate matters generated from various industrial activities. Grain size and total organic carbon (TOC) distribution are one of the important factors governing PCDDs/DFs concentration in this study.

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SAW Filter Made of ZnO/Nanocrystalline Diamond Thin Films (ZnO/나노결정다이아몬드 적층 박막 SAW 필터)

  • Jung, Doo-Young;Kang, Chan-Hyoung
    • Journal of Surface Science and Engineering
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    • v.42 no.5
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    • pp.216-219
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    • 2009
  • A surface acoustic wave (SAW) filter structure was fabricated employing $4{\mu}m$ thick nanocrystalline diamond (NCD) and $2.2{\mu}m$ thick ZnO films on Si wafer. The NCD film was deposited in an $Ar/CH_4$ gas mixture by microwave plasma chemical vapor deposition method. The ZnO film was formed over the NCD film in an RF magnetron sputter using ZnO target and $Ar/O_2$ gas. On the top of the two layers, copper film was deposited by the RF sputter and inter digital transducer (IDT) electrode pattern (line/space : $1.5/1.5{\mu}m$) was defined by the photolithography including a lift-off etching process. The fabricated SAW filter exhibited the center frequency of 1.66 GHz and the phase velocity of 9,960 m/s, which demonstrated that a giga Hertz SAW filter can be realized by utilizing the nanocrystalline diamond thin film.

Fabrication of Micro Pattern on Flexible Substrate by Nano Ink using Superhydrophobic Effect (초발수 현상을 이용한 나노 잉크 미세배선 제조)

  • Son, Soo-Jung;Cho, Young-Sang;Rha, Jong Joo;Cho, Chul-Jin
    • Journal of Powder Materials
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    • v.20 no.2
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    • pp.120-124
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    • 2013
  • This study is carried out to develop the new process for the fabrication of ultra-fine electrodes on the flexible substrates using superhydrophobic effect. A facile method was developed to form the ultra-fine trenches on the flexible substrates treated by plasma etching and to print the fine metal electrodes using conductive nano-ink. Various plasma etching conditions were investigated for the hydrophobic surface treatment of flexible polyimide (PI) films. The micro-trench on the hydrophobic PI film fabricated under optimized conditions was obtained by mechanical scratching, which gave the hydrophilic property only to the trench area. Finally, the patterning by selective deposition of ink materials was performed using the conductive silver nano-ink. The interface between the conductive nanoparticles and the flexible substrates were characterized by scanning electron microscope. The increase of the sintering temperature and metal concentration of ink caused the reduction of electrical resistance. The sintering temperature lower than $200^{\circ}C$ resulted in good interfacial bonding between Ag electrode and PI film substrate.

Self-Organized Synthesis and Mechanism of SnO2@Carbon Tube-Core Nanowire

  • Luo, Minting;Ma, Yong-Jun;Pei, Chonghua;Xing, Yujing;Wen, Lixia;Zhang, Li
    • Bulletin of the Korean Chemical Society
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    • v.33 no.8
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    • pp.2535-2538
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    • 2012
  • $SnO_2@carbon$ tube-core nanowire was synthesized via a facile self-organized method, which was in situ by one step via Chemical Vapor Deposition. The resulting composite was characterized by scanning electron microscopy, X-ray diffraction and transmission electron microscope. The diameter of the single nanowire is between 5 nm and 60 nm, while the length would be several tens to hundreds of micrometers. Then X-ray diffraction pattern shows that the composition is amorphous carbon and tin dioxide. Transmission electron microscope images indicate that the nanowire consists of two parts, the outer carbon tube and the inner tin dioxide core. Meanwhile, the possible growth mechanism of $SnO_2@carbon$ tube-core nanowire is also discussed.

Investigation of Eco-friendly Electroless Copper Coating by Sodium-phosphinate

  • Rha, Sa-Kyun;Lee, Youn-Seoung
    • Journal of the Korean Ceramic Society
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    • v.52 no.4
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    • pp.264-268
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    • 2015
  • Cu films were plated in an eco-friendly electroless bath (No-Formaldehyde) on Ni/screen printed Ag pattern/PET substrate. For electroless Cu plating, we used sodium-phosphinate ($NaH_2PO_2{\cdot}H_2O$) as reducing agent instead of Formaldehyde. All processes were carried out in electroless solution of pH 7 to minimize damage to the PET substrate. According to the increase of sodium-phosphinate, the deposition rate, the granule size, and rms roughness of the electroless Cu film increased and the Ni content also increased. The electroless Cu films plated using 0.280 M and 0.575 M solutions of sodium-phosphinate were made with Cu of 94 at.% and 82 at.%, respectively, with Ni and a small amount P. All electroless Cu plated films had typical FCC crystal structures, although the amount of co-deposited Ni changed according to the variation of the sodium-phosphinate contents. From these results, we concluded that a formation of higher purity Cu film without surface damage to the PET is possible by use of sodium-phosphinate at pH 7.

DMAB Effects in Electroless Ni Plating for Flexible Printed Circuit Board (DMAB첨가량에 따른 연성회로기판을 위한 무전해 Ni 도금박막에 관한 연구)

  • Kim, Hyung-Chul;Rha, Sa-Kyun;Lee, Youn-Seoung
    • Korean Journal of Materials Research
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    • v.24 no.11
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    • pp.632-638
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    • 2014
  • We investigated the effects of DMAB (Borane dimethylamine complex, C2H10BN) in electroless Ni-B film with addition of DMAB as reducing agent for electroless Ni plating. The electroless Ni-B films were formed by electroless plating of near neutral pH (pH 6.5 and pH 7) at $50^{\circ}C$. The electroless plated Ni-B films were coated on screen printed Ag pattern/PET (polyethylene terephthalate). According to the increase of DMAB (from 0 to 1 mole), the deposition rate and the grain size of electroless Ni-B film increased and the boron (B) content also increased. In crystallinity of electroless Ni-B films, an amorphization reaction was enhanced in the formation of Ni-B film with an increasing content of DMAB; the Ni-B film with < 1 B at.% had a weak fcc structure with a nano crystalline size, and the Ni-B films with > 5 B at.% had an amorphous structure. In addition, the Ni-B film was selectively grown on the printed Ag paste layer without damage to the PET surface. From this result, we concluded that formation of electroless Ni-B film is possible by a neutral process (~green process) at a low temperature of $50^{\circ}C$.

Reliability Evaluation of the WSW Device for Hot-carrier Immunity (핫-캐리어 내성을 갖는 WSW 소자의 신뢰성 평가)

  • 김현호;장인갑
    • Journal of the Korea Society of Computer and Information
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    • v.9 no.1
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    • pp.9-15
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    • 2004
  • New WSW(Wrap Side Wall) is proposed to decrease junction electric field in this paper. WSW process is fabricated after first gate etch, followed NM1 ion implantation and deposition & etch nitride layer. New WSW structure has buffer layer to decrease electric field. Also we compared the hot carrier characteristics of WSW and conventional. Also, we design a test pattern including pulse generator, level shifter and frequency divider, so that we can evaluate AC hot carrier degradation on-chip. It came to light that the universality of the hot carrier degradation between DC and AC stress condition exists, which indicates that the device degradation comes from the same physical mechanism for both AC and DC stress. From this universality, AC lifetime under circuit operation condition can be estimated from DC hot carrier degradation characteristics.

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The Optimization of Indium Zinc Oxide Thin Film Process in Color Filter on Array structure

  • Lee, Je-Hun;Kim, Jin-Suek;Jeong, Chang-Oh;Kim, Shi-Yul;Lim, Soon-Kwon;Souk, Jun-Hyung
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1244-1247
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    • 2004
  • For obtaining the best panel quality of color filter on array(COA) architecture in TFF LCD, we investigated the influence of deposition temperature, $O_2$ flow, thickness on the optical transmittance, wet etching and adhesion properties of IZO deposited onto each color photo resist(red, green, blue). Average transmittance of the pixel single layer in the visible range(between 380 and 780nm) was mainly affected by thickness and showed maximum at 1250 ${\AA}$ while the thickness showing peak transparency in each R, G, B wavelength was different. The relation was calculated by using bi-layer transmission and reflectance model, which corresponded to experimental data very well. The adhesion of IZO deposited on each color PR was found to have enhanced value except red PR case, compared to that of IZO which was deposited on $SiN_x$. Wet etching pattern linearity was decreased as the thickness increased. The thickness of IZO was one of vital factors in order to optimize overall pixel process for fabricating COA structure.

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