• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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• pp.121.2-121.2
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• 2011

Aluminum-doped Zinc Oxide (AZO) is considered as an excellent candidate to replace Indium Tin Oxide (ITO), which is widely used as transparent conductive oxide (TCO) for electronic devices such as liquid crystal displays (LCDs), organic light emitting diodes (OLEDs) and organic solar cells (OSCs). In the present study, AZO thin film was applied to the transparent electrode of a channel-shaped flexible organic solar cell using a low-temperature selective-area atomic layer deposition (ALD) process. AZO thin films were deposited on Poly-Ethylene-Naphthalate (PEN) substrates with Di-Ethyl-Zinc (DEZ) and Tri-Methyl-Aluminum (TMA) as precursors and $H_2O$ as an oxidant for the atomic layer deposition at the deposition temperature of $130^{\circ}C$. The pulse time of TMA, DEZ and $H_2O$, and purge time were 0.1 second and 20 second, respectively. The electrical and optical properties of the AZO films were characterized as a function of film thickness. The 300 nm-thick AZO film grown on a PEN substrate exhibited sheet resistance of $87{\Omega}$/square and optical transmittance of 84.3% at a wavelength between 400 and 800 nm.

• Journal of Advanced Marine Engineering and Technology
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• 제38권10호
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• pp.1333-1339
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• 2014

As the demand for petroleum resources increases, and oilfields on lands and in shallow-sea become exhausted, the areas for oil production are expanding to the deep sea and therefore technologies for flow assurance are coming into the highlight. In low temperature environment such as the deep sea, wax is accumulated and prevents stable oil production. Therefore, the development of flow assurance technologies is required. Wax is precipitated in crystalline form when the oil temperature decreases below the wax appearance temperature; it then accumulates on the inner walls of pipelines causing blockages. In particular, in subsea pipelines, which have a large surface contact area with the surrounding seawater, wax deposition problems are frequent. The internal tubular coating can effectively reduce wax deposition without pausing oil production when the coating is appropriately designed. This study carried out wax deposition tests on a number of internal tubular coatings under single flow conditions. The results were analyzed for the effects that the physical properties of the coatings had on wax deposition.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.166.2-166.2
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• 2014

In this work, we demonstrated a facile and effective method for deposition of metal tetraphenylporphyrin (MTPP) thin film by a combined a thermal evaporation (TE) and atomic layer deposition (ALD). For the deposition of Zn-TPP thin film, Tetraphenylporphyrin (TPP) and diethyl zinc (DEZ) were used as organic and inorganic materials, respectively. Optimum conditions for the deposition of Zn-TPP thin film were established systematically: (1) the exposure time of DEZ as inorganic precursor and (2) the substrate temperature were adjusted, respectively. As a result, we verified that the surface reaction between organic semiconductor (TPP) and metal atom (Zn) was ALD process. In addition, we calculated activation energy by using Arrhenius equation for the substrate temperature versus area change rate of pyrrolic nitrogen. The surface and interface reactions between TPP with Zn were investigated by X-ray photoelectron spectroscopy, Raman spectroscopy, UV-vis spectroscopy, and scanning electron microscopy. These results show a facile and well-controllable fabrication technique for the metal-organic thin film for future electronic applications.

• Nuclear Engineering and Technology
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• 제34권3호
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• pp.242-249
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• 2002

The relationship between the tritium release rate from the nuclear power plant and tritium concentration in the environment around the Kori site was modeled. The tritium concentration in the atmosphere was calculated by multiplying the release rates and $\chi$/Q values, and the d3V deposition rate at each sector according to the direction and the distance was obtained using a dry deposition velocity. The area around Kori site was divided into 6 zones according to the deposition rate. The six zones were divided into 14 compartments for the numerical simulation. Transfer coefficients between the compartments were derived using site characterization data. Source terms were calculated from the dry deposition rates. Tritium concentration in surface soil water and groundwater was calculated based upon a compartment model. The semi-analytical solution of the compartment model was obtained with a computer program, AMBER. The results showed that most of tritium deposited onto the land released into the atmosphere and the sea. Also, the estimated concentration in the top soil agreed well to that measured. Using the model, tritium concentration was predicted in the case that the tritium release rates were doubled.

• 한국수자원학회논문집
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• 제40권5호
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• pp.409-418
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• 2007

건기에 합류식 관거 내에 퇴적된 고형물은 우기에 재부상하여 초기부하(first-flush) 현상의 주된 원인이 되고 있으며, 이러한 고형물의 퇴적으로 인해 관거 내 통수능이 감소하여 도시지역의 국지적인 내수침수가 발생하고 있다. 이와 같은 문제를 해결하기 위해서는 장기간에 걸친 관거 내 고형물 퇴적량을 관측할 필요가 있으나 많은 비용과 노력이 수반되어야 한다. 본 논문에서는 MOUSE 모형에 의해 산정된 결과로부터 고형물 퇴적량을 산정하기 위한 회귀식의 개발 및 적용성을 검토하였다. 분석 결과 관거 내 퇴적고형물의 관측 자료가 구비되어 있지 않아 실질적으로 비교하기는 곤란하지만 MOUSE 모형이나 EPA(미환경보호청)에서 제시한 공식을 이용하여 산정한 결과와 비교해 볼 때 본 연구에서 개발된 산정식은 적용성이 있음을 보여주고 있다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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• pp.787-790
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• 2003

A rf triode magnetron sputtering system is designed and installed its construction in vacuum chamber. In order to calibrate the rf triode magnetron sputtering for thin films deposition processes, the effects of different glow discharge conditions were investigated in terms of the deposition rate measurements. The basic parameters for calibrating experiment in this sputtering system are rf power input, gas pressure, plasma current, and target-to-substrate distance. Because a knowledge of the deposition rate is necessary to control film thickness and to evaluate optimal conditions which are an important consideration in preparing better thin films, the deposition rates of copper as a testing material under the various sputtering conditions are investigated. Furthermore, a triode sputtering system designed in our team is simulated by the SIMION program. As a result, it is sure that the simulation of electron trajectories in the sputtering system is confined directly above the target surface by the force of $E{\times}B$ field. Finally, some teats with the above 4 different sputtering conditions demonstrate that the deposition rate of rf triode magnetron sputtering is relatively higher than that of the conventional sputtering system. This means that the higher deposition rate is probably caused by a high ion density in the triode and magnetron system. The erosion area of target surface bombarded by Ar ion is sputtered widely on the whole target except on both magnet sides. Therefore, the designed rf triode magnetron sputtering is a powerful deposition system.

• Fisheries and Aquatic Sciences
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• 제8권3호
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• pp.167-176
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• 2005

Atmospheric deposition and riverine waters were sampled throughout a year, to estimate the loading fluxes of polycyclic aromatic hydrocarbons (PAHs) into the Masan Bay and its vicinity, Korea. Atmospheric deposition fluxes of total PAHs in the surveyed area varied from 62.2 to 464 ${\mu}g/m^2/year$. Concentration of total PAHs in water samples from six rivers ranged from 34.6 to 239 ng/L. Contribution of the carcinogenic PAHs to the total PAHs occupied $38\%$ and $50\%$ for atmospheric deposition and river waters, respectively. Atmospheric deposition fluxes and water concentrations of PAHs were slightly low or moderate to those in locations from some countries. Correspondence analysis was used to investigate the loading characteristics of PAHs according to transport routes. Atmospheric deposition samples were corresponded to higher molecular aromatics of PAHs, while riverine water samples were associated with lower molecular weight of PAHs. The results indicate that the higher-molecular-weight PAHs can be primarily transported by atmosphere deposition and the lower-molecular-weight PAHs can be mainly contaminated by riverine discharge into the Masan Bay and its vicinity. Loadings fluxes of PAHs into the Masan Bay and its vicinity were 39.2 g/day via atmosphere and 10.3 g/day via rivers, showing that atmospheric input was about 4 times higher than riverine one. Therefore, in order to minimize the contamination burden of PAHs from terrestrial sources to the Masan Bay and its vicinity, the control and management of PAHs deriving from atmosphere will be necessary.

• 대한기계학회논문집B
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• 제41권4호
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• pp.239-248
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• 2017

원형 실린더 주위의 유동에 부유된 입자가 실린더 근처에서 분산되거나 실린더에 부착되는 특성을 이해하는 것이 중요하다. 본 연구에서는 입자의 부착을 조절하는 방안으로 실린더의 회전을 고려해 보았고, 실린더의 회전 속도 및 입자의 Stokes 수가 실린더 주위의 유동과 입자의 분산 및 부착 특성에 미치는 영향을 수치해석적으로 연구하였다. 해석 결과 4보다 작은 Stokes 수에서는 회전속도가 증가함에 따라 부착효율이 크게 감소하였고, 4보다 큰 Stokes 수에서는 회전속도가 증가함에 따라 부착효율이 다소 증가하였다. 한편, 회전속도가 일정한 경우에는 Stokes 수가 증가함에 따라 입자의 부착효율이 증가하고, 입자의 부착 위치도 넓어졌다.

• 터널과지하공간
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• 제14권6호
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• pp.429-439
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• 2004

국내 원전에서 발생되는 36,000톤의 사용후핵연료를 처분하기 위해서는 약 $4km^2$의 지하 처분장이 필요하다. 본 연구에서는 굴착량과 처분장 면적을 최소화하기 위한 지하 심부 처분장 배치의 최적화를 실시하였다. 열 해석 결과를 토대로 처분 터널과 처분공 간격이 처분장 배치에 미치는 영향을 고려한 결과, 처분장 면적과 굴착량은 처분 터널의 길이가 길어짐에 따라 감소하였다. 주어진 열적 기준을 만족하면서 처분장 면적을 줄이기 위해서는 처분 터널의 간격을 줄이고 처분공 간격을 늘리는 것이 유리하였으며, 반면에 굴착량을 최소화하는 경우 처분공 간격을 줄이고 처분 터널 간격을 늘려주는 것이 효과적인 것으로 나타났다.

• 한국표면공학회지
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• 제49권5호
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• pp.416-422
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• 2016

We have investigated the effects of applied potential, deposition time and electrolyte types on shapes and physical properties of Cu dendrites by potentiostatic electrodeposition. Finer shape of dendrites was observed at less cathodic potential by 100mV than at the limiting current, due to 'effective overpotential'. The shape of copper dendrite is related to the deposition time, too. The dendrite depositing for 10 min showed the finest shape. The finer dendrite has the less apparent density and the larger specific surface area. Dendrite from chloride solution has the lowest density and the largest surface area among three plating solutions, sulfate, chloride and pyrophosphate.