• Title/Summary/Keyword: decay properties

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Enhanced Photosensitivity in Monolayer MoS2 with PbS Quantum Dots

  • Cho, Sangeun;Jo, Yongcheol;Woo, Hyeonseok;Kim, Jongmin;Kwak, Jungwon;Kim, Hyungsang;Im, Hyunsik
    • Applied Science and Convergence Technology
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    • v.26 no.3
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    • pp.47-49
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    • 2017
  • Photocurrent enhancement has been investigated in monolayer (1L) $MoS_2$ with PbS quantum dots (QDs). A metal-semiconductor-metal (Au-1L $MoS_2$-Au) junction device is fabricated using a standard photolithography method. Considerably improved photo-electrical properties are obtained by coating PbS QDs on the Au-1L $MoS_2$-Au device. Time dependent photoconductivity and current-voltage characteristics are investigated. For the QDs-coated $MoS_2$ device, it is observed that the photocurrent is considerably enhanced and the decay life time becomes longer. We propose that carriers in QDs are excited and transferred to the $MoS_2$ channel under light illumination, improving the photocurrent of the 1L $MoS_2$ channel. Our experimental findings suggest that two-dimensional layered semiconductor materials combined with QDs could be used as building blocks for highly-sensitive optoelectronic detectors including radiation sensors.

Fabrication of High Sensitive Photoconductive Multilayer Using Se,As and Te and its Application (Se, As 및 Te를 이용한 고감도 다층 광도전막의 제작 및 그 응용)

  • 박기철;이건일;김기완
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.25 no.4
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    • pp.422-429
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    • 1988
  • The photoconductive multilayer of Se-As(hole blocking layer)/Se-As-Te (photoconductive layer) /Se-As (layer for supporiting hole transport)/Se-As(layer or controlling total capacitance)/Sb2S3(electron blocking layer) was fabricated and its electrical and optical properties were investigated. The photoconductive multilayer is made of evaporated a-Se as the base material, doped with As and Te to prevent the crystallization of a-Se and to enhance red sensitivity, respectively. The multilayer with good image reproducibility has the following deposition condition. The first layer has the thickness of 250\ulcornerat the deposition rate of 250\ulcornersec. The second layer has the thickness of 800\ulcornerat the deposition rate of 250\ulcornersec. The third layer has the thickness of 125\ulcornerat the deposition rate of 250\ulcornersec. The fourth layer has the thickness of 1700\ulcornerunder the Ar gas ambient of 50x10**-3torr. The image pick-up tube, employing this multilayer demonstrates the following characteristics. The photosensitivity is 0.8, the resolution limit is above 300TV line, and the decay lag is about 7%. And spectral response convers the whole visible range. Therfore the application to color TV camera is expected.

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Synthesis and Properties of Novel Y-type Nonlinear Optical Polyester Containing Dioxynitroazobenzene Group with Enhanced Thermal Stability of Dipole Alignment

  • Kim, Mi-Sung;Cho, You-Jin;Song, Mi-Young;Lee, Ju-Yeon
    • Bulletin of the Korean Chemical Society
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    • v.32 no.9
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    • pp.3361-3366
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    • 2011
  • New Y-type polyester (3) containing nitrophenylazoresorcinoxy groups as NLO chromophores, which are components of the polymer backbone, was prepared and characterized. Polyester 3 is soluble in common organic solvents such as N,N-dimethylformamide and acetone. It shows a thermal stability up to $240^{\circ}C$ in thermogravimetric analysis with glass-transition temperature ($T_g$) obtained from differential scanning calorimetry near $116^{\circ}C$. The second harmonic generation (SHG) coefficient ($d_{33}$) of poled polymer film at the 1064 nm fundamental wavelength is around $4.63{\times}10^{-9}$ esu. The dipole alignment exhibits a thermal stability even at $4^{\circ}C$ higher than $T_g$, and there is no SHG decay below $120^{\circ}C$ due to the partial main-chain character of polymer structure, which is acceptable for NLO device applications.

SIGNIFICANCE OF ACTINIDE CHEMISTRY FOR THE LONG-TERM SAFETY OF WASTE DISPOSAL

  • Kim, Jae-Il
    • Nuclear Engineering and Technology
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    • v.38 no.6
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    • pp.459-482
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    • 2006
  • A geochemical approach to the long-term safety of waste disposal is discussed in connection with the significance of actinides, which shall deliver the major radioactivity inventory subsequent to the relatively short-term decay of fission products. Every power reactor generates transuranic (TRU) elements: plutonium and minor actinides (Np, Am, Cm), which consist chiefly of long-lived nuclides emitting alpha radiation. The amount of TRU actinides generated in a fuel life period is found to be relatively small (about 1 wt% or less in spent fuel) but their radioactivity persists many hundred thousands years. Geological confinement of waste containing TRU actinides demands, as a result, fundamental knowledge on the geochemical behavior of actinides in the repository environment for a long period of time. Appraisal of the scientific progress in this subject area is the main objective of the present paper. Following the introductory discussion on natural radioactivities, the nuclear fuel cycle is briefly brought up with reference to actinide generation and waste disposal. As the long-term disposal safety concerns inevitably with actinides, the significance of the aquatic actinide chemistry is summarized in two parts: the fundamental properties relevant to their aquatic behavior and the geochemical reactions in nanoscopic scale. The constrained space of writing allows discussion on some examples only, for which topics of the primary concern are selected, e.g. apparent solubility and colloid generation, colloid-facilitated migration, notable speciation of such processes, etc. Discussion is summed up to end with how to make a geochemical approach available for the long-term disposal safety of nuclear waste or for the performance assessment (PA) as known generally.

Scintillation properties of CsSrCl3 single crystal (CsSrCl3 단결정의 섬광특성)

  • Doh, Sih-Hong;Kim, Sung-Hwan;Ra, Se-Jin;Kim, Hong-Joo;Kang, Hee-Dong;Oh, Moon-Young
    • Journal of Sensor Science and Technology
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    • v.16 no.5
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    • pp.337-341
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    • 2007
  • $CsSrCl_{3}$ crystal was grown using Czochralski method from equimolar mixture of CsCl and $SrCl_{2}$. The spectrum range of the luminescence excited by 205 nm of wavelength was about $280{\sim}550$ nm, and its peak emission appeared at 343 nm. The luminescence decay curve of the $CsSrCl_{3}$ revealed two exponential components with time constants of 60 ns and 700 ns. The energy resolution for $^{137}Cs$ 662 keV ${\gamma}$-ray was 10.3 %. The pulse shape was linear at high energy, but some deviation existed in the low energy region.

Scintillation Properties of Acrylate Based Plastic Scintillator by Photoploymerization Method (아크릴레이트 기반 광중합 플라스틱 섬광체의 섬광 특성)

  • Kim, Sunghwan;Lee, JoonIl
    • Journal of radiological science and technology
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    • v.39 no.4
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    • pp.637-642
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    • 2016
  • In this study, we prepared and characterized a acrylate based UV-curable plastic scintillator. It was used co-polymers TMPTA, DHPA and Ultima $Gold^{TM}$ LLT organic scintillator. The emission spectrum of the plastic scintillator was located in the range of 380~520 nm, peaking at 423 nm. And the scintillator is more than 50% transparent in the range of 400~800 nm. The emission spectrum is well match to the quantum efficiency of photo-multiplier tube and the fast decay time of the scintillation is 12 ns, approximately. This scintillation material provides the possibility of combining 3D printing technology, and then the applications of the plastic scintillator may be expected in human dosimetry etc.

A Hydraulic Model Test of Wave Transformation in the Surf Zone (쇄파대에서의 파랑 변형에 대한 수리모형실험)

  • 정신택;채장원;정원무
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.3 no.3
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    • pp.163-169
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    • 1991
  • Sixty seven regular wave tests were performed in a wave-current flume to investigate proper-ties of waves breaking on irregular slope profiles. In these tests, 1/10, 1/20 beach slopes were made using angles and plywoods. A little differences were found in such properties as breaker depth and height indices. runup for plane slopes comparing with other laboratory experiments. however. for smaller deepwater wave steepness, measured breaker height and depth data values were smaller than other formulas. On wave runup agreement was good between experiments and Hunt formula. however. measured data values were influenced by number of breaking. Significant differences were found in breaker depth index for plane and barred slopes. Wave height decay after breaking was found to be smaller than Dally et al.'s formula (1984).

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Involvement of the Phospholipase C β1 Pathway in Desensitization of the Carbachol-activated Nonselective Cationic Current in Murine Gastric Myocytes

  • Kim, Byung Joo;So, Insuk;Kim, Ki Whan
    • Molecules and Cells
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    • v.22 no.1
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    • pp.65-69
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    • 2006
  • In murine gastrointestinal myocytes muscarinic stimulation activates nonselective cation channels via a G-protein and $Ca^{2+}$-dependent pathway. We recorded inward cationic currents following application of carbachol ($I_{CCh}$) to murine gastric myocytes held at -60 mV, using the whole-cell patch-clamp method. The properties of the inward cationic currents were similar to those of the nonselective cation channels activated by muscarinic stimulation in other gastrointestinal smooth muscle cells. CCh-induced $I_{CCh}$ and spontaneous decay of $I_{CCh}$ (desensitization of $I_{CCh}$) occurred. Unlike the situation in guinea pig gastric myocytes, desensitization was not affected by varying $[EGTA]_i$. Pretreatment with the PLC inhibitor (U73122) blocked the activation of $I_{CCh}$, and desensitization of $I_{CCh}$ was attenuated in PLC ${\beta}_1$ knock-out mice. These results suggest that the desensitization of $I_{CCh}$ in murine gastric myocytes is not due to a pathway dependent on intracellular $Ca^{2+}$ but to the PLC ${\beta}_1$ pathway.

A Scaling of Velocity and Magnetic field in Decaying Turbulence in Expanding/Collapsing Media

  • Park, Jun-Seong;Ryu, Dong-Su;Cho, Jung-Yeon
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.2
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    • pp.108.2-108.2
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    • 2011
  • We investigate decaying magnetohydrodynamic (MHD) turbulence by including the effects of expansion and collapse of the background medium. The problem has two time scales, the eddy turn-over time($t_{eddy}$) and the expansion/collapse time scale(${\tau}_H$). The turbulence is expected to behave differently in two regimes of $t_{eddy}$ < ${\tau}_H$ and $t_{eddy}$ > ${\tau}_H$. For instance, for $t_{eddy}$ < ${\tau}_H$, the turbulence would decay more or less as in a static medium. On the other hand, for $t_{eddy}$ > ${\tau}_H$, the effects of expansion and collapse would be dominant. We examine the properties of turbulence in the regimes of $t_{eddy}$ < ${\tau}_H$ and $t_{eddy}$ > ${\tau}_H$. Based on it, we derive a scaling for the time evolution of flow velocity and magnetic field.

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Preparation of Novel T-type Polyurethanes with High Thermal Stability of Second Harmonic Generation and Their Nonlinear Optical Properties

  • Jang, Han-Na;Lee, Ga-Young;Lee, Ju-Yeon
    • Bulletin of the Korean Chemical Society
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    • v.29 no.4
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    • pp.811-816
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    • 2008
  • 2,5-Di-(2'-hydroxyethoxy)benzylidenemalononitrile (3) was prepared and polymerized with 2,4-toluenediisocyanate and 3,3'-dimethoxy-4,4'-biphenylenediisocyanate to yield novel T-type polyurethanes 4 and 5 containing 2,5-dioxybenzylidenemalononitrile, nonlinear optical (NLO)-chromophores as part of the polymer backbones. Polyurethanes 4 and 5 were soluble in common organic solvents such as acetone and N,Ndimethylformamide and showed a thermal stability up to $250{^{\circ}C}$ with glass-transition temperatures ($T_g$) in the range $119-146{^{\circ}C}$. The second harmonic generation (SHG) coefficients ($d_{33}$) of poled polymer films at 1064 nm fundamental wavelength were around $5.82{\times}10^{-9}$ esu. The dipole alignment exhibited high thermal stability up to $T_g$, and there was no SHG decay below $140{^{\circ}C}$ due to the partial main-chain character of the polymer structure, which was acceptable for nonlinear optical device applications.